Pesticidal compositions and processes related thereto
View Patent ↗This document discloses molecules having the following formula (“Formula One”): and processes related thereto.
1. A composition comprising a molecule according to
wherein
(a) A is
(b) R1 is H;
(c) R2 is H;
(d) R3 is H;
(e) R4 is H, Cl, Br, unsubstituted C 1 -C 6 alkyl, or unsubstituted C 2 -C 6 alkenyl;
(f) R5 is H or Cl;
(g) R6 is H, substituted or unsubstituted C 1 -C 6 alkyl, unsubstituted C 2 -C 6 alkenyl, unsubstituted C 3 -C 10 cycloalkyl, (C 1 -C 6 alkyl)OC(═O)(C 1 -C 6 alkyl), or C 1 -C 6 alkyl-(C 3 -C 10 cyclohaloalkyl), wherein each said R6, which is substituted, has one or more substituents selected from the group consisting of CN and C 3 -C 10 cycloalkyl;
(h) R7 is O or S;
(i) R8 is substituted or unsubstituted C 1 -C 6 alkyl, unsubstituted C 2 -C 6 alkenyl, substituted or unsubstituted C 3 -C 10 cycloalkyl, OR9, N(R9) 2 , or SR9, wherein each said R8, which is substituted, has one or more substituents selected from the group consisting of F, Cl, Br, I, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 haloalkyloxy, N(R9)S(O) n R9, OR9, and S(O) n R9;
(j) R9 is (each independently) H, substituted or unsubstituted C 1 -C 6 alkyl, unsubstituted C 2 -C 6 alkenyl, S(O) n C 1 -C 6 alkyl, N(C 1 -C 6 alkyl) 2 , wherein each said R9, which is substituted, has one or more substituents selected from the group consisting of F, Cl, Br, I, and S(O) n C 1 -C 6 alkyl;
(k) n is 0, 1, or 2; and
(l) X is CR n1 where R n1 is H or F.
2. A composition according to claim 1 wherein said molecule is one of the following molecules
Com-
pound
No.
Structure
32
55
57
58
59
60
64
67
70
73
74
75
76
79
80
86
90
95
97
98
101
102
103
105
111
115
121
122
123
124
125
133
134
136
137
141
142
143
144
145
150
153
154
155
157
158
159
160
161
162
163
164
165
166
168
172
173
174
175
176
177
179
181
182
183
185
186
187
188
189
190
191
192
193
194
195
196
199
200
202
203
204
205
206
207
208
209
210
211
212
213
214
215
217
218
219
221
222
223
224
225
227
229
235
236
237
238
239
241
242
243
244
249
253
258
259
260
262
263
270
275
277
278
282
283
284
286
292
300
301
302
303
304
306
307
311
314
315
317
320
321
322
323
324
325
326
329
330
331
332
333
334
335
336
337
338
339
341
342
344
345
346
350
351
353
361
362
363
364
365
366
371
372
382
385
386
389
392
393
394
397
406
412
413
427
428
429
432
439
450
452
453
454
455
457
458
459
460
461
463
464
465
466
467
469
471
472
478
479
480
482
486
490
491
492
493
494
495
505
506
507
508
519
522
534
536
537
538
540
544
549
550
551
552
553
554
555
590
591
592
3. A composition according to claim 1 wherein said molecule said R8 is (unsubstituted C 1 -C 6 alkyl)-S(O) n -(substituted C 1 -C 6 alkyl) wherein said substituents on said substituted alkyl is selected from the group consisting of F, Cl, Br, and I.
4. A composition according to claim 1 wherein said molecule said R4 is H, Cl, CH 3 , CH 2 CH 3 , or CH═CH 2 .
5. A composition according to claim 1 wherein said molecule said R6 is C 1 -C 6 alkyl.
6. A composition according to claim 1 wherein said molecule said R6 is H, CH 3 , or CH 2 CH 3 .
7. A composition according to claim 1 wherein said molecule said R6 is methyl or ethyl.
8. A composition according to claim 1 wherein said molecule said R8 is selected from (substituted or unsubstituted C 1 -C 6 alkyl)-S(O) n -(substituted or unsubstituted C 1 -C 6 alkyl) wherein said substituents on said substituted alkyls are selected from F, Cl, Br, or I.