Sidewall support for a run flat tire
View Patent ↗Particular embodiments include run-flat tires having sidewall supports that are manufactured from a rubber composition that is based upon a tin end-functionalized polybutadiene rubber as well as an additional second rubber component and a mixture of carbon blacks. The first carbon black may be characterized as being a low-surface area, high-structure carbon black and the second carbon black may be characterized as a low-surface area carbon black. The low-surface area, high-structure carbon black may be added to the rubber composition in an amount that provides a modulus of elongation at 10% measured at 23° C. of between 8 MPa and 10 MPa.
1. A run-flat tire having a sidewall support, the sidewall support manufactured from a rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable elastomer composition comprising, per 100 parts by weight of rubber:
a tin end-functionalized polybutadiene rubber;
a second rubber component;
a first carbon black, the first carbon black being a low-surface area, high-structure carbon black having a nitrogen surface area of between 15 m 2 /g and 25 m 2 /g and a COAN of between 65 ml/100 g and 85 ml/100 g; and
a second carbon black, the second carbon black being a low-surface area carbon black having a nitrogen surface area of greater than 0 m 2 /g and 11 m 2 /g, wherein a total loading of the first and second carbon blacks is between 70 phr and 120 phr and wherein the first carbon black is between 20 wt. % and 90 wt. % of the total loading of the first and second carbon blacks.
2. The run-flat tire of claim 1 , wherein the total loading of the first and second carbon blacks is between 70 phr and 110 phr.
3. The run-flat tire of claim 1 , wherein the first carbon black is between 25 wt. % and 85 wt. % of the total loading of the first and second carbon blacks.
4. The run-flat tire of claim 1 , wherein the first carbon black is between 25 wt. % and 70 wt. % of the total loading of the first and second carbon blacks.
5. The run-flat tire of claim 1 , wherein an OAN of the first carbon black is between 100 ml/100 g and 150 ml/100 g.
6. The run-flat tire of claim 1 , wherein an iodine number of the first carbon black is between 10 mg/g and 25 mg/g.
7. The run-flat tire of claim 1 , wherein the cross-linkable elastomer composition comprises between 30 phr and 70 phr of the tin end-functionalized polybutadiene rubber.
8. The run-flat tire of claim 1 , wherein the cross-linkable elastomer composition comprises between 40 phr and 60 phr of the tin end-functionalized polybutadiene rubber.
9. The run-flat tire of claim 1 , wherein the second rubber component is selected from the group consisting of polybutadienes, polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and mixtures thereof.
10. The run-flat tire of claim 1 , wherein the second rubber component is natural rubber.
11. The run-flat tire of claim 1 , wherein the first carbon black is included in an amount to provide a modulus of elongation at 10% measured at 23° C. of between 7.5 MPa and 10.5 MPa.
12. The run-flat tire of claim 1 , wherein the first carbon black is included in an amount to provide a modulus of elongation at 10% measured at 23° C. of between 8 MPa and 10 MPa.
13. The run-flat tire of claim 1 , wherein the second carbon black has a nitrogen surface area of between 2 m 2 /g and 11 m 2 /g.
14. The run-flat tire of claim 13 , wherein the first carbon black is included in an amount to provide a modulus of elongation at 10% measured at 23° C. of between 8 MPa and 10 MPa.
15. The run-flat tire of claim 13 , wherein the cross-linkable elastomer composition comprises between 30 phr and 70 phr of the tin end-functionalized polybutadiene rubber.
16. The run-flat tire of claim 13 , wherein the second rubber component is natural rubber.
17. The run-flat tire of claim 13 , wherein the first carbon black has an OAN of between 100 ml/100 g and 150 ml/100 g and an iodine number of between 10 mg/g and 25 mg/g.
18. The run-flat tire of claim 13 , wherein the cross-linkable elastomer composition comprises between 40 phr and 60 phr of the tin end-functionalized polybutadiene rubber.
19. The run-flat tire of claim 18 , wherein the first carbon black has a nitrogen surface area of between 17 m 2 /g and 22 m 2 /g and a COAN of between 70 ml/100 g and 80 ml/100 g.
20. A run-flat tire having a sidewall support, the sidewall support manufactured from a rubber composition that is based upon a cross-linkable elastomer composition, the cross-linkable elastomer composition comprising, per 100 parts by weight of rubber:
a tin end-functionalized polybutadiene rubber;
a second rubber component selected from the group consisting of polybutadienes, polyisoprenes, natural rubber, butadiene copolymers, isoprene copolymers and mixtures thereof;
a first carbon black, the first carbon black being a low-surface area, high-structure carbon black having a nitrogen surface area of between 15 m 2 /g and 25 m 2 /g and a COAN of between 65 ml/100 g and 85 ml/100 g; and
a second carbon black, the second carbon black being a low-surface area carbon black having a nitrogen surface area of between 2 m 2 /g and 11 m 2 /g, wherein a total loading of the first and second carbon blacks is between 70 phr and 120 phr, wherein the first carbon black is between 10 wt. % and 90 wt. % of the total loading of the first and second carbon blacks, and wherein the first carbon black is included in an amount to provide a modulus of elongation at 10% measured at 23° C. of between 7.5 MPa and 10.5 MPa.