Energy and water recovery from pressure oxidation flash vessel steam
View Patent ↗The invention relates to a method for recovering energy and water from pressure oxidation flash steam where first flash steam directly obtained from a flash vessel is contacted with a first recirculating condensate having a first low condensate temperature to condense at least part of the water vapor in the first dirty flash steam and simultaneously to heat the first recirculating condensate to obtain a first recirculating condensate having a first high condensate temperature and a first vent steam. The invention further relates to a pressure oxidation arrangement adapted for use in the method.
1. A method of recovering energy and water from pressure oxidation flash steam, characterized in that the recovery of energy and cooling of a condensate are performed in a heat exchanger, and in that the method comprises a step wherein:
(a) a first flash steam directly obtained from a first flash vessel is contacted with a first recirculating condensate having a first low condensate temperature
to condense at least part of any water vapor comprised in the said first flash steam on the first recirculating condensate and
simultaneously with the contacting to heat the said first recirculating condensate to obtain a first recirculating condensate having a first high condensate temperature and a first vent steam,
wherein the first flash steam is obtained by flashing, in the first flash vessel, pressure oxidation discharge slurry from a pressure oxidation autoclave,
wherein the first recirculating condensate having a first high condensate temperature is an aqueous solution comprising condensed water and slurry resulting from condensing the first flash steam,
wherein the step (a) is performed in a first direct contact condenser.
2. The method as claimed in claim 1 , wherein the first flash steam is obtained by a step wherein a pressure oxidation discharge slurry obtained directly from a pressure oxidation autoclave is allowed to flash in the first flash vessel to obtain the said first flash steam and a first cooled slurry.
3. The method as claimed in claim 2 , wherein the pressure oxidation discharge slurry is obtained by pressure oxidation of metal containing ore or concentrate comprising 5 to 40% w/w sulfur as metal sulphides.
4. The method as claimed in claim 1 , wherein the method further comprises a step wherein:
(b) a second flash steam directly obtained from a second flash vessel is contacted with a second recirculating condensate having a second low condensate temperature to condense at least part of any water vapor comprised in the said second flash steam on the second recirculating condensate and simultaneously with the contacting to heat the said second recirculating condensate to obtain a second recirculating condensate having a second high condensate temperature and a second vent steam.
5. The method as claimed in claim 4 , wherein the second flash steam is obtained by a step wherein a first cooled slurry obtained from a first flash vessel is allowed to flash in the second flash vessel to obtain the said second flash steam and a second cooled slurry.
6. The method as claimed in claim 4 , wherein the method further comprises a step wherein the second flash steam is combined with the first vent steam before it is contacted with a second recirculating condensate having a second low condensate temperature in the second condenser.
7. The method as claimed in claim 4 , wherein step (b) is performed in a second direct contact condenser.
8. The method as claimed in claim 4 , wherein step (b) is performed at atmospheric pressure.
9. The method as claimed in claim 4 , wherein the second flash steam is contacted counter currently with the second recirculating condensate having a second low condensate temperature.
10. The method as claimed in claim 1 characterized in that the first flash steam is contacted counter currently with the first recirculating condensate having a first low condensate temperature.
11. The method of claim 1 , further comprising step (b) wherein the first recirculating condensate having a first high condensate temperature is a source of heat energy.
12. The method of claim 1 , wherein the recovery of energy and cooling of a condensate are performed in a heat exchanger, and in that the method comprises a step wherein:
(a) a first flash steam directly obtained from a first flash vessel is contacted with a first recirculating condensate having a first low condensate temperature, and simultaneously with the contacting to heat the said first recirculating condensate to obtain a first recirculating condensate having a first high condensate temperature and a first vent steam, wherein the step (a) is performed in a first direct contact condenser,
the method further comprising recovering heat energy and the condensed water from the pressure oxidation flash steam by using the direct contact condenser.