Stainless separator for fuel cell and method of manufacturing the same
A stainless steel separator for fuel cells and a method of manufacturing the same are disclosed. The method includes preparing a stainless steel sheet as a matrix, performing surface modification on a surface of the stainless steel sheet to form a Cr-rich passive film having a comparatively increased amount of Cr in a superficial layer of the stainless steel sheet by decreasing an amount of Fe in the superficial layer of the stainless steel sheet, and forming a coating layer on the surface of the surface-modified stainless steel sheet. The coating layer is one selected from a metal nitride layer (MN x ), a metal/metal nitride layer (M/MN x ), a metal carbide layer (MC y ), and a metal boride layer (MB) (where 0.5≦x≦1, 0.42≦y≦1, 0.5≦z≦2).
1. A stainless steel separator for fuel cells, the separator comprising:
a stainless steel sheet having a matrix structure;
a Cr-rich passive film directly formed on a surface of the stainless steel sheet, and containing 20˜75 wt % chromium; and
a coating layer disposed directly on the Cr-rich passive film,
wherein the coating layer is a metal boride layer (MB z ), and 0.5≦z≦2, and
wherein the stainless steel separator is heat treated at 100˜300° C. under vacuum, in air or in an inert gas atmosphere.
2. The stainless steel separator according to claim 1 , wherein the passive film has a (Cr+Ni)/Fe ratio of 1 or more in terms of atomic weight ratio.
3. The stainless steel separator according to claim 1 , wherein the stainless steel separator has a corrosion current density less than 1 μA/cm 2 and a contact resistance less than 20 mΩ·cm 2 on both surfaces thereof.