Articles comprising metal, hard material, and an inoculant
View Patent ↗Methods of forming at least a portion of an earth-boring tool include providing particulate matter including a hard material in a mold cavity, melting a metal and the hard material to form a molten composition comprising a eutectic or near-eutectic composition of the metal and the hard material, casting the molten composition to form the at least a portion of an earth-boring tool within the mold cavity, and providing an inoculant within the mold cavity. Methods of forming a roller cone of an earth-boring rotary drill bit include forming a molten composition, casting the molten composition within a mold cavity, solidifying the molten composition to form the roller cone, and controlling grain growth using an inoculant as the molten composition solidifies. Articles including components of earth-boring tools are fabricated using such methods.
1. An article comprising at least a portion of an earth-boring tool, the article comprising a eutectic or near-eutectic composition including a metal phase, a hard material phase, and an inoculant, wherein the hard material phase comprises at least a portion of the inoculant, and wherein the metal phase comprises at least a portion of the inoculant.
2. The article of claim 1 , wherein the inoculant comprises at least one of a transition metal aluminate, a transition metal metasilicate, and a transition metal oxide.
3. The article of claim 1 , wherein the eutectic or near-eutectic composition comprises from about 0.5% to about 5% inoculant by weight.
4. The article of claim 1 , wherein the metal phase comprises at least one of cobalt, iron, nickel, and alloys thereof.
5. The article of claim 1 , wherein the hard material phase comprises a ceramic compound selected from the group consisting of carbides, borides, oxides, nitride, and mixtures thereof.
6. The article of claim 1 , further comprising a composite microstructure that includes regions of the metal phase and regions of the hard material phase.
7. The article of claim 1 , wherein the hard material phase comprises a metal carbide phase including at least one of an MC phase and an M 2 C phase, wherein M is at least one metal element and C is carbon.
8. An article comprising at least a portion of an earth boring tool, the article comprising: a eutectic or near eutectic composition comprising a metal and a hard material, at least one mixed metal carbide phase comprising at least one of an M 6 C phase and an M 12 C phase, wherein M is at least one metal element, and C is carbon; and an inoculant, wherein the at least one mixed metal carbide phase comprises an eta phase of W x Co y C, wherein x is from about 0.5 to about 6 and is from about 0.5 to about 6.
9. The article of claim 8 , wherein the eutectic or near eutectic composition comprises from about 40% to about 90% cobalt or cobalt-based alloy by weight and from about 0.5% to about 3.8% carbon by weight, and wherein a balance of the mixture is at least substantially comprised of tungsten.
10. The article of claim 8 , wherein the inoculant comprises a material selected from the group consisting of transition metal aluminates, transition metal metasilicates, and transition metal oxides.
11. The article of claim 8 , wherein the inoculant comprises a material selected from the group consisting of cobalt aluminate, cobalt metasilicate, and cobalt oxide.