Process for producing dialkyl carbonates
View Patent ↗The present invention relates to a continuous process for producing lower dialkyl carbonates as a main product and alkylene glycol as a by-product by transesterification of a cyclic alkylene carbonate (e.g. ethylene or propylene carbonate) with lower alkyl alcohols in the presence of a catalyst and also the necessary purification of the dialkyl carbonate in a subsequent process step. For optimization of the economic efficiency and energy efficiency of the process, additional devices are used for intermediate heating of the internal liquid streams within the apparatus.
1. A process comprising preparing continuously both dialkyl carbonate of the formula
(R 1 O) 2 CO,
in which R 1 is a straight-chain or branched C1-C4-alkyl and alkylene glycol of the formula
HO—R 2 —OH,
in which R 2 is a C 2 -C 4 -alkylene
by transesterifying cyclic alkylene carbonate with an alkyl alcohol of the formula
R 1 OH,
in which R 1 is as defined above
in the presence of a catalyst in a transesterification column, by first purifying the alkylene glycol in a workup column producing a heat of condensation, wherein the heat of condensation of the alkylene glycol workup column is recovered and used directly or indirectly to vaporize at least one stream containing alkyl alcohol fed to the transesterification column.
2. The process for preparing dialkyl carbonate as claimed in claim 1 , wherein the heat of condensation of the alkylene glycol workup column is used to preheat a feed in a dialkyl carbonate workup column or to vaporize the alkyl alcohol for the transesterification column.
3. The process as claimed in claim 1 , wherein the transesterification column has a reaction zone having an upper, a middle and a lower section, and a stripping section beneath the reaction zone.
4. The process for preparing dialkyl carbonate as claimed in claim 3 , wherein the transesterification is conducted in countercurrent in the presence of a catalyst in the transesterification column in such a way that alkylene carbonate stream is introduced into the upper section of the reaction zone of the column and a dialkyl carbonate-containing alkyl alcohol stream having a dialkyl carbonate content of 0.2% to 30% by weight into the middle or lower section of the reaction zone of the transesterification column.
5. The process for preparing dialkyl carbonate as claimed in claim 4 , wherein the transesterification column is supplied with a further stream comprising alkyl alcohol, and wherein the further stream of alkyl alcohol is introduced beneath the dialkyl carbonate-containing alkyl alcohol stream.
6. The process for preparing dialkyl carbonate as claimed in claim 1 , wherein the cyclic alkylene carbonate used is ethylene carbonate or propylene carbonate, and the alkyl alcohol used is methanol or ethanol.
7. The process for preparing dialkyl carbonate as claimed in claim 1 , wherein the temperature in the reaction zone is in the range from 20 to 200° C. and the pressure is in the range from 0.2 to 20 bar.