Active material powder and method of producing the same
An active material powder includes an active material particle, and a coating layer. The coating layer contains LiNbO 3 and has pores. When a total volume of pores having a diameter of 2 nm to 7 nm and a total volume of pores having a diameter of 2 nm to 200 nm are respectively represented by V 1 and V 2 , V 1 /V 2 is 0.185 or less. In addition, a method of producing an active material powder includes: obtaining, with a fluidized bed granulating-coating machine, a powder including an active material particle to which an alkoxide compound is attached; and promoting hydrolysis of the alkoxide compound by exposing the powder to a humidified inert gas atmosphere. An intake-gas temperature of the fluidized bed granulating-coating machine is 100° C. or higher. A time during which the powder is exposed to the humidified inert gas atmosphere is four hours or longer.
1. An active material powder comprising:
an active material particle; and
a coating layer that is attached to a surface of the active material particle, contains LiNbO 3 , and has pores, wherein
when a total volume of pores having a diameter of 2 nm to 7 nm among the pores is represented by V 1 , and when a total volume of pores having a diameter of 2 nm to 200 nm among the pores is represented by V 2 , V 1 /V 2 is 0.185 or less.
2. The active material powder according to claim 1 , wherein a coverage of the coating layer on the surface of the active material particle is 50% or higher.
3. A method of producing an active material powder comprising:
obtaining a powder including an active material particle and a coating layer precursor attached to a surface of the active material particle by attaching an alkoxide solution to the surface of the active material particle and by concurrently drying the alkoxide solution attached to the surface of the active material particle with a fluidized bed granulating-coating machine, the alkoxide solution containing an alkoxide compound;
promoting hydrolysis of the alkoxide compound by exposing the powder to a humidified inert gas atmosphere; and
forming a coating layer on the surface of the active material particle by heating the powder after the promotion of the hydrolysis, wherein
an intake-gas temperature of the fluidized bed granulating-coating machine is 100° C. or higher,
a time during which the powder is exposed to the humidified inert gas atmosphere is four hours or longer, and
when a total volume of pores having a diameter of 2 nm to 7 nm among the pores is represented b V 1 , and when a total volume of pores having a diameter of 2 nm to 200 nm among the pores is represented by V 2 , V 1 /V 2 is 0.185 or less.
4. The method according to claim 3 , wherein
the alkoxide solution is a sol-gel solution.