Resin composition, film, bag product and production process of resin composition
View Patent ↗An object of the present invention is to provide a resin composition improved in film formability and/or mechanical property, particularly tensile elastic modulus or tearing strength, of the film. The present invention provides a resin composition including at least (A) an aliphatic polyester-based resin and (C) a starch, the aliphatic polyester-based resin (A) forming a matrix phase and the starch (C) forming a dispersed phase, wherein the average particle diameter of the dispersed phase is 1 μm or less.
1. A process for producing a resin composition comprising (A) an aliphatic polyester-comprising resin, (B) a thermoplastic resin other than an aliphatic polyester-comprising resin, (C) starch, and (D) a plasticizer suitable for plasticizing starch, the process comprising:
mixing (X) a composition comprising (B) the thermoplastic resin other than an aliphatic polyester-comprising resin, (C) starch having an average particle diameter of 1 micron or less, and (D) the plasticizer suitable for plasticizing starch, with (A) the aliphatic polyester-comprising resin.
2. The process of claim 1 , wherein during the mixing the amount of water present is less than 1 mass %.
3. The process of claim 1 , wherein the mixing forms a resin composition comprising less than 1 mass % water.
4. The process of claim 1 , wherein the (A) aliphatic polyester-comprising resin has a cyclic dimer content of 1,000-10,000 ppm.
5. The process of claim 1 , wherein the (A) aliphatic polyester-comprising resin comprises a diol unit and a dicarboxylic acid unit as constituent units.
6. The process of claim 1 , wherein the (A) aliphatic polyester-comprising resin has a melting temperature of 130° C. or less.
7. The process of claim 1 , wherein the (A) aliphatic polyester-comprising resin is at least one selected from the group consisting of a polybutylene succinate-comprising resin and a polybutylene succinate adipate-comprising resin.
8. The process of claim 1 , wherein the (D) plasticizer is an organic compound having a hydroxyl group.
9. The process of claim 1 , wherein the mixing includes blending all of the raw materials to form a blend composition, and charging the blend composition into a hopper of an extruder and melt-mixing the blend composition in the extruder.
10. The method of claim 1 , wherein the mixing includes blending the (A) aliphatic polyester-comprising resin, the (C) starch and the (D) plasticizer and charging the resultant blended composition into a hopper of an extruder.
11. The method of claim 1 , wherein the mixing comprises blending the (B) thermoplastic resin, the (C) starch and the (D) plasticizer to form a blend composition and melt-mixing the blend composition in an extruder.
12. The method of claim 1 , wherein the mixing is carried out in an extruder to effect melt-mixing.
13. The method of claim 1 , wherein (B) the thermoplastic resin other than an aliphatic polyester-comprising resin is an aliphatic-aromatic polyester-based resin.
14. The method of claim 1 , wherein (B) the thermoplastic resin other than an aliphatic polyester-comprising resin is a polybutylene adipate terephthalate-based resin.
15. The method of claim 1 , wherein the mixing forms a composition having a sea-island structure in which the aliphatic polyester-comprising resin (A) is a matrix phase, the starch (C) is a first dispersed phase, and the thermoplastic resin other than the aliphatic polyester-comprising resin (B) is a second dispersed phase.
16. The method of claim 1 , wherein the mixing forms a mixture wherein the aliphatic polyester-comprising resin (A) is a matrix phase, the starch (C) is a first dispersed phase, and the thermoplastic resin other than the aliphatic polyester-comprising resin (B) is a second dispersed phase; wherein an average particle diameter of the first dispersed phase is 0.5 μm or less and the content of the starch (C) is from 30 mass % to 60 mass % based on the entire resin composition (100 mass %), and wherein the plasticizer (D) accounts for from 17 mass % to 55 mass % based on the total weight of the starch (C).
17. The process of claim 1 , wherein the mixing is carried out in a twin-screw extruder having a main raw material feed part for feeding raw materials, an auxiliary raw material feed part, and a devolatilization part between the auxiliary raw material feed part and a die head.
18. The process of claim 17 , wherein, during the mixing, the (C) starch is fed from the main raw material feed part and the (A) aliphatic polyester-comprising resin is fed from the auxiliary raw material feed part, and devolatilization is carried out in the devolatilization part.
19. The method of claim 1 , wherein the (C) starch and the (D) plasticizer are mixed first, then
the (A) aliphatic polyester-comprising resin and the (B) thermoplastic resin are fed to an extruder with a feeding device.
20. The method of claim 19 , wherein the feeding device is a side feeder.
21. The method of claim 19 , wherein the (B) thermoplastic resin and the (A) aliphatic polyester-comprising resin are melt mixed in the same extruder.
22. The method of claim 16 , further comprising:
before the mixing, kneading the thermoplastic resin other than the aliphatic polyester-comprising resin (B), the starch (C) and the plasticizer (D) to form the composition, then adding the aliphatic polyester-comprising resin (A) to the composition and kneading.