METHODS OF USING TANKMIX ADDITIVE CONCENTRATES CONTAINING PARAFFINIC OILS
Tankmix additive concentrates containing a surfactant and a petroleum derived paraffinic oil and the use of aqueous pesticide spray mixtures incorporating such tankmix additive concentrates are described. The tankmix additive concentrates described herein include from 0.5 to 50 weight percent of a polymeric surfactant, a anionic ester surfactant, a nonionic surfactant, or mixtures thereof, and from 1 to 95 weight percent of a petroleum derived paraffinic oil. The tankmix additive concentrates form a stable emulsion upon dilution into a pesticide spray mixture.
1 . A method for reducing spray drift during pesticide spray application comprising:
providing a tankmix additive concentrate comprising:
from 0.5 to 50 weight percent of a surfactant, wherein the surfactant is a polymeric surfactant, a nonionic surfactant, a anionic surfactant, or mixtures thereof;
from 1 to 95 weight percent of a petroleum derived paraffinic oil.
2 . The method of claim 1 , further comprising adding the tankmix additive concentrate to a pesticide spray mixture, wherein the tankmix additive concentrate forms a stable emulsion upon addition to pesticide spray mixture.
3 . The method of claim 2 , wherein the amount of spray drift generated when spraying is decreased compared to a pesticide spray mixture sprayed without the tankmix additive concentrate.
4 . The method of claim 1 , wherein the petroleum derived paraffinic oil is a normal paraffin, an isoparaffin, a cycloparaffin, a highly refined paraffinic mineral oil, a solvent dewaxed light and/or a heavy paraffinic distillate, or mixtures thereof.
5 . The method of claim 2 , wherein the pesticide spray mixture contains a herbicide, an insecticide, a fungicide, or mixtures thereof.
6 . The method of claim 5 , wherein the pesticide spray mixture contains a herbicide.
7 . The method of claim 6 , wherein the herbicide is an auxinic herbicide.
8 . The method of claim 1 , wherein the anionic surfactant is an acid or salt of a mono or dialkyl phosphate ester, an acid or salt of an ethoxylated mono or dialkyl phosphate ester, an acid or salt of a mono or dialkyl phosphate ester of an ethoxylated tristyrylphenol, an acid or salt of a mono or dialkyl phosphate ester of an ethoxylated phenol or an ethoxylated alkylphenol, a salt of an alkylbenzenesulfonate, or mixtures thereof.
9 . The method of claim 1 , wherein the polymeric surfactant is an ABA block copolymer having a hydrophilic portion of polyethylene oxide and a hydrophobic portion of poly(12-hydroxystearate), a polyvinyl alcohol resin wherein the degree of hydrolysis is 86-89%, a block or graft acrylate or methacrylate copolymer, an alkyd polyethylene oxide resin, an AB block copolymer containing EO and PO blocks, or mixtures thereof.
10 . The method of claim 1 , wherein the nonionic surfactant is an alcohol alkoxylate, a fatty alcohol alkoxylate, an ethoxylated castor oil, a sorbitan ester, an ethoxylated sorbitan ester, an ethoxylated sorbitol ester, an ethoxylated tristyrylphenol, or mixtures thereof.
11 . The method of claim 7 , wherein the auxinic herbicide is a water soluble salt of 2,4-D, a water soluble salt of aminocyclopyrachlor, a water soluble salt of aminopyralid, a water soluble salt of clopyralid, a water soluble salt of dicamba, a water soluble salt of picloram, a water soluble salt of triclopyr, a water soluble salt of halauxifen, or mixtures thereof.
12 . The method of claim 11 , wherein the auxinic herbicide is a water soluble salt of 2,4-D.
13 . The method of claim 12 , wherein the water soluble salt of 2,4-D is 2,4-D choline salt or 2,4-D dimethyl ammonium salt.
14 . The method of claim 2 , wherein the pesticide spray mixture further comprises an additional herbicide.
15 . The method of claim 14 , wherein the additional herbicide is glyphosate or glufosinate.
16 . The method of claim 14 , wherein the pesticide spray mixture contains a water soluble salt of 2,4-D or a water soluble salt dicamba, and the additional herbicide is glyphosate or glufosinate.
17 . The method of claim 2 , wherein the pesticide spray mixture is sprayed 30 feet or more away from a sensitive or susceptible crop.
18 . A tankmix additive concentrate, comprising:
from 0.5 to 50 weight percent of a surfactant; and
from 1 to 95 weight percent of a petroleum derived paraffinic oil;
wherein the tankmix additive concentrate forms a stable emulsion in a pesticide spray mixture upon addition of the tankmix additive concentrate into the pesticide spray mixture.
19 . The tankmix additive concentrate of claim Error! Reference source not found, wherein the petroleum derived paraffinic oil is a normal paraffin, an isoparaffin, a cycloparaffin, a highly refined paraffinic mineral oil, a solvent dewaxed light and/or a heavy paraffinic distillate, or mixtures thereof.
20 . The tankmix additive concentrate of claim 18 , wherein the surfactant is at least one of a polymeric surfactant, a nonionic surfactant, and an anionic surfactant.
21 . The tankmix additive concentrate of claim Error! Reference source not found, wherein the polymeric surfactant is an ABA block copolymer having a hydrophilic portion of polyethylene oxide and a hydrophobic portion of poly(l2-hydroxystearate), a polyvinyl alcohol resin wherein the degree of hydrolysis is 86-89%, a block or graft acrylate or methacrylate copolymer, an alkyd polyethylene oxide resin, an AB block copolymer containing EO and PO blocks, or mixtures thereof.
22 . The tankmix additive concentrate of claim Error! Reference source not found, wherein the nonionic surfactant is an alcohol alkoxylate, a fatty alcohol alkoxylate, ethoxylated castor oils, sorbitan esters, ethoxylated sorbitan esters, ethoxylated sorbitol esters, ethoxylated tristyrylphenols, or mixtures thereof.
23 . The tankmix additive concentrate of claim Error! Reference source not found, wherein the anionic surfactant is a salt of an alkylbenzenesulfonate, an acid or salt of a phosphate ester, or mixtures thereof.
24 . The tankmix additive concentrate of claim Error! Reference source not found, wherein the anionic surfactant is an acid or salt of a mono or dialkyl phosphate ester, an acid or salt of an ethoxylated mono or dialkyl phosphate ester, an acid or salt of a mono or dialkyl phosphate ester of an ethoxylated tristyrylphenol, an acid or salt of a mono or dialkyl phosphate ester of an ethoxylated phenol or an ethoxylated alkylphenol, or mixtures thereof.