Golf balls having layers based on polyamide and fatty acid amide blends
View Patent ↗Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the layers is formed from a thermoplastic polyamide composition, comprising a blend of about 40 to about 99% by weight polyamide and about 1 to about 60% by weight fatty acid amide. Preferably, the ball has a dual core construction. A rubber composition is preferably used to form the outer core layer and the polyamide composition is preferably used to form the inner core. The flex modulus of the polyamide composition is preferably at least 15% greater than the flex modulus of the rubber composition.
1. A golf ball, comprising:
a) a dual core having an inner core and outer core layer, the inner core having an outer surface and geometric center and the outer core layer having an outer surface and inner surface; the inner core consisting essentially of a polyamide composition of about 40 to about 99% by weight polyamide and about 11 to about 60% by weight fatty acid amide and the outer core layer comprising a rubber composition,
the polyamide composition having a second flex modulus value; wherein a composition consisting of 100% by weight polyamide has a first flex modulus value, and the second flex modulus of the polyamide composition is at least 10% less than the first flex modulus value and at least 15% greater than the flex modulus of the rubber composition, and wherein the center of the inner core and surface of the outer core layer each has a hardness and the center hardness of the inner core is greater than the surface hardness of the outer core layer; and
b) a cover having at least one layer disposed about the dual core.
2. The golf ball of claim 1 , wherein the polyamide is selected from the group consisting of polyamide 6; polyamide 6,6; polyamide 6,10; polyamide 6,12; polyamide 11; polyamide 12; polyamide 6,9; and polyamide 4,6, and copolymers and blends thereof.
3. The golf ball of claim 1 , wherein the fatty acid amide is a primary monoamide selected from the group consisting of stearamide, oleamide, erucamide, behenamide, and palmitamide, and mixtures thereof.
4. The golf ball of claim 1 , wherein the fatty acid amide is a substituted monoamide selected from the group consisting of lauryl oleamide, stearyl erucamide, hydroxy fatty acid amides, N-methylol fatty acid amides, and cocamide diethanolamide, and mixtures thereof.
5. The golf ball of claim 1 , wherein the fatty acid amide is a bisamide selected from the group consisting of ethylene bis(stearamide), methylene bis(oleamide), and mixtures thereof.
6. The golf ball of claim 1 , wherein the polyamide composition has a flex modulus of 20,000 psi to 150,000 psi and the rubber composition has a flex modulus of 1,000 to 60,000 psi, the flex modulus of the polyamide composition being greater than the flex modulus of the rubber composition.
7. The golf ball of claim 1 , wherein the center hardness of the inner core is about 50 Shore D or greater and the surface hardness of the outer core is about 15 Shore D or greater, the center hardness of the inner core being greater than the surface hardness of the outer core layer.