Low compression golf balls containing cores made of plasticized thermoplastic compositions
View Patent ↗Low compression multi-piece golf balls having a solid core comprising at least one layer made of a plasticized thermoplastic composition are provided. Preferably, the ball has a compression of less than 60 and more preferably less than 50. The ball includes a cover in addition to the core sub-assembly. For example, two-piece and three-piece golf balls may be made. The plasticized thermoplastic composition preferably comprises: a) ethylene acid copolymer, b) plasticizer, and c) cation source. Preferably, a fatty acid ester such as butyl oleate is used as the plasticizer. In two-layered core constructions, the outer core layer is preferably formed from a thermoset composition such as polybutadiene rubber. The core layers may have different hardness levels. The core structure and resulting ball have relatively good resiliency at given compressions.
1. A golf ball, comprising:
i) a core comprising a thermoplastic composition, the core haying an outer surface hardness (H core surface ) and a center hardness (H core center ), the H core surface being greater than the H core center to provide a positive hardness gradient, the thermoplastic composition comprising;
a) an acid copolymer of ethylene and an α, β-unsaturated carboxylic acid, optionally including a softening monomer selected from the group consisting of alkyl acrylates and methacrylates;
b) plasticizer; and
c) a cation source present in an amount sufficient to neutralize from about 0 to about 100% of all acid groups present in the composition; and
d) a non-acid polymer, wherein the non-acid polymer is an alkyl acrylate rubber selected from ethylene-alkyl acrylates and ethylene-alkyl methacrylates and is present in an amount of greater than 50 wt.%, based on the combined weight of the acid copolymer and the non-acid polymer
and
ii) a cover disposed about the core, wherein the ball has a compression of less than 60.
2. The golf ball of claim 1 , wherein the acid copolymer of ethylene and an α, β-unsaturated carboxylic acid does not include a softening monomer, and wherein the acid is selected from acrylic acid and methacrylic acid and is present in the acid copolyMer in an amount of from about 15 to about 30 weight %, based on the total weight of the acid copolymer.
3. The golf ball of claim 1 , wherein the thermoplastic material comprises about 3 to about 50% by, weight plasticizer.
4. The, golf ball of claim 3 , wherein the plasticizer is a fatty acid ester.
5. The golf ball of claim 4 , wherein the fatty acid ester is selected from the group consisting of methyl oleate, ethyl oleate, propyl oleate, butyl oleate, and octyl oleate, and mixtures thereof.
6. The golf ball of claim 1 , wherein the thermoplastic composition comprises an acid copolymer of ethylene and an α, β-unsaturated carboxylic acid containing acid groups such that 70% or less of the acid groups are neutralized.
7. The golf ball of claim 1 , wherein the acid copolymer of ethylene and an α, β-unsaturated carboxylic acid contains acid groups such that greater than 70% of the acid groups are neutralized.
8. The golf ball of claim 7 , wherein 90% or greater of the acid groups are neutralized.
9. The golf ball of claim 7 , wherein the acid copolymer of ethylene and an α, β-unsaturated carboxylic acid is selected from the group consisting of ethylene/(meth) acrylic acid/n-butyl acrylate; ethylene/(meth)acrylic acid/ethyl acrylate; ethylene/(meth)acrylic acid/methyl acrylate; ethylene/(meth),acrylic acid/n-butyl acrylate; and ethylene/(meth)acrylic acid/isobutyl acrylate copolymers.
10. The golf ball of claim 1 , wherein the core has a diameter in the range of about 1.475 to about 1.600 inches.
11. The golf ball of claim 1 , wherein the H core center is in the range of about 10 Shore C to about 70 Shore C and the H core surface is in the range of about 15 Shore C to about 90 Shore C.
12. The golf ball of claim 1 , wherein the H core center is in the range of about 30 Shore C to about 69 Shore C and the H core surface is in the range of about 31 Shore C to about 70 Shore C.
13. The golf ball of claim 1 , wherein the ball has a compression in the range of about 25 to about 55.