Process for producing electrolyte for electrochemical battery cell
Disclosed is a process for producing an electrolyte for an electrochemical battery cell. In this process, a Lewis acid, a Lewis base and aluminum are mixed. The mixture is heated for a minimum period of six hours to a temperature above a minimum temperature of at least 200° C. and above the melting point of the mixture. An adduct of the Lewis acid and the Lewis base is thereby formed.
1. A process for producing an electrolyte for an electrochemical battery cell, comprising:
mixing a Lewis acid, a Lewis base and aluminum;
heating the mixture for a minimum period of 6 hours to a temperature above a minimum temperature, the minimum temperature being at least 200° C. and being above the melting point of the mixture, thereby forming an adduct of the Lewis acid and the Lewis base; and
adding sulfur dioxide (SO 2 ) to the adduct of the Lewis acid and the Lewis base.
2. The process according to claim 1 , wherein the minimum temperature is 250° C.
3. The process according to claim 1 , wherein the minimum period is 12 hours.
4. The process according to claim 1 , wherein the mixture contains at least 40 mmol of aluminum for each mole of Lewis acid.
5. The process according to claim 1 , wherein the mole ratio of the sum of the free Lewis base and the Lewis base contained in the Lewis acid/Lewis base adduct to the Lewis acid contained in the Lewis acid/Lewis base adduct is greater than 1.
6. The process according to claim 1 , wherein the adduct formed is an aluminate, halogenide, oxalate, borate, phosphate, arsenate or gallate of an alkali metal.
7. The process according to claim 6 , wherein the adduct is an aluminate, halogenide, oxalate, borate, phosphate, arsenate or gallate of lithium.
8. The process according to claim 1 , wherein the adduct formed contains, relative to the mole number of all adducts of a Lewis acid and a Lewis base present in the electrolyte, at most 30 mol % of adducts of a Lewis acid and a Lewis base having a cation differing from the cation of lithium.
9. The process according to claim 1 , wherein the adduct formed of the Lewis acid and the Lewis base includes a lithiumtetrahalogenoaluminate.
10. The process according to claim 9 , wherein the lithiumtetrahalogenoaluminate is lithiumtetrachloroaluminate.
11. The process according to claim 1 , wherein the Lewis acid is AlCl3.
12. The process according to claim 1 , wherein the Lewis base is a chloride of an alkali metal.
13. The process according to claim 1 , further comprising obtaining a liquid electrolyte.
14. The process according to claim 13 , wherein the liquid electrolyte contains at least 1 mole SO 2 per mole of conductive salt.
15. The process according to claim 13 , wherein the liquid electrolyte contains at least 2 mole SO 2 per mole of conductive salt.
16. The process according to claim 13 , wherein the liquid electrolyte contains at least 3 mole SO 2 per mole of conductive salt.
17. The process according to claim 1 , further comprising removing solid contamination by filtration after forming the adduct.
18. The process according to claim 17 , wherein the solid contamination comprises aluminum.
19. A process for producing an electrolyte for an electrochemical battery cell, with the molar concentration of hydroxide groups in the electrolyte being at most 50 mmol per liter and the molar concentration of chlorosulfonate groups in the electrolyte being at most 350 mmol per liter, the process comprising:
mixing a Lewis acid, a Lewis base and aluminum; and
heating the mixture for a minimum period of 6 hours to a temperature above a minimum temperature, the minimum temperature being at least 200° C. and being above the melting point of the mixture, thereby forming an adduct of the Lewis acid and the Lewis base; and
adding sulfur dioxide (SO 2 ) to the adduct of the Lewis acid and the Lewis base, and obtaining a liquid electrolyte.
20. A process for producing an electrolyte for an electrochemical battery cell, comprising:
mixing a Lewis acid, a Lewis base and aluminum; and
heating the mixture for a minimum period of 6 hours to a temperature above a minimum temperature, the minimum temperature being at least 200° C. and being above the melting point of the mixture, thereby forming an adduct of the Lewis acid and the Lewis base; and
adding sulfur dioxide (SO 2 ) to the adduct of the Lewis acid and the Lewis base, and obtaining a liquid electrolyte essentially free of organic materials.