Apparatus and process for gasification of carbonaceous materials to produce syngas
View Patent ↗A process and apparatus are provided for gasification of a carbonaceous material. The process produces a raw syngas that can be further processed in a tar destruction zone to provide a hot syngas. The process includes contacting said carbonaceous material with molecular oxygen-containing gas in a gasification zone to gasify a portion of said carbonaceous material and to produce a first gaseous product. A remaining portion of the carbonaceous material is contacted with molecular oxygen-containing gas in a burn-up zone to gasify additional portion of the carbonaceous material and to produce a second gaseous product and a solid ash. The first gaseous product and said second gaseous product are combined to produce a raw syngas that includes carbon monoxide (CO), carbon dioxide (CO 2 ) and tar. The raw syngas is contacted with molecular oxygen containing gas in a tar destruction zone to produce said hot syngas.
1. A gasification apparatus comprising:
a gasification zone that includes one or more hearths effective for distributing a molecular oxygen containing gas horizontally inside one or more of the gasification hearths, wherein the gasification zone is a cross flow unit;
a burn-up zone continuous with the gasification zone, the burn-up zone including one or more hearths effective for distributing a molecular oxygen containing gas vertically inside one or more of the burn-up hearths, wherein the burn-up zone is a counter current unit,
wherein the gasification and burn-up zones are effective for providing a raw syngas having a CO/CO 2 molar ratio greater than about 0.75 and ratio of carbon content of solid ash to carbon content of carbonaceous material feed is less than about 0.1; and
a tar destruction zone effective for receiving the raw syngas from the gasification and burn-up zones through a connecting zone, wherein the connecting zone includes at least one gas inlet.
2. The gasification apparatus of claim 1 wherein the gasification zone includes up to 10 hearths.
3. The gasification apparatus of claim 1 wherein the burn-up zone includes up to 5 hearths.
4. The gasification apparatus of claim 1 further comprising at least one solids transfer device effective for moving carbonaceous material from the gasification zone to the burn-up zone.
5. The gasification apparatus of claim 1 further comprising at least one gas inlet in the gasification zone, burn-up zone and tar destruction zone.
6. The gasification apparatus of claim 4 wherein the at least one solids transfer device is a transfer ram.
7. A gasification apparatus comprising:
a gasification zone that includes one or more hearths effective for distributing a molecular oxygen containing gas horizontally inside one or more of the gasification hearths;
a burn-up zone continuous with the gasification zone, the burn-up zone including one or more hearths effective for distributing a molecular oxygen containing gas vertically inside one or more of the burn-up hearths, wherein the gasification and burn-up zones are effective for providing a raw syngas having a CO/CO 2 molar ratio greater than about 0.75 and ratio of carbon content of solid ash to carbon content of carbonaceous material feed is less than about 0.1; and
a tar destruction zone effective for receiving the raw syngas from the gasification and burn-up zones through a connecting zone, wherein the connecting zone includes at least one gas inlet;
wherein the gasification zone is a cross flow moving bed unit and the burn-up zone is a counter current unit with gas flowing upward and solid moving downward.