Battery and battery pack
Batteries and battery packs are provided. In one embodiment, the battery includes a positive electrode, a negative electrode, and an electrolyte including a fluidic electrolyte and a non-fluidic electrolyte. The fluidic electrolyte is configured to be imaged as a void image in a secondary electron image and a reflection electron image obtained by energy dispersive X-ray spectroscopy, and the non-fluidic electrolyte is configured to be imaged in the secondary electron image and the reflection electron image with a non-fluidic electrolyte contrast different from a contrast associated with a member selected from the group consisting of a solid current collector, an active material, a conductive material, a binding material and a separator.
1. A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte including a fluidic electrolyte and a non-fluidic electrolyte, the fluidic electrolyte configured to be imaged as a void image in a secondary electron image and a reflection electron image obtained by energy dispersive X-ray spectroscopy, and the non-fluidic electrolyte configured to be imaged in the secondary electron image and the reflection electron image with a non-fluidic electrolyte contrast different from a contrast associated with a member selected from the group consisting of a solid current collector, an active material, a conductive material, a binding material and a separator, wherein a content of the non-fluidic electrolyte is greater than 0 up to 6% by volume with respect to the electrolyte.
2. The battery according to claim 1 , wherein the non-fluidic electrolyte is present between the positive electrode and the negative electrode, and the fluidic electrolyte is present at least in a void inside active material layers of the positive electrode and the negative electrode.
3. The battery according to claim 2 , wherein the fluidic electrolyte is present between the positive electrode and the negative electrode.
4. The battery according to claim 1 , wherein the separator is interposed between the positive electrode and the negative electrode, and the non-fluidic electrolyte is present between the separator and at least one of the positive electrode and the negative electrode.
5. The battery according to claim 1 , wherein the electrolyte includes an electrolyte salt, and wherein the electrolyte salt includes an imide salt compound expressed by Chem. 1,
M + [(ZY) 2 N] − (Chem. 1)
where M + represents a monovalent cation, Y represents SO 2 or CO, and Z represents a fluorine atom.
6. The battery according to claim 5 , wherein at least one Z is a fluorine atom.
7. The battery according to claim 1 , wherein the non-fluidic electrolyte comprises a polymeric material, and a weight-average molecular weight of the polymeric material is 500,000 or more and 1,000,000 or less.
8. The battery according to claim 7 , wherein the polymeric material is at least one of polyvinylidene fluoride and polyacrylonitrile.
9. The battery according to claim 1 , wherein an active material of the positive electrode includes a lithium composite phosphate having an olivine type structure expressed by Chem. I,
Li a M1 b PO 4 (Chem. I)
where M1 represents at least one element selected from group II to group XV, and a and b represent values within ranges of 0≦a≦2.0 and 0.5≦b≦2.0.
10. The battery according to claim 9 , wherein M1 includes iron.
11. A battery pack comprising:
the battery according to claim 1 ;
a control unit that controls the battery; and
an exterior package in which the battery is accommodated.
12. A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte including a fluidic electrolyte and a non-fluidic electrolyte, the fluidic electrolyte configured to be imaged as a void image in a secondary electron image and a reflection electron image obtained by energy dispersive X-ray spectroscopy, and the non-fluidic electrolyte configured to be imaged in the secondary electron image and the reflection electron image with a non-fluidic electrolyte contrast different from a contrast associated with a member selected from the group consisting of a solid current collector, an active material, a conductive material, a binding material and a separator, wherein the non-fluidic electrolyte includes an electrolytic solution including a solvent and an electrolyte salt, and wherein a content of the electrolytic solution in the non-fluidic electrolyte is 90 to 99% by mass.
