Process to improve coverage and electrical performance of solid electrolytic capacitors
View Patent ↗A method for forming a capacitor, a capacitor formed thereby and an improved composition for a conductive coating are described. The method includes providing an anode, forming a dielectric on the anode and forming a cathode layer over the dielectric by applying a monoamine, a weak acid and a conductive polymer.
1. A capacitor formed by a method comprising:
providing an anode;
forming a dielectric on said anode; and
forming a cathode layer over said dielectric by:
applying a monoamine;
applying a weak acid; and
applying a conductive polymer wherein said monoamine and said weak acid do not crosslink said conductive polymer.
2. A capacitor comprising:
an anode;
a dielectric at least partially encasing said anode; and
a cathode on said dielectric wherein said cathode comprises an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine and said weak acid do not crosslink said conductive polymer.
3. The capacitor of claim 2 wherein said weak acid has a pKa of at least 0.25 to no more than 10 in water.
4. The capacitor of claim 2 wherein said weak acid has a pKa of at least 0.25 to no more than 10 in water measured as a monomer.
5. The capacitor of claim 3 wherein said weak acid has a pKa of at least 1 to no more than 7 in water.
6. The capacitor of claim 5 wherein said weak acid has a pKa of at least 2 to no more than 6 in water.
7. A capacitor comprising:
an anode;
a dielectric at least partially encasing said anode; and
a cathode on said dielectric wherein said cathode comprises an intrinsically conducting polymer, a weak acid and a monoamine wherein said weak acid is selected from the group consisting of carbonic acid, boric acid, phosphoric acid, phosphonic acids, carboxylic acids, acrylic acid, benzoic acid, malonic acid, maleic acid, succinic acid, glutaric acid, adipic acid, sebacic acid, phenol, benzoic acid, phthalic acid, 2,2-bis(hydroxymethyl)propionic acid, dimethylolpropionic acid, citric acid, trimesic acid, butanetetracarboxylic acid and polyacrylic acid and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
8. The capacitor of claim 7 wherein said weak acid is selected from the group consisting of carboxylic acid, phosphoric acid, and phosphonic acids.
9. The capacitor of claim 2 wherein said monoamine comprises at least one hydroxyl group.
10. A capacitor comprising:
an anode;
a dielectric at least partially encasing said anode; and
a cathode on said dielectric wherein said cathode comprises an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine has a pKa in water of at least 30 and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
11. A capacitor comprising:
an anode;
a dielectric at least partially encasing said anode; and
a cathode on said dielectric wherein said cathode comprises an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine is defined by a formula selected from the group consisting of: R1NH2, R1R2NH, and R1R2R3N wherein R1, R2, R3 independently are selected from alkyl, substituted alkyl, aromatic and substituted aromatic with the proviso that none of R1, R2 or R3 are an amine, a phosphonium, a sulfonium or any strong acid groups that has a pKa below 0.25 in water and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
12. The capacitor of claim 11 wherein said R 1 , R 2 , R 3 are independently substituted with at least one group selected from the group consisting of hydroxy, thiol, sulfide, epoxy, phosphonate, phosphate and carboxylic.
13. The capacitor of claim 12 wherein said R 1 , R 2 , R 3 are independently substituted with at least one group selected from the group consisting of hydroxy, thiol, sulfide, epoxy, phosphonate and phosphate.
14. The capacitor of claim 12 wherein said monoamine comprises at least one hydroxy group.
15. The capacitor of claim 14 wherein said monoamine comprises no more than five hydroxyl groups.
16. The capacitor of claim 11 wherein said monoamine is selected from the group consisting of: ammonia, ethylamine, diethylamine, triethylamine, propylamine, dipropylamine, tripropylamine, isopropylamine, diisopropylamine, butylamine, tripropylamine, dibutylamine, tributylamine, isobutylamine, diisobutylamine, triisobutylamine, methylethylamine, pentylamine, hexylamine, octylamine, decylamine, allylamine, ethanolamine, diethanolamine, triethanolamine, methylethanolamine, butylethanolamine, cyclohexylethanolamine, cyclohexyldiethanolamine, N-ethylethanolamine, N-propylethanol amine, tris(hydroxymethyl)aminomethane, 3-amino-1-propanol, amino-2-propanol, diisoprpanolamine, triisopropanolamine, 5-amino-1-pentanol, 6-amino-1-hexanol, pyridine, aniline, methyl-aniline, nitro-aniline, 1-naphthylamine, 2-naphthylamine, and glucosamine.
17. The capacitor of claim 2 wherein said anode is a valve metal or a conductive oxide of said valve metal.
18. The capacitor of claim 17 wherein said valve metal is selected from the group consisting of Al, W, Ta, Nb, Ti, Zr and Hf.
