In-situ gelatinous triblock copolymer elastomers in polyurethane flexible foams
Combinations of gelatinous elastomer and polyurethane foam may be made by introducing a plasticized A-B-A triblock copolymer resin and/or an A-B diblock copolymer resin into a mixture of polyurethane foam forming components including a polyol and an isocyanate. The plasticized copolymer resin is polymerized to form the gelatinous elastomer in-situ while simultaneously polymerizing the polyol and the isocyanate to form polyurethane foam. The polyurethane reaction is exothermic and can generate sufficient temperature to melt the styrene-portion of the A-B-A triblock copolymer resin thereby extending the crosslinking and in some cases integrating the A-B-A triblock copolymer within the polyurethane polymer matrix. The combination has a marbled appearance. The gel component has higher heat capacity than polyurethane foam and thus has good thermal conductivity and acts as a heat sink. Another advantage of in situ gel-foam is that the gel component provides higher support factors compared to the base foam alone.
1. A method of forming a combination of gelatinous elastomer and open cell flexible polyurethane foam comprising:
introducing a copolymer resin selected from the group consisting of a triblock copolymer resin, a diblock copolymer resin, and combinations thereof, into a mixture of open cell flexible polyurethane foam forming components comprising a polyol and an isocyanate, where the copolymer resin is a triblock copolymer resin selected from the group consisting of styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-propylene-styrene (SEPS), styrene-ethylene-ethylene-propylene-styrene (SEEPS), and combinations thereof; and the diblock copolymer resin, if present, is selected from the group consisting of styrene-ethylene-propylene (SEP), styrene-ethylene-butylene (SEB), styrene-ethylene-ethylene (SEE), and combinations thereof; and
simultaneously polymerizing the copolymer resin to form the gelatinous elastomer in-situ while polymerizing the polyol and the isocyanate to form an open cell flexible polyurethane foam;
where the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam.
2. The method of claim 1 further comprising at least partially polymerizing the in-situ copolymer resin by heat produced by polymerizing the polyol and the polyisocyanate to form the open cell flexible polyurethane foam.
3. The method of claim 1 where the copolymer resin is a triblock copolymer resin and the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam.
4. The method of claim 1 where the copolymer resin is plasticized.
5. The method of claim 4 where the copolymer resin is formed by compounding a copolymer with at least one plasticizing oil and optionally a component selected from the group consisting of colorants; solvents; elastomeric diblock copolymer; antioxidants; antistatic agents; antimicrobial agents; flame retardants; ultraviolet stabilizers; phase change materials; surface tension modifiers; emulsifying agents; surfactants; fragrances; active hydrogen-containing components selected from the group consisting of primary amines, secondary amines, primary hydroxyls, secondary hydroxyls and combinations thereof; solid fillers; liquid fillers; and combinations thereof.
6. The method of claim 5 where the copolymer resin comprises a colorant selected from the group consisting of inorganic pigment, carbon black, organic colorant, organic dye, reactive colorant, reactive dye and combinations thereof, and where the colorant is present in an amount up to about 50 parts per hundred of the copolymer resin.
7. The method of claim 5 where the copolymer resin comprises a solvent selected from the group consisting of saturated acyclic aliphatic hydrocarbons, unsaturated acyclic aliphatic hydrocarbons, saturated cyclic aliphatic hydrocarbons, unsaturated cyclic aliphatic hydrocarbons, aromatic hydrocarbons, chlorinated hydrocarbons, alcohols, glycol ethers, ketones, aldehydes, epoxides, carboxylic acids, esters, glycol ether esters, fatty acids, phosphite esters, phosphate esters, dimethylsulfoxide, dimethylformamide, hexamethylphosphorotriamide, furan, water, methylene chloride, toluene, acetone and combinations thereof.
8. The method of claim 5 where the plasticizing oil is selected from the group consisting of a paraffinic mineral oil, naphthenic mineral oil, synthetic oil produced from polybutenes, polypropenes, polyterpenes, paraffins, isoparaffins, polyols, polyoxyalkyleneamines, glycols, soybean-based polyols, castor bean-based polyols, canola oil, safflower oil, sunflower oil, soybean oil, castor oil and combinations thereof, and the plasticizing oil is present in the range of from about 1 to about 1400 parts per hundred of copolymer resin.
