IP Library Granted Patent US 10,138,796
Granted Patent B2
US 10,138,796 · App. 14/654,949 · Granted Nov 27, 2018

Ferritic stainless steel for automotive exhaust system, which have excellent corrosion resistance against condensate, moldability, and high-temperature oxidation resistance, and method for manufacturing same

Inventors: Han Jin Ryu (Pohang-si, KR); Gi Sun Tae (Pohang-si, KR); Hyung Gu Kang (Pohang-si, KR); Hun Jae Ha (Pohang-si, KR)
Assignee: POSCO
F01N13/16B32B15/012C21D6/002C21D6/005C21D6/008C21D8/00C21D8/005C21D9/46C22C38/00C22C38/001C22C38/004C22C38/008C22C38/02C22C38/04C22C38/18C22C38/20C22C38/28C23C2/02C23C2/12C25F1/06C21D2211/005Y10T428/12757
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Quick Facts
Patent No.
US 10,138,796
App. No.
14/654,949
Granted
Nov 27, 2018
Kind
B2
Abstract

Provided is a ferritic stainless steel having excellent corrosion resistance against condensate, moldability, and high-temperature oxidation resistance, wherein the ferritic stainless steel is capable of being manufactured in an economically advantageous manner without adding expensive alloying elements. The ferritic stainless steel includes, by weight %, C: greater than 0 and 0.01% or less, Cr: 9 to 13%, Si: 0.5 to 1.0%, Mn: greater than 0 and 0.5% or less, P: greater than 0 and 0.035% or less, S: greater than 0 and 0.01% or less, Ti: 0.15 to 0.5%, N: greater than 0 and 0.01% or less, Sn: 0.05 to 0.5%, and the remainder is Fe and inevitable impurities, wherein Sn concentrated at the surface part of the stainless steel is 10 times or more than Sn concentrated at the base part.

Claims (11)

1. A ferritic stainless steel, comprising: by wt %, C: more than 0 and 0.01% or less, Cr: 9 to 13%, Si: 0.5 to 1.0%, Mn: more than 0 and 0.5% or less, P: more than 0 and 0.035% or less, S: more than 0 and 0.01% or less, Ti: 0.15 to 0.5%, N: more than 0 and 0.01% or less, Sn: 0.05 to 0.5%, and Fe and unavoidable impurities as the remainder,

wherein Sn concentrated at a surface part of the stainless steel is 10 times or more than Sn concentrated at a base part of the stainless steel,

the surface part extends from a surface of the stainless steel to a depth of 1 μm and the base part is the remainder of the stainless steel, and

0.5 to 1.5% Sn is included in the surface part of the stainless steel.

2. The ferritic stainless steel of claim 1 , further comprising 0.5 to 1.0% Cu.

3. The ferritic stainless steel of claim 2 , wherein the stainless steel has (5Sn+Cu) in a range of 0.5 to 2.0.

4. The ferritic stainless steel of claim 1 , wherein the stainless steel has (Si+Ti)/(C+N) in a range of 50 to 90.

5. The ferritic stainless steel of claim 1 , wherein a coating of aluminum covers the surface of the stainless steel.

6. The ferritic stainless steel of claim 5 , wherein the coating of aluminum has a thickness of 200 μm or less.

7. The ferritic stainless steel of claim 4 , wherein the stainless steel has a maximum corrosion depth of 0.25 mm or less measured using a JASO M609-91 method which is a method for measuring corrosion resistance under an environment of condensed water.

8. The ferritic stainless steel of claim 4 , wherein the stainless steel has a corrosion area ratio of 5% or less measured after 3 cycles of a JASO M611-92 method were performed, and a maximum corrosion depth of 0.25 mm or less measured after 100 cycles of the JASO M611-92 method were performed, the JASO M611-92 method is a method for measuring corrosion on an external surface of an automobile exhaust gas system.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061777/0974 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061562/0012 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2015
From: RYU, HAN JIN; TAE, GI SUN; KANG, HYUNG GU; HA, HUN JAE
To: POSCO
Reel/Frame 035884/0668 →
Priority Claims (2)
KR 10-2012-0152206 · Dec 24, 2012 · national
KR 10-2012-0153792 · Dec 26, 2012 · national
Continuity (1)
Related Publication 20150345361A1 · Dec 3, 2015