Method for restoring activity to a spent hydroprocessing catalyst, a spent hydroprocessing catalyst having restored catalytic activity, and a hydroprocessing process
View Patent ↗A regenerated spent hydroprocessing catalyst treated with a chelating agent and having incorporated therein a polar additive.
1. An activity-restored hydroprocessing catalyst composition, comprising:
a regenerated hydroprocessing catalyst, comprising a hydroprocessing catalyst, including a Group VIII metal component, a Group VIB metal component, and a support material, that has become spent by use under hydrotreatment conditions to provide a spent hydroprocessing catalyst containing a carbon content above 0.5 wt. %, wherein said spent hydroprocessing catalyst is heat treated by contacting it with an oxygen-containing gas under carbon burning conditions to provide said regenerated hydroprocessing catalyst having a reduced carbon concentration less than that of the spent hydroprocessing catalyst;
a chelating agent selected from the group of compounds consisting of aminocarboxylic acids, polyamines, aminoalcohols, oximes, and polyethyleneimines; and
a polar additive that is a heterocompound having polarity and a dipole moment of at least 0.45.
2. An activity-restored hydroprocessing catalyst composition as recited in claim 1 , wherein said chelating agent is an aminocarboxylic acid selected from the group of compounds consisting of ethylenediaminetetraacetic acid (EDTA) hydroxyethylenediaminetriacetic acid (HEDTA), diethylenetriaminepentaacetic acid (DTPA), and nitrilotriacetic acid (NTA).
3. An activity-restored hydroprocessing catalyst composition as recited in claim 2 , wherein said polar additive is amide compound.
4. An activity-restored hydroprocessing catalyst composition as recited in claim 3 , wherein said Group VIII metal component is either nickel or cobalt present in said hydroprocessing catalyst in an amount in the range of from 0.1 to 6 weight percent, based on the metal as an element and the total weight of the hydroprocessing catalyst, and said Group VIB metal component is either molybdenum or chromium present in said hydroprocessing catalyst in an amount in the range of from 5 to 25 weight percent, based on the metal as an element and the total weight of the hydroprocessing catalyst.
5. An activity-restored hydroprocessing catalyst composition as recited in claim 4 , wherein said support material comprises alumina.
6. An activity-restored hydroprocessing catalyst composition as recited in claim 5 , wherein said polar additive has a boiling temperature within the range of from 50° C. to 275° C.
7. An activity-restored hydroprocessing catalyst composition as recited in claim 6 , wherein said polar additive is dimethylformamide.
8. An activity-restored hydroprocessing catalyst composition as recited in claim 7 , wherein said chelating agent is present in said regenerated hydroprocessing catalyst in an amount in the range of from 0.005 mole chelant per mole of active Group VIB and Group VIII metal (0.005 mole/mole) to 1 mole chelant per mole of active Group VIB and Group VIII metal (1 mole/mole).
9. An activity-restored hydroprocessing catalyst composition as recited in claim 8 , wherein said chelating agent is diethylenetriaminepentaacetic acid (DTPA).
10. A hydroprocessing process, comprising: contacting under hydroprocessing conditions the composition of claim 3 .
11. A hydroprocessing process, comprising: contacting under hydroprocessing conditions the composition of claim 2 .
12. A hydroprocessing process, comprising: contacting under hydroprocessing conditions the composition of claim 1 .