13. A battery comprising:
a positive electrode;
a negative electrode; and
an electrolyte including a fluidic electrolyte and a non-fluidic electrolyte, the fluidic electrolyte configured to be imaged as a void image in a secondary electron image and a reflection electron image obtained by energy dispersive X-ray spectroscopy, and the non-fluidic electrolyte configured to be imaged in the secondary electron image and the reflection electron image with a non-fluidic electrolyte contrast different from a contrast associated with a member selected from the group consisting of a solid current collector, an active material, a conductive material, a binding material and a separator,
wherein a content of the non-fluidic electrolyte is greater than 0 up to 6% by volume with respect to the electrolyte, and
wherein the non-fluidic electrolyte includes an electrolytic solution including a solvent and an electrolyte salt, and wherein a content of the electrolytic solution in the non-fluidic electrolyte is 90 to 99% by mass.
14. An apparatus comprising the battery according to claim 1 , wherein the apparatus is selected from the group consisting of an electronic apparatus, an electrically driven vehicle, an electrical storage device, and an electric power system.
15. An apparatus comprising the battery according to claim 12 , wherein the apparatus is selected from the group consisting of an electronic apparatus, an electrically driven vehicle, an electrical storage device, and an electric power system.
16. An apparatus comprising the battery according to claim 13 , wherein the apparatus is selected from the group consisting of an electronic apparatus, an electrically driven vehicle, an electrical storage device, and an electric power system.
17. The battery according to claim 12 , wherein the non-fluidic electrolyte is present between the positive electrode and the negative electrode, and the fluidic electrolyte is present at least in a void inside active material layers of the positive electrode and the negative electrode.
18. The battery according to claim 13 , wherein the non-fluidic electrolyte is present between the positive electrode and the negative electrode, and the fluidic electrolyte is present at least in a void inside active material layers of the positive electrode and the negative electrode.
19. The battery according to claim 12 , wherein the separator is interposed between the positive electrode and the negative electrode, and the non-fluidic electrolyte is present between the separator and at least one of the positive electrode and the negative electrode.
20. The battery according to claim 13 , wherein the separator is interposed between the positive electrode and the negative electrode, and the non-fluidic electrolyte is present between the separator and at least one of the positive electrode and the negative electrode.
21. The battery according to claim 12 , wherein the electrolyte includes an electrolyte salt, and wherein the electrolyte salt includes an imide salt compound expressed by Chem. 1,
M + [(ZY) 2 N] − (Chem. 1)
where M + represents a monovalent cation, Y represents SO 2 or CO, and Z represents a fluorine atom.
22. The battery according to claim 13 , wherein the electrolyte includes an electrolyte salt, and wherein the electrolyte salt includes an imide salt compound expressed by Chem. 1,
M + [(ZY) 2 N] − (Chem. 1)
where M + represents a monovalent cation, Y represents SO 2 or CO, and Z represents a fluorine atom.
23. The battery according to claim 12 , wherein the non-fluidic electrolyte comprises a polymeric material, and a weight-average molecular weight of the polymeric material is 500,000 or more and 1,000,000 or less.
24. The battery according to claim 13 , wherein the non-fluidic electrolyte comprises a polymeric material, and a weight-average molecular weight of the polymeric material is 500,000 or more and 1,000,000 or less.
25. The battery according to claim 12 , wherein an active material of the positive electrode includes a lithium composite phosphate having an olivine type structure expressed by Chem. I,
Li a M1 b PO 4 (Chem. I)
where M1 represents at least one element selected from group II to group XV, and a and b represent values within ranges of 0≦a≦2.0 and 0.5≦b≦2.0.
26. The battery according to claim 13 , wherein an active material of the positive electrode includes a lithium composite phosphate having an olivine type structure expressed by Chem. I,
Li a M1 b PO 4 (Chem. I)
where M1 represents at least one element selected from group II to group XV, and a and b represent values within ranges of 0≦a≦2.0 and 0.5≦b≦2.0.
27. A battery pack comprising:
the battery according to claim 12 ;
a control unit that controls the battery; and
an exterior package in which the battery is accommodated.
28. A battery pack comprising:
the battery according to claim 13 ;
a control unit that controls the battery; and
an exterior package in which the battery is accommodated.