Method of manufacturing a pressure vessel for growing single crystals
View Patent ↗An object of the present invention is to manufacture single crystals of high quality on an industrial production scale by preventing impurities from being mixed in single crystals when the single crystals are produced by the solvothermal method. A pressure vessel body 1 , in which a supercritical state is maintained, is made of heat resistant alloy, a portion of the pressure vessel body is open, a corrosion-resistant mechanical lining 5 is provided on an inner face of the pressure vessel and on an entire outer circumferential edge of the opening, and the opening is sealed by an airtight mating face formed out of a corrosion-resistant mechanical lining, which is formed on the outer circumferential edge of the opening, and by an airtight mating face of the corrosion-resistant mechanical lining cover 6 on an inner face of the cover 3 through a corrosion-resistant gasket member. Since the pressure vessel body and the inner face of the cover are covered with the corrosion-resistant mechanical lining, corrosion can be prevented. The corrosion-resistant mechanical lining ensures the sealing property on the airtight mating face between the pressure vessel body and the cover and further effectively prevents corrosion in the airtight sealing portion and it becomes possible to repeatedly open and close the airtight sealing portion.
1. A method of manufacturing a pressure vessel for growing single crystals, comprising:
preparing a pressure vessel body made of a heat resistant alloy for maintaining a supercritical state, the pressure body including an opening;
preparing a corrosion-resistant mechanical lining provided on an inner face of the pressure vessel body and on an entire outer circumferential edge of the opening, wherein the corrosion-resistant mechanical lining is composed by joining the corrosion-resistant mechanical lining formed on the outer circumferential edge of the opening and the corrosion-resistant mechanical lining formed on the inner face of the pressure vessel body, a joining portion of which being distant from a corner portion of the corrosion-resistant mechanical lining;
coating one or both of the inner wall of the pressure vessel body and the outer wall of the corrosion-resistant mechanical lining with ductile material;
providing a hole for deflating gas staying between the pressure vessel body and the corrosion-resistant mechanical lining to the pressure vessel body;
incorporating the corrosion-resistant mechanical lining into the pressure vessel body,
removing gas staying in a gap formed between the pressure vessel body and the corrosion-resistant mechanical lining through the hole;
sealing the opening by a cover under a condition that the corrosion-resistant mechanical lining formed on the outer circumferential edge of the opening is used as an airtight mating face;
pressuring in the pressure vessel body and deforming the corrosion-resistant mechanical lining so as to closely contact the corrosion-resistant mechanical lining with the pressure vessel body; and
cladding the corrosion-resistant mechanical lining and the pressure vessel body with each other,
wherein:
the joining portion is located on the inner face of the pressure vessel body;
the corrosion-resistant mechanical lining includes a first portion formed on the inner face of the pressure vessel body having a first wall thickness and a second portion formed on the inner face of the pressure vessel body having a second wall thickness;
the first wall thickness is greater than the second wall thickness; and
the first portion is closer to the opening of the pressure vessel body than the second portion.
2. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the corrosion-resistant mechanical lining is composed by joining the corrosion-resistant mechanical lining formed on the outer circumferential edge of the opening and the corrosion-resistant mechanical lining formed on the inner face of the pressure vessel body by means of welding.
3. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the ductile material is made of Pt, Au, Ag, Cu or Ta.
4. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 , further comprising:
providing the hole to a bottom portion of the pressure vessel body; and
arranging a penetration preventing member between the bottom portion of the pressure vessel body and the corrosion-resistant mechanical lining when incorporating the corrosion-resistant mechanical lining into the pressure vessel body.
5. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the corrosion-resistant mechanical lining is made of at least one material selected from the group consisting of (a) Pt, (b) Ir, (c) an alloy in which at least one of Ir, Rh, Au, Ru, Re or ZrO 2 is added into Pt, (d) an alloy in which at least one of Pt, Rh, Ru or Re is added to Ir, (e) an alloy in which at least one of Pt, Au, Ir, Ru or Re is added into Rh, and (f) a combination thereof.
6. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the corrosion-resistant mechanical lining is made of at least one material selected from the group consisting of (a) an alloy in which at least one of Au, Ru, Re or ZrO 2 is added into Pt, (b) an alloy in which at least one of Ru or Re is added to Ir, (c) an alloy in which at least one of Pt, Au, Ir, Ru or Re is added into Rh, and (d) a combination thereof.
7. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein both the inner wall of the pressure vessel body and the outer wall of the corrosion-resistant mechanical lining are coated with the ductile material.
8. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the ductile material is made of Ag, Cu or Ta.
9. The method of manufacturing a pressure vessel for growing single crystals according to claim 1 ,
wherein the corrosion-resistant mechanical lining and the ductile material are made of different materials.