Composite ballistic resistant laminate
View Patent ↗An impact penetration resistant laminate comprises a plurality of alternating layers of (i) non-fibrous ultra-high molecular weight polyethylene monolayers and (ii) a thermoplastic adhesive, the adhesive having a basis weight of no greater than 5 gsm and a zero-shear-rate viscosity, determined from an oscillating disc rheometer in a frequency sweep between 0.1 rad/s and 100 rad/s, conducted per ASTM D 4440 at 125° C., and calculated from fitting to a Carrea-Yasuda four parameter model, of at least 1500 Pa-s, wherein (a) at least 90 percent of the monolayers are arranged such that the orientation of one monolayer is offset with respect to the orientation of an adjacent monolayer, and (b) the modulus of elasticity through the thickness of the laminate is at least 3 GPa.
1. A consolidated impact penetration resistant laminate comprising a plurality of alternating layers of (i) non-fibrous ultra-high molecular weight polyethylene monolayers and (ii) a thermoplastic adhesive, the adhesive having a basis weight of no greater than 5 gsm and a zero-shear-rate viscosity, determined from an oscillating disc rheometer in a frequency sweep between 0.1 rad/s and 100 rad/s, conducted per ASTM D 4440 at 125° C., and calculated from fitting to a Carrea-Yasuda four parameter model, of at least 10,000 Pa-s, wherein
(a) at least 90 percent of the monolayers are arranged such that the orientation of one monolayer is offset with respect to the orientation of an adjacent monolayer, and
(b) the modulus of elasticity through the thickness of the laminate, as measured by Test Method A, is at least 3 GPa.
2. The laminate of claim 1 wherein the modulus of elasticity through the thickness of the laminate is at least 3.2 GPa.
3. The laminate of claim 1 wherein the adhesive further comprises a thixotrope.
4. The laminate of claim 1 wherein adjacent monolayers have an orientation that is essentially orthogonal to each other.
5. The laminate of claim 2 wherein the modulus of elasticity through the thickness of the laminate is at least 3.5 GPA.
6. The laminate of claim 1 wherein the adhesive has a zero-shear-rate viscosity of at least 100,000 Pa-s.
7. The laminate of claim 5 wherein the modulus of elasticity through the thickness of the laminate is at least 4 GPa.
8. The laminate of claim 6 wherein the adhesive has a zero-shear-rate viscosity of at least 1,000,000 Pa-s.
9. The laminate of claim 3 wherein the thixotrope is an organic dendritic or inorganic particle.