Antistatic polymer composition
A polymer composition having a reduced tendency to create a static electric charge during a molding operation is provided. More particularly, the composition contains an ionic liquid that is distributed within a polymer matrix that contains an aromatic polymer. In addition to being electrically conductive, the ionic liquid can exist in liquid form during melt processing, which allows it to be more uniformly blended within the aromatic polymer matrix. This improves electrical connectivity and thereby enhances the ability of the composition to rapidly dissipate static electric charges from its surface.
1. A camera module that comprises a molded part and a lens assembly, wherein the molded part comprises a polymer composition comprising a fibrous filler that contains glass fibers, the polymer composition further comprising an ionic liquid distributed within a polymer matrix, the polymer matrix including an aromatic polymer having a glass transition temperature of about 100° C. or more, and wherein the aromatic polymer is a polyamide and is present in the composition in an amount of from about 30 wt. % to about 80 wt. % of the composition, the ionic liquid is present in the composition in an amount of from about 0.3 wt. % to about 5 wt. % of the composition, and the glass fibers are present in the composition in an amount of from about 5 wt. % to about 40 wt. % of the composition, further wherein the composition exhibits a melt viscosity of from about 0.1 Pa·s to about 80 Pa·s as determined at a shear rate of 1000 seconds −1 in accordance with ISO Test No. 11443 at a temperature that is 15° C. higher than the melting temperature of the composition, and wherein the molded part exhibits a surface resistivity of about 1×10 15 ohms or less as determined in accordance with IED 60093.
2. The camera module of claim 1 , wherein the aspect ratio of the glass fibers range from about 10 to about 60.
3. The camera module of claim 1 , wherein the fibrous filler consists essentially of the glass fibers.
4. The camera module of claim 1 , wherein the polymer composition further comprises carbon fibers, graphite, carbon black, or a combination thereof.
5. The camera module of claim 1 , wherein the ionic liquid is present in the composition from about 0.4 wt. % to about 3 wt. %.
6. The cameral module of claim 1 , wherein the ionic liquid has a melting temperature of about 400° C. or less and is a salt that contains a cationic species and a counterion.
7. The camera module of claim 6 , wherein the cationic species is a quaternary onium.
8. The camera module of claim 7 , wherein the quaternary onium is an ammonium compound having the structure N + R 1 R 2 R 3 R 4 , wherein R 1 , R 2 , and/or R 3 are independently a C 1 -C 6 alkyl and R 4 is hydrogen or a C 1 -C 4 alkyl group.
9. The camera module of claim 8 , wherein the ammonium compound is tri-butylmethylammonium.
10. The camera module of claim 6 , wherein the counterion is a halogen, sulfate, sulfonate, sulfosuccinate, amide, imide, borate, phosphate, phosphinate, antimonite, aluminate, fatty acid carboxylate, cyanate, acetate, or a combination thereof.
11. The camera module of claim 6 , wherein the counterion is bis(pentafluoroethylsulfonyl)imide, bis(trifluoromethylsulfonyl)imide, or bis(tri-fluoromethyl)imide.
12. The camera module of claim 1 , wherein the ionic liquid includes tri-butylmethylammonium bis(trifluoromethylsulfonyl)imide.
13. The camera module of claim 1 , wherein the polyamide contains an aromatic repeating unit derived from an aromatic dicarboxylic acid and an aliphatic repeating unit derived from an aliphatic diamine having from 4 to 14 carbon atoms.
14. The camera module of claim 13 , wherein the aromatic dicarboxylic acid is terephthalic acid.
15. The camera module of claim 13 , wherein the aliphatic diamine is 1,9-nonanediamine, 2-methyl-1,8-octanediamine, or a combination thereof.