High Molecular Weight Steric Barrier for Electrophoretic Particles
The present invention is directed to a pigment particle comprising a core pigment particle the surface of which is covered by a barrier layer formed of a polymer having an average molecular weight of more than about 200 kDa. Such pigment particle used in an electrophoretic fluid can reduce residual image, and thus providing a method for improving performance of an electrophoretic display.
1 . A method for improving performance of an electrophoretic display, comprising:
(a) obtaining charged pigment particles each comprising a core pigment particle covered by a barrier layer formed of a polymer having an average molecular weight of more than 200 kDa,
(b) dispersing the pigment particles of (a) in a solvent or solvent mixture to form an electrophoretic display fluid,
(c) enclosing the electrophoretic fluid between two electrode plates to form an electrophoretic display, and
(d) switching the electrophoretic display from one image state to another image state,
whereby a residual image of the electrophoretic display is reduced.
2 . The method of claim 1 , wherein the average molecular weight of the polymer is more than about 235 kDa.
3 . The method of claim 2 , wherein the average molecular weight of the polymer is more than about 300 kDa.
4 . The method of claim 1 , wherein the core pigment particle is an inorganic pigment particle.
5 . The method of claim 1 , wherein the core pigment particle is an organic pigment particle.
6 . The method of claim 1 , wherein the polymer is polyethylene, polystyrene, polymethylmethacrylate, polybutylmethacrylate, polylaurylmethacrylate, polyvinylpyrrolidone, a polymer of perfluorinated monomer, or any combination thereof.
7 . The method of claim 1 , wherein the electrophoretic display fluid contains only one type of charged pigment particles.
8 . The method of claim 1 , wherein the electrophoretic display fluid contains two types of charged pigment particles, and at least one of the two types is the charged pigment particles of step (a).
9 . The method of claim 8 , wherein the two types of charged pigment particles are oppositely charged and of contrasting colors.
10 . The method of claim 9 , wherein the two types of charged pigment particles are black and white, respectively.
11 . The method of claim 1 , wherein the electrophoretic display fluid further comprises a charge control agent.