Processes for enhancing flame retardance and chemical resistance of polymers
View Patent ↗Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.
1. A method for forming a cross-linked polycarbonate article, comprising:
providing a composition that comprises:
a cross-linkable polycarbonate resin having endcaps derived from a monohydroxybenzophenone, a weight average molecular weight (Mw) from 15,000 to 30,000 and a polydispersity index (PDI) from 3.0 to 4.0 as measured by GPC using a UV detector and polycarbonate standards, and a monohydroxybenzophenone-derived endcap content from 3.0 to 4.5 wt %;
optionally one or more additional polycarbonate base resins different from the cross-linkable polycarbonate resin; and
a flame retardant;
wherein the monohydroxybenzophenone-derived endcap content of the composition is between 1.2 wt % and 4 wt %, and wherein the composition has a melt flow rate (MFR) of 7 to 20 g/10 min measured at 300° C./1.2 kg/360 sec dwell;
forming an article from the composition; and
exposing the formed article to UV radiation from a UV radiation source for a time sufficient to form the cross-linked polycarbonate article;
wherein the cross-linked polycarbonate article has a gel layer of at least 5 microns thickness as measured by optical microscopy, and wherein the molded article after exposure to UV radiation has a pFTP(V1) of at least 0.95 at 1.2 mm thickness after aging for 7 days at 70° C.
2. The method of claim 1 , wherein the UV radiation source is a metal halide doped mercury lamp, an electrodeless D-bulb, an electrodeless H-bulb, an electrodeless V-bulb, a Xenon Arc lamp, or a UVA (320-390 nm) light emitting diode (LED).
3. The method of claim 1 , wherein the UV radiation source is a metal halide doped mercury lamp or an electrodeless D-bulb.
4. The method of claim 3 , wherein the molded article is exposed to UV radiation from a metal halide doped mercury lamp providing at least 12 J/cm 2 of UVA as measured using an EIT PowerPuck.
5. The method of claim 3 , wherein the molded article is exposed to UV radiation from a metal halide doped mercury lamp providing at least 35.9 J/cm 2 of UVA as measured using an EIT PowerPuck.
6. The method of claim 3 , wherein the molded article is exposed to UV radiation from a metal halide doped mercury lamp providing at least 59.9 J/cm 2 of UVA as measured using an EIT PowerPuck.
7. The method of claim 1 , wherein the molded article is exposed to filtered UV radiation using a 280 nm long pass filter.
8. The method of claim 1 , wherein the molded article is exposed to filtered UV radiation using a 320 nm long pass filter.
9. The method of claim 1 , wherein the article is formed by injection molding.
10. A method for preparing an injection-molded article having low yellowness and high chemical resistance, comprising:
receiving a composition that comprises:
a cross-linkable polycarbonate resin having endcaps derived from a monohydroxybenzophenone, a weight average molecular weight (Mw) from 15,000 to 30,000 and a polydispersity index (PDI) from 3.0 to 4.0 as measured by GPC using a UV detector and polycarbonate standards, and a monohydroxybenzophenone-derived endcap content from 3.0 to 4.5 wt %;
optionally one or more additional polycarbonate base resins different from the cross-linkable polycarbonate resin; and
optionally a flame retardant;
wherein the composition has a melt flow rate (MFR) of 7 g/10 min or higher, measured at 300° C./1.2 kg/360 sec dwell;
injection-molding the composition to a molded article; and
exposing the molded article to a selected UV light range and a selected dosage of UV radiation to obtain the injection-molded article, wherein the injection molded article has a yellowness index (YI) of 15 or less at 3.2 mm thickness when measured at least 48 hours after UV exposure, and has a % retention of 85% or greater at 3.2 mm thickness in a tensile elongation at break test using the ASTM D638 Type I method at 50 mm/min after exposure to acetone under 1.0% strain at 23° C.
11. The method of claim 10 , wherein the injection molded article has a pFTP(V1) of at least 0.70 at 1.2 mm thickness after aging for 7 days at 70° C.
12. The method of claim 10 , wherein the injection molded article has a YI of 8 or less.
13. The method of claim 10 , wherein the composition has a melt flow rate (MFR) of 7 to 20 g/10 min.
14. The method of claim 10 , wherein the composition comprises Rimar salt flame retardant, and the injection molded article has a pFTP(V1) of at least 0.70 at 1.2 mm thickness after aging for 7 days at 70° C.
15. The method of claim 10 , wherein the composition comprises Rimar salt flame retardant, and the injection molded article has a pFTP(V1) of at least 0.90 at 1.2 mm thickness after aging for 7 days at 70° C.
16. The method of claim 10 , wherein the composition comprises Rimar salt flame retardant, and the injection molded article has a pFTP(V0) of at least 0.60 at 1.2 mm thickness after aging for 7 days at 70° C.
17. A composition, comprising:
a cross-linkable polycarbonate resin having endcaps derived from a monohydroxybenzophenone and a weight average molecular weight (Mw) from 15,000 to 30,000 and a polydispersity index (PDI) from 3.0 to 4.0 as measured by GPC using a UV detector and polycarbonate standards;
optionally one or more additional polycarbonate base resins different from the cross-linkable polycarbonate resin; and
a flame retardant;
wherein the composition comprises at least 45 wt % of the cross-linkable polycarbonate resin, wherein the monohydroxybenzophenone-derived endcap content of the composition is between 1.2 wt % and 4 wt %, wherein the composition has a melt flow rate (MFR) of 7 to 20 g/10 min measured at 300° C./1.2 kg/360 sec dwell, and wherein an article formed from the composition has a light transmission (% T), of 85% or greater at 3.2 mm thickness.
18. A molded article formed from the composition of claim 17 , wherein after irradiation with UV light, the article has (a) a light transmission (% T) of 75% or greater at 3.2 mm thickness, and (b) either:
(i) a gel layer of at least 8 microns thickness as measured by optical microscopy; or
(ii) an increase in Mw of at least 30% as measured by GPC using a UV detector and polycarbonate standards.
19. The molded article of claim 18 , wherein the article has a pFTP(V1) of at least 0.95 at 1.2 mm thickness after aging for 7 days at 70° C.
20. The molded article of claim 18 , wherein the article has a delta yellowness index (YI) value of 12 or less at 3.2 mm thickness measured at least 48 hours after UV exposure.
21. The molded article of claim 18 , wherein the article has a pFTP(V0) of at least 0.6 at 1.2 mm thickness.
22. The molded article of claim 18 , wherein the article has a % retention of 85% or greater at 3.2 mm thickness in a tensile elongation at break test using the ASTM 0638 Type I method at 50 mm/min after exposure to acetone under 1% strain at 23° C.
23. The molded article of claim 22 , wherein the article has a delta yellowness index (YI) of less than 12 at 3.2 mm thickness measured at least 48 hours after UV exposure.
24. The molded article of claim 22 , wherein the article has a pFTP(V1) of at least 0.95 at 1.2 mm thickness after aging for 7 days at 70° C.
25. The molded article of claim 18 , wherein the article has a % retention of 90% or greater at 3.2 mm thickness in a tensile elongation at break test using the ASTM D638 Type I method at 50 mm/min after exposure to acetone under 1% strain at 23° C.
26. The molded article of claim 25 , wherein the article has a delta yellowness index (YI) of less than 12 at 3.2 mm thickness measured at least 48 hours after UV exposure.
27. The molded article of claim 25 , wherein the article has a pFTP(V1) of at least 0.95 at 1.2 mm thickness after aging for 7 days at 70° C.