Methods of fabricating a polycrystalline diamond body with a sintering aid/infiltrant at least saturated with non-diamond carbon and resultant products such as compacts
View Patent ↗Embodiments of the invention relate to methods of fabricating a polycrystalline diamond compacts and applications for such polycrystalline diamond compacts. In an embodiment, a method of fabricating a polycrystalline diamond body includes mechanically milling non-diamond carbon and a sintering aid material for a time and aggressiveness sufficient to form a plurality of carbon-saturated sintering aid particles and sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form the polycrystalline diamond body.
1. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains having diamond-to-diamond bonding therebetween, the polycrystalline diamond table formed by a method including:
mechanically milling non-diamond carbon and a sintering aid material for a time and an aggressiveness sufficient to form a plurality of the carbon-saturated sintering aid particles; and
sintering the plurality of diamond particles in the presence of a plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table, the carbon-saturated sintering aid particles catalyzing formation of diamond-to-diamond bonding between the plurality of diamond particles to form the polycrystalline diamond table.
2. The polycrystalline diamond compact of claim 1 wherein mechanically milling non-diamond carbon and a sintering aid material for a time and aggressiveness sufficient to form a plurality of carbon-saturated sintering aid particles includes ball milling, attritor milling, horizontal ball milling, or high-energy ball milling the non-diamond carbon and the sintering aid material.
3. The polycrystalline diamond compact of claim 1 wherein the time is less than about 2200 hours.
4. The polycrystalline diamond compact of claim 1 wherein the time is about 100 hours to about 1100 hours.
5. The polycrystalline diamond compact of claim 1 wherein the time is about 150 hours to about 700 hours.
6. The polycrystalline diamond compact of claim 1 wherein the plurality of sintering aid particles includes at least one member selected from the group consisting of cobalt, nickel, iron, copper, aluminum, titanium, tungsten, niobium, zirconium, tantalum, silicon, and boron.
7. The polycrystalline diamond compact of claim 1 wherein the plurality of sintering aid particles includes at least one member selected from the group consisting of copper, aluminum, and tungsten.
8. The polycrystalline diamond compact of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of greater than about 0.01 atomic %.
9. The polycrystalline diamond compact of claim 1 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 10 atomic % to about 30 atomic %.
10. The polycrystalline diamond compact of claim 9 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 5 atomic % to about 25 atomic %.
11. The polycrystalline diamond compact of claim 9 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 1 atomic % to about 10 atomic %.
12. The polycrystalline diamond compact of claim 9 wherein the plurality of carbon-saturated sintering aid particles exhibit a carbon content of about 25 atomic % to about 30 atomic %.
13. The polycrystalline diamond compact of claim 1 wherein the non-diamond carbon includes at least one member selected from the group consisting of lamp black, graphite, carbon-12 graphite, carbon-13 graphite, carbon-14 graphite, carbon nanotubes, graphene, amorphous carbon, amorphous carbon-12, amorphous carbon-13, amorphous carbon-14, carbon-12, carbon-13, carbon-14, and fullerenes.
14. The polycrystalline diamond compact of claim 1 wherein the method further includes:
prior to the act of sintering, assembling the plurality of carbon-saturated sintering aid particles between the plurality of diamond particles and a substrate to form an assembly; and
wherein sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table includes subjecting the assembly to a high-pressure/high-temperature process effective to infiltrate the plurality of diamond particles with a carbon-saturated infiltrant from the plurality of carbon-saturated sintering aid particles to sinter the plurality of diamond particles and form the polycrystalline diamond table that bonds to the substrate.
15. The polycrystalline diamond compact of claim 14 wherein the method further includes:
removing the polycrystalline diamond table from the substrate;
leaching the polycrystalline diamond table to at least partially remove sintering aid material, provided from the carbon-saturated infiltrant, from the polycrystalline diamond table to form an at least partially leached polycrystalline diamond table; and
bonding the at least partially leached polycrystalline diamond table to an additional substrate to form an additional polycrystalline diamond compact.
16. A polycrystalline diamond compact, comprising:
a substrate; and
a polycrystalline diamond table bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains having diamond-to-diamond bonding therebetween, the polycrystalline diamond table formed by a method including:
mechanically milling non-diamond carbon and a sintering aid material for a time sufficient to form a plurality of carbon-saturated sintering aid particles;
mixing the plurality of carbon-saturated sintering aid particles and a plurality of diamond particles to form a mixture; and
subjecting the mixture to a high-pressure/high-temperature process effective to sinter the plurality of diamond particles to form the polycrystalline diamond body.
17. The polycrystalline diamond compact of claim 16 wherein the time is about 150 hours to about 700 hours.
18. The polycrystalline diamond compact of claim 16 wherein the plurality of sintering aid particles includes at least one member selected from the group consisting of cobalt, nickel, iron, copper, aluminum, titanium, tungsten, niobium, zirconium, tantalum, silicon, and boron.
19. The polycrystalline diamond compact of claim 16 wherein the non-diamond carbon includes at least one member selected from the group consisting of lamp black, graphite, carbon-12 graphite, carbon-13 graphite, carbon-14 graphite, carbon nanotubes, graphene, amorphous carbon, amorphous carbon-12, amorphous carbon-13, amorphous carbon-14, carbon-12, carbon-13, carbon-14, and fullerenes.
20. A polycrystalline diamond compact, comprising:
a substrate;
a polycrystalline diamond table bonded to the substrate, the polycrystalline diamond table including a plurality of diamond grains having diamond-to-diamond bonding therebetween, the polycrystalline diamond table formed by a method including:
mechanically milling non-diamond carbon with a sintering aid material for a time sufficient to form a plurality of carbon-saturated sintering aid particles;
sintering a plurality of diamond particles in the presence of the plurality of carbon-saturated sintering aid particles to form a polycrystalline diamond table, wherein the carbon-saturated sintering aid particles catalyzes formation of diamond-to-diamond bonding between the plurality of diamond particles used to form the polycrystalline diamond table;
at least partially leaching a sintering aid material from the polycrystalline diamond table to form an at least partially leached polycrystalline diamond table;
forming an assembly including the at least partially leached polycrystalline diamond table positioned at least proximate to a substrate; and
subjecting the assembly to a high-pressure/high-temperature process effective to infiltrate the at least partially leached polycrystalline diamond table with an infiltrant and bond the infiltrated polycrystalline diamond table to the substrate.