Zinc-plated steel sheet for hot pressing having outstanding surface characteristics, hot-pressed moulded parts obtained using the same, and a production method for the same
Provided is a zinc-plated steel sheet for hot pressing having outstanding surface characteristics, comprising: a steel foundation plate comprising a metal surface diffusion layer of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, an aluminum-rich layer containing at least 30 wt. % of aluminum formed on the surface diffusion layer, and a zinc plating layer formed on the aluminum-rich layer. In this way, a metal having a low affinity for oxygen is coated to an effective thickness prior to annealing and thus the creation of annealing oxides at the surface of the steel sheet is suppressed and a uniform zinc plating layer is formed, and alloying of the zinc plating layer is promoted during press-processing heat treatment. Cracking in the steel foundation plate during hot press molding is prevented.
1. A hot-pressed part comprising:
a base steel sheet;
a zinc plating layer including a Fe—Zn phase having a metal, in which a reduced amount of Gibbs free energy for one mole of oxygen during an oxidation reaction is smaller than that of Cr, dissolved in an amount of about 0.008 wt % or more formed on the base steel sheet; and
an oxide layer having an average thickness range of about 0.01 μm to about 5 μm formed on the zinc plating layer,
wherein the oxide layer comprises a continuous coating layer having an average thickness range of about 10 nm to about 300 nm, the continuous coating layer comprising one or more oxides selected from the group consisting of SiO 2 and Al 2 O 3 , and
an oxide including ZnO and MnO is formed on the continuous coating layer.
2. The hot-pressed part of claim 1 , wherein the oxide layer comprises ZnO and comprises about 0.01 wt % to about 50 wt % of one or more oxides selected from the group consisting of MnO, SiO 2 , and Al 2 O 3 .
3. The hot-pressed part of claim 2 , wherein a content of MnO in the oxide is smaller than that of ZnO in the oxide.
4. The hot-pressed part of claim 1 , wherein the oxide layer comprises about 10 wt % or less of FeO.
5. The hot-pressed part of claim 1 , wherein a zinc diffusion phase non-uniformly exists at an upper portion of the base steel sheet.
6. The hot-pressed part of claim 5 , wherein an average thickness of the zinc diffusion phase is about 5 μm or less.
7. The hot-pressed part of claim 1 , wherein a Zn content of the zinc plating layer is about 30 wt % or more.
8. The hot-pressed part of claim 7 , wherein a thickness of the zinc plating layer is about 1.5 times larger than that before hot press forming.
9. The hot-pressed part of claim 1 , wherein a ratio of an alloy phase having a Fe content of about 60 wt % or more in the zinc plating layer is about 70 wt % or more with respect to the total zinc plating layer.
10. The hot-pressed part of claim 1 , wherein the metal, in which a reduced amount of Gibbs free energy for one mole of oxygen during an oxidation reaction is smaller than that of Cr, is one or more selected from the group consisting of Ni, Fe, Co, Cu, Sn, and Sb.
11. The hot-pressed part of claim 6 , wherein the base steel sheet comprises about 0.1 wt % to about 0.4 wt % of C, about 2.0 wt % or less (excluding 0 wt %) of Si, about 0.1 wt % to about 4.0 wt % of Mn, and Fe as well as unavoidable impurities as a remainder.
12. The hot-pressed part of claim 1 , wherein the base steel sheet further comprises one or more selected from the group consisting of about 0.001% to about 0.02% of N, about 0.0001% to about 0.01% of B, about 0.001% to about 0.1% of Ti, about 0.001% to about 0.1% of Nb, about 0.001% to about 0.1% of V, about 0.001% to about 1.0% of Cr, about 0.001% to about 1.0% of Mo, about 0.001% to about 0.1% of Sb, and about 0.001% to about 0.3% of W.