Composition for preparing polysaccharide fibers
View Patent ↗Solutions formed by combining poly(α(1→3) glucan) with CS 2 in aqueous alkali metal hydroxide solution have been shown to produce the xanthated form of the poly(α(1→3) glucan). The solutions so formed have been shown to be useful for solution spinning into fiber of poly(α(1→3) glucan) when the spun fiber is coagulated in an acidic coagulation bath. The fibers so produced exhibit desirable physical properties. The poly(α(1→3) glucan) employed was synthesized by fermentation.
1. A process comprising forming a solution by dissolving in a 0.75 to 2 molar aqueous alkali metal hydroxide, CS 2 , and 5 to 15 percent by weight of the total weight of the resulting solution of poly(α(1→3) glucan) characterized by a number average molecular weight of at least 10,000 Da, causing said solution to flow through a spinneret, forming a fiber thereby; and contacting said fiber with an acidic liquid coagulant; wherein said process the weight ratio of CS 2 to poly(α(1→3) glucan) lies in the range of 0.1 to 1.0.
2. The process of claim 1 wherein 7.5 to 15 percent by weight of poly(α(1→3) glucan) is dissolved in said solution.
3. The process of claim 1 wherein the alkali metal hydroxide is NaOH.
4. The process of claim 1 wherein the concentration of NaOH is 1.0to 1.7 molar.
5. The process of claim 1 wherein the poly(α(1→3) glucan) 100% of the repeat units are glucose, and 100% of the linkages between repeat units are α(1→3) glycoside linkages.
6. The process of claim 1 further comprising allowing the solution to stand for a period of 1 to 8 hours prior to spinning.
7. The process of claim 1 wherein the poly(α(1→3) glucan) is characterized by a number average molecular weight in the range of 40,000-100,000Daltons.
8. The process of claim 1 wherein the CS 2 is added last.