Energy efficient, temporary shear thinning siloxane lubricants and method of using
View Patent ↗A method of using energy-efficient lubricant compositions to reduce wear between two surfaces exposed to a high shear condition is provided. The lubricant compositions comprise polysiloxane base oils having alkyl, aryl, or a combination of alkyl and aryl functionality. The polysiloxane base oils may be defined according to the formula: wherein R, and R′ are independently selected, such that R is an alkyl group having between 1-3 carbon atoms; R′ is an alkyl or aryl group having between 6 to 20 carbon atoms; and m and n are integers, such that 25<(m+n)<500 and the ratio of m/(m+n) is greater than 0.05 and less than 1.00.
1. A method of reducing the film friction that occurs between two mechanical surfaces when the surfaces are moved relative to one another, said method comprising providing a lubricant composition between the two mechanical surfaces, the lubricant composition comprising at least one polysiloxane base oil; the polysiloxane base oil corresponding to the structural formula
and exhibiting a coefficient of friction that is less than 0.07 at a temperature of at least 303 K with a EHL film thickness of 10 nm or more;
wherein R and R′ are independently selected, such that R is an alkyl group having between 1-3 carbon atoms; R′ is an alkyl group having between 6-20 carbon atoms; m is an integer, and n is an integer with the provisos that 25<(m+n)<500 and 0.05<m/(m+n)<1.00.
2. The method according to claim 1 , wherein in the polysiloxane base oil R is a methyl group and R′ is an alkyl group with between 6-12 carbon atoms; and 50<(m+n)<500 and 0.05<m/(m+n)<0.30.
3. The method according to claim 1 , wherein the polysiloxane base oil corresponds to the structural formula:
4. The method according to claim 1 , wherein the lubricant composition comprises a second polysiloxane base oil including an aryl group.
5. The method according to claim 4 , wherein the polysiloxane base oil has the structure:
and the second polysiloxane base oil has the structure:
6. The method according to claim 1 , wherein the polysiloxane base oil exhibits an initial viscosity (η o ) that decreases to an effective viscosity (η eff ) when exposed to the high shear condition; wherein the ratio of η eff /η o is between 0.99 and 0.05.
7. The method according to claim 1 , wherein the polysiloxane base oil exhibits a total mass in excess of 10,000 g/mol.
8. The method according to claim 1 , wherein the lubricant composition further comprises at least one functional additive selected as one from the group of extreme pressure additives, anti-wear additives, antioxidants, antifoams, and corrosion inhibitors.
9. The method according to claim 1 , wherein the two surfaces represent an elastohydrodynamic lubrication (EHL) contact point in a machine element.
10. The method according to claim 9 , wherein the machine element is a sliding bearing, a rolling element bearing, a gear, a cam and a cam follower, or a traction drive, and optionally, the two surfaces are metal surfaces.
11. The method according to claim 1 , wherein the lubricant provides one or more of the following: an EHL film thickness between the two surfaces that is less than 2000 nm, a coefficient of film friction less than 0.05 at a temperature of 398 K, and a coefficient of friction that is less than 0.25 at a shear rate less than 1,000 sec −1 .
12. A method of reducing film friction between rolling or sliding surfaces in a machine element, the method comprising the steps of:
providing a machine element having a first surface and a second surface; the first and second surfaces representing an elastohydrodynamic lubrication (EHL) contact point in the machine element;
providing a lubricant composition between the first surface and second surface, the lubricant composition comprising:
at least one polysiloxane base oil, free of non-silicone base oil, corresponding to the structural formula:
wherein R and R′ are independently selected, such that R is an alkyl group having between 1-3 carbon atoms; R′ is an alkyl group having between 6-20 carbon atoms; m is an integer, and n is an integer with the provisos that 25<(m+n)<500 and 0.05<m/(m+n)<1.00; and
allowing the first surface to roll or slide past the second surface such that the lubricant composition is exposed to a high shear condition defined by a shear rate that is between 1,000 sec −1 and 100,000,000 sec −1 ;
wherein the lubricant composition exhibits a coefficient of friction that is less than 0.07 at a temperature of at least 303 K with a film thickness of 10 nm or more.
13. The method according to claim 12 , wherein in the polysiloxane base oil R is a methyl group and R′ is an alkyl group with between 6-12 carbon atoms; and 50<(m+n)<500 and 0.05<m/(m+n)<0.30.
14. The method according to claim 12 , wherein the polysiloxane base oil corresponds to the structural formula:
15. The method according to claim 12 , wherein the lubricant composition further comprises a second polysiloxane base oil including an aryl group.
16. The method according to claim 15 , wherein the polysiloxane base oil has the structure:
and the second polysiloxane base oil has the structure:
17. The method according to claim 12 , wherein the machine element is a rolling element bearing, a gear, a cam and a cam follower, or a traction drive.
18. The method according to claim 12 , wherein lubricant composition provides at least one of the following: an EHL film thickness between the first surface and second surface that is 2000 nm or less at a temperature of 303 K and 1000 nm or less at a temperature of 398 K; or a coefficient of friction less than 0.05 at a temperature of 398 K.