Process for preparing a hydrowax
The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800° C.; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen-containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt %, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.
1. A process for preparing a dewaxed product comprising the steps of:
(a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in a range of from 550 to 800° C. and a ratio of hydrocarbons boiling in a range of from 370-543° C. to hydrocarbons boiling in a range of from 550-800° C. of less than 25;
(b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen-containing gas under hydrotreating conditions to obtain a hydrotreated product;
(c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrodenitrification catalyst comprising (i) Mo, (ii) Ni and/or Co, and (iii) alumina and a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, wherein the hydrodenitrification catalyst is arranged upstream of the hydrocracking catalyst, wherein the hydrocracking catalyst comprises zeolite Y in an amount of from 18 to 30 wt % and amorphous silica-alumina in an amount of less than 50 wt %, based on the total weight of the hydrocracking catalyst, wherein the zeolite Y has a Si/Al ratio in the range of from 8-50, and wherein a volume ratio of the hydrotreating catalyst as used in step (b) to the hydrocracking catalyst is in the range of from 2 to 4; and
(d) recovering the hydrocracked product as obtained in step (c), wherein at least part of hydrocarbons contained in the hydrocracked product is recycled to step (b) and wherein a hydrowax product is recovered from the hydrocracked product; and
(e) contacting the hydrowax product with a dewaxing catalyst, comprising metallosilicate crystallites, a binder, and a hydrogenation component, under catalytic dewaxing conditions to yield the dewaxed product having a pour point of at least 10° C. less than a pour point of the hydrowax product.
2. A process according to claim 1 , wherein the hydrocarbonaceous feedstock as provided in step (a) contains more than 8% by weight of hydrocarbons boiling in a range of from 550 to 800° C.
3. A process according to claim 1 , wherein the hydrocarbonaceous feedstock as provided in step (a) contains between 8-30% by weight of hydrocarbons boiling in a range of from 560 to 800° C.
4. A process according to claim 1 , wherein the hydrocracking catalyst also comprises an amorphous silica-alumina in an amount of less than 45 wt %, based on the total weight of the hydrocracking catalyst.
5. A process according to claim 1 , in which the hydrotreating conditions in steps (b) comprise a temperature in a range of from 250-480° C., a pressure in the range of from 30-250 bar, and a weight hourly space velocity in a range of from 0.2-10 hr 1 .
6. A process according to claim 1 , in which the hydrocracking conditions in steps (c) comprise a temperature in a range of from 350-460° C., a pressure in the range of from 80-240 bar, and a weight hourly space velocity in a range of from 0.4-7 hr 1 .
7. A process according to claim 1 , wherein the entire hydrotreated product as obtained in step (b) is subjected to the hydrocracking in step (c).
8. A process according to claim 1 , wherein the hydrotreating catalyst as used in step (b) comprises one or more metals from Groups VB, VIB and/or VIII of the Periodic Table of the Elements, on a solid carrier.
9. A process according to claim 1 , wherein the hydrocracking catalyst as used in step (c) comprises one or more metals from Groups VIB and/or VIII of the Periodic Table of the Elements.