Method for producing saturated aldehyde from 1,2-alkanediol
View Patent ↗Provided is a method that produces a saturated aldehyde from a 1,2-alkanediol in high yield. Disclosed is a method for producing a saturated aldehyde from a 1,2-alkanediol in the presence of a regular mesoporous material.
1. A method for producing a saturated aldehyde, the method comprising contacting a 1,2-alkanediol with a regular mesoporous material to convert the 1,2-alkanediol into a saturated aldehyde, wherein the regular mesoporous material is a regular mesoporous material obtained by reacting a layered silicate with a surfactant.
2. The method according to claim 1 , wherein an average pore size of the regular mesoporous material is 2.0 nm or more and 10.0 nm or less.
3. The method according to claim 1 , wherein an acid quantity of the regular mesoporous material is 1.0 mmol/g or more and 10.0 mmol/g or less.
4. The method according to claim 1 , wherein the layered silicate is selected from kanemite (NaHSi 2 O 5 .3H 2 O), sodium disilicate crystals (α, β, γ, σ-Na 2 Si 2 O 5 ), makatite (Na 2 Si 4 O 9 .5H 2 O), ilerite (Na 2 Si 8 O 17 .xH 2 O), magadiite (Na 2 Si 14 O 29 .xH 2 O), and kenyaite (Na 2 Si 20 O 41 .xH 2 O).
5. The method according to claim 1 , wherein the regular mesoporous material is FSM-16.
6. The method according to claim 1 , wherein the 1,2-alkanediol is 1,2-propanediol.
7. The method according to claim 1 , wherein the saturated aldehyde is propionaldehyde.
8. The method according to claim 1 , wherein the 1,2-alkanediol is contacted with a regular mesoporous material such that W/F is 0.01 g·min/ml or more and 1000 g·min/ml or less.
9. The method according to claim 1 , wherein a temperature of the regular mesoporous material during the contacting is set to 200° C. or higher and 800° C. or lower.
10. The method according to claim 1 , wherein
the 1,2-alkanediol is 1,2-propanediol,
the saturated aldehyde is propionaldehyde,
the 1,2-propanediol is contacted with the regular mesoporous material such that W/F is 0.01 g·min/ml or more and 1000 g·min/ml or less,
a temperature of the regular mesoporous material during the contacting is set to 200° C. or higher and 800° C. or lower, and
the yield of propionaldehyde is at least 42.5%.
11. The method according to claim 10 , wherein the regular mesoporous material is FSM-16.
12. The method according to claim 10 , wherein the regular mesoporous material is MCM-41.
13. The method according to claim 1 , wherein the yield of saturated aldehyde is at least 42.5%.
14. The method according to claim 1 , wherein the yield of saturated aldehyde is at least 42.5%-63.0%.
15. The method according to claim 10 , wherein the yield of propionaldehyde is 42.5%-63.0%.