9. The method of claim 1 where the copolymer resin further comprises an inert carrier selected from the group consisting of non-polar carriers, polar carriers, polyether polyol carriers, isocyanate/polyether prepolymers, liquid or solid fillers, liquid or solid flame retardants, and/or blowing agents.
10. The method of claim 1 where the gelatinous elastomer formed in-situ is at least partially crosslinked.
11. A method of forming a combination of gelatinous elastomer and open cell flexible polyurethane foam comprising:
introducing a copolymer resin selected from the group consisting of a triblock copolymer resin, a diblock copolymer resin, and combinations thereof, into a mixture of open cell flexible polyurethane foam forming components comprising a polyol and an isocyanate, where the copolymer resin is a triblock copolymer resin selected from the group consisting of styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-propylene-styrene (SEPS), styrene-ethylene-ethylene-propylene-styrene (SEEPS), and combinations thereof; and the diblock copolymer resin, if present, is selected from the group consisting of styrene-ethylene-propylene (SEP), styrene-ethylene-butylene (SEB), styrene-ethylene-ethylene (SEE), and combinations thereof, and at least partially polymerizing the in-situ copolymer resin by heat produced by polymerizing the polyol and the polyisocyanate to form the open cell flexible polyurethane foam; and
simultaneously polymerizing the copolymer resin to form the gelatinous elastomer in-situ while polymerizing the polyol and the isocyanate to form an open cell flexible polyurethane foam;
where the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam, where the copolymer resin is plasticized.
12. The method of claim 11 where the copolymer resin is a triblock copolymer resin and the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam.
13. The method of claim 11 where the copolymer resin is formed by compounding a copolymer with at least one plasticizing oil and optionally a component selected from the group consisting of colorants; solvents; elastomeric diblock copolymer; antioxidants; antistatic agents; antimicrobial agents; flame retardants; ultraviolet stabilizers; phase change materials; surface tension modifiers; emulsifying agents; surfactants; fragrances; active hydrogen-containing components selected from the group consisting of primary amines, secondary amines, primary hydroxyls, secondary hydroxyls and combinations thereof; solid fillers; liquid fillers; and combinations thereof.
14. The method of claim 11 where the gelatinous elastomer formed in-situ is at least partially crosslinked.
15. A method of forming a combination of gelatinous elastomer and open cell flexible polyurethane foam comprising:
introducing a copolymer resin selected from the group consisting of a triblock copolymer resin, a diblock copolymer resin, and combinations thereof, into a mixture of open cell flexible polyurethane foam forming components comprising a polyol and an isocyanate, where the copolymer resin is a triblock copolymer resin selected from the group consisting of styrene-ethylene-butylene-styrene (SEBS), styrene-ethylene-propylene-styrene (SEPS), styrene-ethylene-ethylene-propylene-styrene (SEEPS), and combinations thereof; and at least partially polymerizing the in-situ copolymer resin by heat produced by polymerizing the polyol and the polyisocyanate to form the open cell flexible polyurethane foam; and
simultaneously polymerizing the copolymer resin to form the gelatinous elastomer in-situ while polymerizing the polyol and the isocyanate to form an open cell flexible polyurethane foam;
where the copolymer resin is added in the range of about 0.1 to about 200 parts per hundred of the polyol component of open cell flexible polyurethane foam.
16. The method of claim 15 where the copolymer resin is plasticized.
17. The method of claim 15 where the copolymer resin is formed by compounding a copolymer with at least one plasticizing oil and optionally a component selected from the group consisting of colorants; solvents; elastomeric diblock copolymer; antioxidants; antistatic agents; antimicrobial agents; flame retardants; ultraviolet stabilizers; phase change materials; surface tension modifiers; emulsifying agents; surfactants; fragrances; active hydrogen-containing components selected from the group consisting of primary amines, secondary amines, primary hydroxyls, secondary hydroxyls and combinations thereof; solid fillers; liquid fillers; and combinations thereof.
18. The method of claim 1 where the gelatinous elastomer formed in-situ is at least partially crosslinked.