IP Library Granted Patent US 9,822,287
Granted Patent B2
US 9,822,287 · App. 14/710,986 · Granted Nov 21, 2017

Adhesive composition and endoscope device

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Quick Facts
Patent No.
US 9,822,287
App. No.
14/710,986
Granted
Nov 21, 2017
Kind
B2
Abstract

An adhesive composition comprising a main agent including at least one epoxy resin selected from a bisphenol A epoxy resin, a bisphenol F epoxy resin, and a phenol novolac epoxy resin, and an acrylic rubber; a curing agent including xylylene diamine; and a filler including silica. The adhesive composition further comprises an ion exchanger.

Claims (24)

1. An adhesive composition comprising:

a main agent comprising an acrylic rubber and an epoxy resin, wherein the epoxy resin is selected from the group consisting of a bisphenol A epoxy resin, a bisphenol F epoxy resin, and a phenol novolac epoxy resin, and combinations thereof;

a curing agent containing xylylene diamine;

a filler containing silica; and

an organic ion exchanger comprising at least one of styrene, divinyl benzene, and derivatives thereof.

2. The adhesive composition according to claim 1 , wherein the organic ion exchanger is contained in a content of 0.8 to 12 parts by mass based on 100 parts by mass of the main agent.

3. An endoscope device comprising at least two constituent members bonded to each other through an adhesive layer obtained by curing an adhesive composition according to claim 1 .

4. An endoscope device comprising at least two constituent members bonded to each other through an adhesive layer obtained by curing an adhesive composition according to claim 2 .

5. The adhesive composition according to claim 1 , wherein the acrylic rubber has an average particle size of 300 nm or less.

6. The adhesive composition according to claim 1 , wherein the acrylic rubber is contained in a content of about 1 to 20 parts by mass based on 100 parts by mass of the main agent.

7. The adhesive composition according to claim 1 , wherein the acrylic rubber is contained in a content of about 5 to 15 parts by mass based on 100 parts by mass of the main agent.

8. The adhesive composition according to claim 1 , wherein the epoxy resin is selected from the group consisting of bisphenol A epoxy resin, bisphenol F epoxy resin, and phenol novolac epoxy resin.

9. The adhesive composition according to claim 1 , wherein the bisphenol A epoxy resin is contained in a content of about 20 to 70 parts by weight, based on 100 parts by mass of the main agent.

10. The adhesive composition according to claim 1 , wherein the bisphenol A epoxy resin is contained in a content of 30 to 60 parts by weight, based on 100 parts by mass of the main agent.

11. The adhesive composition according to claim 1 , wherein the bisphenol F epoxy resin is contained in a content of about 10 to 60 parts by weight, based on 100 parts by mass of the main agent.

12. The adhesive composition according to claim 1 , wherein the bisphenol F epoxy resin is contained in a content of about 30 to 60 parts by weight, based on 100 parts by mass of the main agent.

13. The adhesive composition according to claim 1 , wherein the phenol novolac epoxy resin is contained in a content of about 20 to 40 parts by weight, based on 100 parts by mass of the main agent.

14. The adhesive composition according to claim 1 , wherein the phenol novolac epoxy resin is contained in a content of about 30 parts by weight, based on 100 parts by mass of the main agent.

15. The adhesive composition according to claim 1 , wherein the xylylene diamine is contained in a content of about 10 to 99% by mass of the total amount of the curing agent.

16. The adhesive composition according to claim 1 , wherein the xylylene diamine is contained in a content of about 30 to 97% by mass of the total amount of the curing agent.

17. The adhesive composition according to claim 1 , wherein the curing agent further comprises a derivative of xylylene diamine.

18. The adhesive composition according to claim 17 , wherein the derivative of xylylene diamine is selected from the group consisting of alkylene oxide adducts, glycidyl ester adducts, glycidyl ether adducts, Mannich adducts, acrylonitrile adducts, epichlorohydrin adducts and xylylene diamine trimer.

19. The adhesive composition according to claim 1 , wherein the silica is spherical silica of an average particle size of 4 μm to 7 μm.

20. The adhesive composition according to claim 1 , wherein the silica is contained in a content of 20 to 40 parts by mass, based on 100 parts by mass of the adhesive main agent.

Assignments (2)
CHANGE OF ADDRESS Recorded Jul 3, 2017
From: OLYMPUS CORPORATION
To: OLYMPUS CORPORATION
Reel/Frame 043076/0827 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 13, 2015
From: YOKOYAMA, HIROKI; KOBAYASHI, KOJI; MATSUMOTO, JUN; NAKAMURA, MITSUHIRO
To: OLYMPUS CORPORATION
Reel/Frame 035628/0575 →