Recyclable golf ball and method of making
View Patent ↗Golf ball comprising a non-dissolvable layer having a spherical outer surface; and a dissolvable tie layer or dissolvable layer, dispersible in water heated to a heating temperature of about 80° C.-90° C. or greater, disposed concentrically about the spherical outer surface and being bonded with the first non-dissolvable layer at an interface there between. The dissolvable tie layer/dissolvable layer may be formed from a composition consisting of a 1-50 percent aqueous mono-valent high acid ionomer dispersion, or, from an ionomer resin composition. The ionomer of either composition has an acid level greater than 18%; has more than 45% of acid groups that are neutralized with a monovalent cation; and is formed from an acid copolymer having a starting melt index of greater than 180 g/10 min. @ 190° C. with a 2160 g load. The dissolvable tie layer/dissolvable layer may have a thickness of less than about 0.010 inches, and up to about 0.090 inches in some embodiments.
1. A golf ball comprising:
a first molded non-dissolvable layer having a first spherical outer surface;
a dissolvable tie layer disposed concentrically about the first spherical outer surface by at least one of dipping, soaking, rolling, wiping, spraying, and brushing and being bonded with the first layer at an interface there between;
a second molded non-dissolvable layer disposed concentrically about a second spherical outer surface of the dissolvable tie layer and being bonded with the dissolvable tie layer at an interface there between;
wherein the dissolvable tie layer has a thickness of up to about 0.005 inches, and is formed from a tie layer composition consisting of a 1-50 percent aqueous mono-valent high acid ionomer dispersion;
wherein the ionomer of the tie layer composition: (i) has an acid level greater than 18%; (ii) has more than 45% of acid groups that are neutralized with a monovalent cation; and (iii) is formed from an acid copolymer having a starting melt index of greater than 180 g/10 min.@190° C. with a 2160 g load;
wherein the dissolvable tie layer is dispersible in water heated to a heating temperature of about 80° C.-90° C. or greater; and
wherein the first molded non-dissolvable layer and the second molded non-dissolvable layer are not dispersible in water at the heating temperature.
2. The golf ball of claim 1 , wherein the first molded non-dissolvable layer and the second molded non-dissolvable layer are different.
3. The golf ball of claim 1 , wherein the first molded non-dissolvable layer and the second molded non-dissolvable layer are substantially similar.
4. The golf ball of claim 1 , wherein the first molded non-dissolvable layer comprises a core, the dissolvable tie layer comprises an inner cover layer, and the second molded non-dissolvable layer comprises an outer cover layer.
5. The golf ball of claim 1 , wherein the first molded non-dissolvable layer comprises an inner cover layer, the dissolvable tie layer comprises a second inner cover layer and the second molded non-dissolvable layer comprises an outer cover layer.
6. The golf ball of claim 1 , wherein the monovalent cation is selected from the group consisting of Na, Li, and K.