Methods of forming polycrystalline compacts
View Patent ↗Methods of forming a polycrystalline compact for use in an earth-boring tool include sintering a plurality of hard particles with catalyst material to form a polycrystalline material that includes a plurality of inter-bonded particles of hard material integrally formed with the catalyst material and introducing at least a portion of the polycrystalline material to a reactive material to remove at least a portion of the catalyst material contained within the polycrystalline material. The reactive material may include at least one of a molten glass, an ionic compound, a leaching liquor, and a chemical plasma. The reactive material may be introduced to the polycrystalline material at a temperature of greater than or equal to a melting point thereof.
1. A method of forming a polycrystalline compact cutting element, the method comprising:
forming a cutting element comprising a polycrystalline material and a catalyst material disposed in interstitial spaces between inter-bonded crystals of the polycrystalline material; and
removing at least a portion of the catalyst material from the interstitial spaces between inter-bonded crystals of the polycrystalline material, wherein removing at least a portion of the catalyst material from the interstitial spaces comprises:
exposing at least a portion of the polycrystalline material to a solution comprising acetic acid; and
subsequently adding at least one of an oxalic acid and an oxalic acid ester to the solution to which the at least a portion of the polycrystalline material is exposed.
2. The method of claim 1 , wherein forming a cutting element comprising a polycrystalline material and a catalyst material disposed in interstitial spaces between inter-bonded crystals of the polycrystalline material comprises forming a cutting element comprising the polycrystalline material and a catalyst material comprising cobalt disposed in the interstitial spaces between inter-bonded crystals of the polycrystalline material.
3. The method of claim 1 , wherein removing at least a portion of the catalyst material from the interstitial spaces between inter-bonded crystals of the polycrystalline material comprises removing at least a portion of the catalyst material from the interstitial spaces to a substantially uniform depth from a face of the polycrystalline material.
4. The method of claim 3 , wherein removing at least a portion of the catalyst material from the interstitial spaces to a substantially uniform depth from the face of the polycrystalline material comprises removing a portion of the catalyst material to a substantially uniform depth of between about twenty-five micrometers (25 μm) and about one hundred micrometers (100 μm) from the face of the polycrystalline material.
5. The method of claim 3 , wherein removing at least a portion of the catalyst material from the interstitial spaces to a substantially uniform depth from the face of the polycrystalline material comprises removing a portion of the catalyst material to a substantially uniform depth of at least about 100 micrometers (100 μm) from the face of the polycrystalline material.
6. A method of forming a polycrystalline compact cutting element, comprising:
at least partially melting a reactive material by heating the reactive material to a temperature of at least about two hundred degrees Celsius (200° C.);
introducing a melted portion of the reactive material to a polycrystalline compact comprising a catalyst material dispersed throughout a plurality of interstitial spaces between inter-bonded grains of a polycrystalline material; and
removing at least a portion of the catalyst material from at least a portion of the plurality of interstitial spaces with the reactive material.
7. The method of claim 6 , wherein at least partially melting a reactive material by heating the reactive material to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating a reactive material comprising at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass to a temperature of at least about two hundred degrees Celsius (200° C.).
8. The method of claim 7 , wherein heating a reactive material comprising at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass to a temperature of between about three hundred degrees Celsius (300° C.) and about seven hundred fifty degrees Celsius (750° C.).
9. The method of claim 7 , wherein heating a reactive material comprising at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass and a sodium material to a temperature of at least about two hundred degrees Celsius (200° C.).
10. The method of claim 9 , wherein heating at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass and a sodium material to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating at least one of a silicate glass, a borosilicate glass, an aluminosilicate glass, a high silica glass, a phosphosilicate glass, or a borophosphosilicate glass and at least one of sodium hydroxide, sodium carbonate, sodium borohydrate, or sodium chloride to a temperature of at least about two hundred degrees Celsius (200° C.).
11. The method of claim 6 , wherein at least partially melting a reactive material by heating the reactive material to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating a reactive material comprising an ionic compound to a temperature of at least about two hundred degrees Celsius (200° C.).
12. The method of claim 11 , wherein heating a reactive material comprising an ionic compound to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating an ionic compound comprising at least one of a nitrate, a fluoroborate, an ethanoate, a hexafluorophosphate, or a halide to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about four hundred degrees Celsius (400° C.).
13. The method of claim 11 , wherein heating a reactive material comprising an ionic compound to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating an ionic compound comprising an alkali metal salt to a temperature of at least about two hundred degrees Celsius (200° C.).
14. The method of claim 13 , wherein heating an ionic compound comprising an alkali metal salt to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating an alkali metal salt comprising at least one of lithium, sodium, potassium, rubidium, cesium, or francium to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about four hundred degrees Celsius (400° C.).
15. The method of claim 6 , wherein at least partially melting a reactive material by heating the reactive material to a temperature of at least about two hundred degrees Celsius (200° C.) comprises heating a reactive material comprising a rare earth element to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about one thousand degrees Celsius (1000° C.).
16. The method of claim 15 , wherein heating a reactive material comprising a rare earth element to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about one thousand degrees Celsius (1000° C.) comprises heating a eutectic composition comprising a rare earth element to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about one thousand degrees Celsius (1000° C.).
17. The method of claim 16 , wherein heating a eutectic composition comprising a rare earth element to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about one thousand degrees Celsius (1000° C.) comprises heating a eutectic composition comprising cobalt to a temperature of at least about two hundred degrees Celsius (200° C.) and less than about one thousand degrees Celsius (1000° C.).