19. The capacitor of claim 18 wherein said anode is selected from the group consisting of Al, Ta, Nb and NbO.
20. The capacitor of claim 2 wherein said dielectric is an oxide of said anode.
21. The capacitor of claim 2 wherein said conductive polymer is selected from the group consisting of polypyrrole, polyaniline and polythiophene.
22. The capacitor of claim 2 wherein said cathode further comprises an organic compound containing at least two epoxy functional groups.
23. The capacitor of claim 21 wherein said conductive polymer is poly(3,4-ethylenedioxythiophene).
24. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
25. The composition for the formation of a conductive coating of claim 24 wherein said conductive polymer is selected from the group consisting of polypyrrole, polyaniline and polythiophene.
26. The composition for the formation of a conductive coating of claim 24 wherein said conductive polymer is poly(3,4-ethylenedioxythiophene).
27. The composition for the formation of a conductive coating of claim 24 wherein said weak acid has a pKa of at least 0.25 to no more than 10 in water.
28. The composition for the formation of a conductive coating of claim 24 wherein said weak acid has a pKa of at least 0.25 to no more than 10 in water as the monomer.
29. The composition for the formation of a conductive coating of claim 28 wherein said weak acid has a pKa of at least 1 to no more than 7 in water.
30. The composition for the formation of a conductive coating of claim 29 wherein said weak acid has a pKa of at least 2 to no more than 6 in water.
31. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine wherein said weak acid is selected from the group consisting of carbonic acid, boric acid, phosphoric acid, phosphonic acids, carboxylic acids, acrylic acid, benzoic acid, malonic acid, maleic acid, succinic acid, glutaric acid, adipic acid, sebacic acid, phenol, benzoic acid, phthalic acid, 2,2-bis(hydroxymethyl)propionic acid, dimethylolpropionic acid, citric acid, trimesic acid, butanetetracarboxylic acid and polyacrylic acid and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
32. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine wherein said weak acid is selected from the group consisting of carboxylic acid, phosphoric acid, and phosphonic acids and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
33. The composition for the formation of a conductive coating of claim 24 wherein said monoamine comprises at least one hydroxyl group.
34. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine has a pKa in water of at least 30 and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
35. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine is defined by a formula selected from the group consisting of: R1NH2, R1R2NH, and R1R2R3N wherein R1, R2, R3 independently are selected from alkyl, substituted alkyl, aromatic and substituted aromatic with the proviso that none of R1, R2 or R3 are an amine, a phosphonium, a sulfonium or any strong acid groups that has a pKa below 0.25 in water and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
36. The composition for the formation of a conductive coating of claim 35 wherein said R 1 , R 2 , R 3 are independently substituted with at least one group selected from the group consisting of hydroxy, thiol, sulfide, epoxy, phosphonate, phosphate and carboxylic.
37. The composition for the formation of a conductive coating of claim 36 wherein said R 1 , R 2 , R 3 are independently substituted with at least one group selected from the group consisting of hydroxy, thiol, sulfide, epoxy, phosphonate and phosphate.
38. The composition for the formation of a conductive coating of claim 36 wherein said monoamine comprises at least one hydroxy group.
39. The composition for the formation of a conductive coating of claim 38 wherein said monoamine comprises no more than five hydroxyl groups.
40. A composition for the formation of a conductive coating comprising an intrinsically conducting polymer, a weak acid and a monoamine wherein said monoamine is selected from the group consisting of: ammonia, ethylamine, diethylamine, triethylamine, propylamine, dipropylamine, tripropylamine, isopropylamine, diisopropylamine, butylamine, tripropylamine, dibutylamine, tributylamine, isobutylamine, diisobutylamine, triisobutylamine, methylethylamine, pentylamine, hexylamine, octylamine, decylamine, allylamine, ethanolamine, diethanolamine, triethanolamine, methylethanolamine, butylethanolamine, cyclohexylethanolamine, cyclohexyldiethanolamine, N-ethylethanolamine, N-propylethanol amine, tris(hydroxymethyl)aminomethane, 3-amino-1-propanol, amino-2-propanol, diisoprpanolamine, triisopropanolamine, 5-amino-1-pentanol, 6-amino-1-hexanol, pyridine, aniline, methyl-aniline, nitro-aniline, 1-naphthylamine, 2-naphthylamine, and glucosamine and wherein said monoamine and said weak acid do not crosslink said conductive polymer.
41. The composition for the formation of a conductive coating of claim 24 further comprises an organic compound containing at least two epoxy functional groups.