IP Library Granted Patent US 9,522,305
Granted Patent B2
US 9,522,305 · App. 14/691,720 · Granted Dec 20, 2016

Golf balls comprising a plasticized polyurethane layer

Inventors: Michael J. Sullivan (Old Lyme, CT); Mark L. Binette (Mattapoisett, MA); Robert Blink (Newport, RI); David A. Bulpett (Boston, MA); Brian Comeau (Berkley, MA); Douglas S. Goguen (New Bedford, MA)
Assignee: Acushnet Company
A63B37/0092A63B37/0043A63B37/0044A63B37/0045A63B37/0058A63B37/0062A63B37/0063A63B37/0064A63B37/0075A63B37/0076C08L75/00
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Quick Facts
Patent No.
US 9,522,305
App. No.
14/691,720
Granted
Dec 20, 2016
Kind
B2
Abstract

A golf ball comprising a core and a cover layer, wherein at least one of the core or cover layer comprises a plasticized polyurethane composition comprising at least one polyurethane and at least one plasticizer.

Claims (36)

1. A three-layer golf ball consisting essentially of:

an inner core layer having a diameter of 1.10 inches or less, a center Shore C hardness (H center ) of from 10 to 50, and formed from a composition comprising a polyurethane and from 2 wt % to 50 wt %, based on the total weight of the inner core layer composition, of a plasticizer;

an outer core layer having a thickness of 0.200 inches or greater, an outer surface Shore C hardness (H outer core surface ) of from 70 to 95, and formed from a thermoplastic composition; and

a single layer cover;

wherein H outer core surface −H center ≧40.

2. The golf ball of claim 1 , wherein the plasticizer is selected from the group consisting of dipropylene glycol-dibenzoate, ethyl oleate and propylene carbonate.

3. The golf ball of claim 1 , wherein the plasticizer is present in an amount of from 3 wt % to 40 wt %, based on the total weight of the inner core layer composition.

4. The golf ball of claim 1 , wherein H outer core surface −H center ≧50.

5. The golf ball of claim 1 , wherein H outer core surface −H center ≧60.

6. The golf ball of claim 1 , wherein the inner core layer has an interface Shore C hardness (H inner core interface ) such that −5≦H inner core interface −H center ≦5.

7. The golf ball of claim 6 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface ≦H outer core surface −H center .

8. The golf ball of claim 6 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface >H outer core surface −H center .

9. A three-layer golf ball consisting essentially of:

an inner core layer having a diameter of 1.10 inches or less, a center Shore C hardness (H center ) of from 10 to 50, and formed from a thermoplastic composition;

an outer core layer having a thickness of 0.200 inches or greater, an outer surface Shore C hardness (H outer core surface ) of from 70 to 95, and formed from a thermoplastic composition comprising a polyurethane and from 2 wt % to 50 wt %, based on the total weight of the outer core layer composition, of a plasticizer; and

a single layer cover;

wherein H outer core surface −H center ≧40.

10. The golf ball of claim 9 , wherein the plasticizer is selected from the group consisting of dipropylene glycol-dibenzoate, ethyl oleate and propylene carbonate.

11. The golf ball of claim 9 , wherein the plasticizer is present in an amount of from 3 wt % to 40 wt %, based on the total weight of the outer core layer composition.

12. The golf ball of claim 9 , wherein H outer core surface −H center ≧50.

13. The golf ball of claim 9 , wherein H outer core surface −H center ≧60.

14. The golf ball of claim 9 , wherein the inner core layer has an interface Shore C hardness (H inner core interface ) such that −5≦H inner core interface −H center ≦5.

15. The golf ball of claim 14 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface ≦H outer core surface −H center .

16. The golf ball of claim 14 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface >H outer core surface −H center .

17. A three-layer golf ball consisting essentially of:

an inner core layer having a diameter of 1.10 inches or less, a center Shore C hardness (H center ) of from 10 to 40, and formed from a thermoplastic composition comprising a polyurethane and from 2 wt % to 50 wt %, based on the total weight of the inner core layer composition, of a plasticizer;

an outer core layer having a thickness of 0.200 inches or greater, an outer surface Shore C hardness (H outer core surface ) of from 75 to 95, and formed from a thermoset composition; and

a single layer cover;

wherein H outer core surface −H center ≧50.

18. The golf ball of claim 17 , wherein the plasticizer is selected from the group consisting of dipropylene glycol-dibenzoate, ethyl oleate and propylene carbonate.

19. The golf ball of claim 17 , wherein the plasticizer is present in an amount of from 3 wt % to 40 wt %, based on the total weight of the inner core layer composition.

20. The golf ball of claim 17 , wherein H outer core surface −H center ≧60.

21. The golf ball of claim 17 , wherein H outer core surface −H center ≧70.

22. The golf ball of claim 17 , wherein the inner core layer has an interface Shore C hardness (H inner core interface ) such that −5≦H inner core interface −H center ≦5.

23. The golf ball of claim 22 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface ≦H outer core surface −H center .

24. The golf ball of claim 22 , wherein the outer core layer has an interface Shore C hardness (H outer core interface ) such that H outer core interface −H inner core interface >H outer core surface −H center .

Assignments (5)
SECURITY INTEREST Recorded Aug 3, 2022
From: ACUSHNET COMPANY
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061099/0236 →
ASSIGNMENT OF SECURITY INTEREST IN PATENTS (ASSIGNS 039506-0030) Recorded Aug 3, 2022
From: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS RESIGNING ADMINISTRATIVE AGENT
To: JPMORGAN CHASE BANK, N.A., AS SUCCESSOR ADMINISTRATIVE AGENT
Reel/Frame 061521/0414 →
SECURITY INTEREST Recorded Jul 28, 2016
From: ACUSHNET COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS ADMINISTRATIVE AGENT
Reel/Frame 039506/0030 →
SECURITY INTEREST Recorded Nov 6, 2015
From: ACUSHNET COMPANY
To: KOREA DEVELOPMENT BANK, NEW YORK BRANCH
Reel/Frame 036983/0648 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 21, 2015
From: SULLIVAN, MICHAEL J.; BINETTE, MARK L.; BLINK, ROBERT; BULPETT, DAVID A.; COMEAU, BRIAN; GOGUEN, DOUGLAS S.
To: ACUSHNET COMPANY
Reel/Frame 035455/0991 →
Continuity (2)
Continuation In Part 14672538 · Mar 30, 2015
Related Publication 20160287947A1 · Oct 6, 2016