Cost-effective solid state reactive sintering method for protonic ceramic fuel cells
View Patent ↗The present invention relates to a protonic ceramic fuel cell and a method of making the same. More specifically, the method relates to a cost-effective route which utilizes a single moderate-temperature (less than or equal to about 1400° C.) sintering step to achieve the sandwich structure of a PCFC single cell (dense electrolyte, porous anode, and porous cathode bone). The PCFC layers are stably connected together by the intergrowth of proton conducting ceramic phases. The resulted PCFC single cell exhibits excellent performance (about 450 mW/cm 2 at about 500° C.) and stability (greater than about 50 days) at intermediate temperatures (less than or equal to about 600° C.). The present invention also relates to a two step method for forming a PCFC, and the resulting PCFC.
1. A method for fabricating a protonic ceramic fuel cell, comprising:
preparing an electrolyte precursor;
preparing an anode precursor;
preparing a cathode precursor; and
reactive sintering in a single step the electrolyte precursor, the anode precursor, and the cathode precursor with a proton conducting ceramic at a temperature of less than about 1400° C. to form the protonic ceramic fuel cell comprising an electrolyte, an anode and a cathode.
2. The method of claim 1 , wherein a material for the anode precursor is at least one of a BCZYYb, a BCZY63, a BZY20 and a NiO.
3. The method of claim 1 , wherein the anode is at least one of BCZYYb/Ni 1%, or BCZY63/Cu.
4. The method of claim 2 , wherein the material of the anode precursor is the BCZYYB and the NiO.
5. The method of claim 4 , wherein the material of the anode precursor comprises between about 40 wt. % to about 50 wt. % of the BCZYYb and between about 50 wt. % to about 60 wt. % of the NiO.
6. The method of claim 2 , wherein the material of the anode precursor is the BCZY63 and the NiO.
7. The method of claim 6 , wherein the material of the anode precursor comprises between about 40 wt. % to about 50 wt. % of the BCZY63 and between about 50 wt. % to about 60 wt. % of the NiO.
8. The method of claim 2 , wherein the material of the anode precursor is the BZY20 and the NiO.
9. The method of claim 8 , wherein the material of the anode precursor comprises between about 40 wt. % to about 50 wt. % of the BZY20 and between about 50 wt. % to about 60 wt. % of the NiO.
10. The method of claim 1 , wherein a material for the electrolyte precursor is at least one combination of a BCZYYb and a NiO, a BCZY63 and a CuO, or a BZY20 and a CuO.
11. The method of claim 1 , wherein a material of the electrolyte precursor is at least one of a BCZYYb/Ni, a BCZY63/CuO, or a BZY20/CuO.
12. The method of claim 1 , wherein a material for the cathode precursor is at least one of a BCZY63, a Fe 2 O 3 , a starch, a BCFZ, a BCFZY, and a BCZY27.
13. The method of claim 1 , wherein the cathode comprises a BCZY63/Fe 2 O 3 /starch, a BCZY63/Fe 2 O 3 /BCFZ, a BCFZY, or a BCFZ.
14. The method of claim 1 , further comprising infiltrating a perovskite-type oxide into the cathode precursor as a cathode nanoparticle at a temperature of between about 500° C. to about 900° C.
15. The method of claim 2 , wherein the material for the anode precursor is compressed to form a compressed precursor material anode.
16. The method of claim 10 , wherein the precursor material for the electrolyte precursor is mixed with a solvent to form a slurry.
17. The method of claim 12 , wherein the precursor material for the porous cathode bone is mixed with a solvent to form a slurry.
18. The method of claim 1 , further comprising:
compressing the anode precursor to form a compressed precursor anode;
mixing a solvent with the electrolyte precursor to form an electrolyte slurry;
applying the electrolyte slurry to the compressed precursor anode to form a half-cell;
mixing a solvent with the cathode precursor to form an cathode slurry; and
applying the cathode slurry to the half-cell.
19. The method of claim 1 , wherein an interface between the cathode and the electrolyte comprises no visible cracking.
20. The method of claim 1 , wherein the sintering does not result in cracking of an interface between the cathode and the electrolyte.