Apparatus for preparing cathode active material precursor for lithium secondary batteries and method for preparing the same using the apparatus

1. A method for preparing a cathode active material precursor for lithium secondary batteries using an apparatus having a cylindrical outer chamber having a cylindrical sidewall; an inner cylinder that has the same central axis as the outer chamber and is mounted to rotatably move along the central axis; an electric motor to transfer power to rotate the inner cylinder; a reactant inlet disposed on the outer chamber, to add reactants to a space between the outer chamber and the inner cylinder; and an outlet disposed in the outer chamber, to obtain reaction products after reaction in the space between the outer chamber and the inner cylinder, comprising:

adding reactants containing a metal salt aqueous solution, a basic aqueous solution and an aqueous ammonia solution to a reactant inlet (step 1);

rotating the inner cylinder to form ring-shaped vortex pairs that rotate in opposite directions along the central axial direction and to mix the reactants in the space between the outer chamber and the inner cylinder after addition of the reactants in step 1 (step 2);

obtaining a reaction product-containing solution of the reactants mixed, while the reactants moving in the axial direction of the outer chamber in step 2, from the outlet (step 3);

removing the reaction product-containing solution through the cylindrical sidewall of the outer chamber; and

drying the reaction product-containing solution obtained in step 3 and oxidizing the same in the air (step 4).

2. The method according to claim 1 , wherein step 2 further comprises continuously adding the reactants to the reactant inlet during mixing in the space between the outer chamber and the inner cylinder.

3. The method according to claim 1 , wherein, in step 2, the inner cylinder was rotated at a speed of 10 to 5,000 rpm and the reactants are mixed at a temperature of 30 to 60° C. and at a pH 10 to 12.

4. The method according to claim 1 , wherein, in step 1, the metal salt aqueous solution is a metal salt aqueous solution in which a metal salt containing at least one metal selected from the group consisting of cobalt (Co), manganese (Mn), nickel (Ni), aluminum (Al), magnesium (Mg), copper (Cu), zinc (Zn), iron (Fe), vanadium (V), chromium (Cr), titanium (Ti), tungsten (W) and molybdenum (Mo) is dissolved at a concentration of 1M to 4M in water, and the metal salt is a sulfate, nitrate, acetate, chlorate or phosphate containing at least one metal selected from the group consisting of cobalt (Co), manganese (Mn), nickel (Ni), aluminum (Al), magnesium (Mg), copper (Cu), zinc (Zn), iron (Fe), vanadium (V), chromium (Cr), titanium (Ti), tungsten (W) and molybdenum (Mo).

5. The method according to claim 1 , wherein the basic aqueous solution is a 1M to 8M sodium hydroxide aqueous solution or potassium hydroxide aqueous solution.

6. The method according to claim 1 , wherein the aqueous ammonia solution is a 15 to 30% aqueous ammonia solution and is added at an amount of 1 to 20% by volume, with respect to the total weight of the mixed solution of the reactants.

7. The method according to claim 1 , wherein the reaction product-containing solution is removed through one of a plurality of openings spaced along an axial direction of the cylindrical sidewall of the outer chamber.