Ceramic to ceramic joining method
View Patent ↗The present invention provides a ceramic to ceramic joint and methods for making such a joint. Generally, the joint includes a first ceramic part and a second ceramic part, wherein the first and second ceramic parts each include a ceramic-carbide or a ceramic-nitride material. In some cases, an aluminum-initiated joint region joins the first and second ceramic parts. This joint region typically includes chemical species from the first and second ceramic parts that have diffused into the joint region. Additionally, the first and second ceramic parts each typically include a joint diffusion zone that is disposed adjacent to the joint region and which includes aluminum species from the joint region that have diffused into the joint diffusion zone. Other implementations are also described.
1. A method of forming a ceramic to ceramic joint comprising:
obtaining a first ceramic part and a second ceramic part, wherein the first and second ceramic parts are direct-sintered silicon carbide;
positioning a joint initiator within a joint region between and adjacent the first ceramic part and the second ceramic part, wherein the joint initiator comprises aluminum and has a thickness greater than about 5 μm and less than about 30 μm; and
heating the joint initiator and the first and second ceramic parts adjacent to the joint initiator to a temperature greater than about 700° C. for a time period sufficient to cause diffusion from the joint initiator into the first and second ceramic parts and counter-diffusion of chemical species from the first and second ceramic parts into the joint initiator to form a multi-phase, ceramic joint region having a thickness of about 3 μm to about 5 μm.
2. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator and the first and second ceramic parts adjacent to the joint initiator are heated to a temperature greater than about 800° C.
3. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator and the first and second ceramic parts adjacent to the joint initiator are heated to a temperature greater than about 900° C.
4. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator and the first and second ceramic parts adjacent to the joint initiator are heated to a temperature greater than about 1000° C.
5. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator comprises undoped aluminum.
6. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator has a thickness of less than about 25 μm.
7. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator comprises aluminum ink.
8. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator comprises aluminum powder.
9. The method of forming a ceramic to ceramic joint according to claim 1 , further comprising applying a load to the joint region during the heating step.
10. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step comprises heating within a thermally insulated container.
11. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step comprises localized heating by a torch.
12. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step comprises resistive heating.
13. The method of forming a ceramic to ceramic joint according to claim 1 , wherein diffusion and counter-diffusion of chemical species between the joint initiator and the adjoining first and second ceramic parts comprises diffusing free aluminum from the joint initiator to at least one of the adjoining first and second ceramic parts.
14. The method of forming a ceramic to ceramic joint according to claim 1 , further comprising increasing the joint region's ability to resist oxidation by repeating the heating step and causing additional diffusion and counter-diffusion of the chemical species in the joint region.
15. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step is performed in ambient air.
16. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step is performed in atmospheric pressure.
17. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the heating step is performed in the absence of a vacuum.
18. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the multi-phase, ceramic joint region comprises an aluminum silicon oxycarbide, multi-phase material.
19. The method of forming a ceramic to ceramic joint according to claim 1 , wherein the joint initiator has a thickness of about 25 μm±5 μm.