Pesticidal compositions and processes related thereto
View Patent ↗This document discloses molecules having the following formula (“Formula One”) The molecules disclosed in this document are related to the field of processes to produce molecules that are useful as pesticides (e.g., acaricides, insecticides, molluscicides, and nematicides), such molecules, and processes of using such molecules to control pests.
1. A composition comprising a molecule having the following formula
wherein:
(A) Ar 1 is a substituted phenyl having one or more substituents independently selected from C 1 -C 6 haloalkyl and C 1 -C 6 haloalkoxy;
(B) Het is a triazolyl, oxadiazolyl, or pyrazolyl;
(C) Ar 2 is phenyl or substituted phenyl having one or more substituents independently selected from C 1 -C 6 alkyl;
(D) R 1 is H or CH 3 ;
(E) R 2 is selected from (K), H, C 1 -C 6 alkyl, C alkyl-O—C(═O)C 1 -C 6 alkyl, CH 2 OC(═O)N(H)(C(═O)OCH 2 Ph), and CH 2 S(3,4,5-trimethoxy-2-tetrahydro-pyran);
(F) R 3 is a substituted phenyl having one or more substituents independently selected from F, Cl, CH 3 , 2-CH(CH 3 ) 2 , CH(CH 3 )(C 2 H 5 ), OCH 3 , and phenyl;
(G) R 4 is (K) or H;
(H) M is N or C—R 5 ,
wherein R 5 is selected from H, CN, and C(═O)(C 1 -C 6 alkyl);
(I) Q 1 is O, and Q 2 is O or S;
(K) R 2 and R 4 along with C x (Q 2 )(N x ), optionally as an alternative from sections (E) for R 2 and (G) for R 4 , form a 4- to 7-membered saturated or unsaturated, hydrocarbyl cyclic group,
wherein said hydrocarbyl cyclic group may optionally be substituted with C 1 -C 6 alkyl or oxo.
2. A composition according to claim 1 wherein Ar 1 is a substituted phenyl that has one or more substituents selected from CF 3 , OCF 3 , and OC 2 F 5 .
3. A composition according to claim 1 wherein Het is triazolyl.
4. A composition according to claim 1 wherein Het is 1,2,4 triazolyl.
5. A composition according to claim 1 wherein Ar 2 is phenyl.
6. A composition according to claim 1 wherein R 1 is H.
7. A composition according to claim 1 wherein R 3 is substituted phenyl wherein said substituted phenyl has more than one substituent and at least one pair of said substituents are not ortho to each other.
8. A composition according to claim 1 wherein R 4 is H.
9. A composition according to claim 1 wherein Q 2 is S.
10. A composition comprising a molecule having a structure from compounds listed below:
No.
Structure
AA1
AA2
AA3
AA4
AA5
AA6
AA7
AA8
AA9
AA10
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
A17
A18
A19
A20
A21
A22
A23
A24
A25
A26
A27
A28
A29
A30
A31
A32
A33
A34
A35
A36
A37
A38
A39
A40
A41
A42
A43
A44
A46
A48
A49
A50
A51
A52
A53
A54
A55
A56
A57
A58
A59
A60
A61
A62
A63
A64
A65
A66
A67
A68
A69
A70
A71
A72
A73
A74
A75
A76
A77
A78
A79
A80
A81
A82
A83
A84
A85
A86
A87
A88
A89
A92
A93
A94
A95
A96
A97
A98
A99
A100
A101
A102
A103
A104
A105
A106
A107
A108
A109
A110
A111
A112
A113
A114
A115
A116
A117
A118
A119
A120
A121
A122
A123
A124
A125
11. The composition of claim 10 , wherein the molecule has a structure selected from compounds listed below:
No.
Structure
A1
A2
A3
A4
A5
A6
A7
A8
A9
A10
A11
A12
A13
A14
A15
A16
A17
A18
A19
A20
A21
A22
A23
A24
A25
A26
A27
A28
A29
A30
A31
A32
A33
A34
A35
A36
A37
A38
A39
A40
A41
A42
A43
A44
A46
A48
A49
A92
A93
A94
A95
A96
A97
A98
A99
A100
A101
A102
A103
A104
A105
A106
A107
A108
A109
A110
A111
A112
A113
A114
A115
A116
A117
A118
A119
A120
A121
A122
A123
A124
A125
12. A process comprising applying the composition of claim 10 to a locus to control a pest, in an amount sufficient to control such pest.