Branched broad MWD conjugated diene polymer
View Patent ↗A process is provided for preparing a branched conjugated diene polymer with a molecular weight distribution Mw/Mn of at least 1.1, by anionic polymerization, comprising the following reaction steps: a) polymerizing a mixture of monomers comprising at least one conjugated diene and optionally one or more monoalkenyl arene compounds in the presence of an anionic initiator to form a living polymer; b) terminating the polymerization; and c) optionally functionalizing and/or hydrogenating the polymer so produced, wherein the mixture of monomers comprises an alpha,omega-bis(vinylphenyl)alkane as comonomer. The invention further relates to the polymer so obtained, a latex prepared therefrom, the latex, and articles made from the latex.
1. A process for preparing a branched conjugated diene polymer with a molecular weight distribution Mw/Mn of at least 1.1, by anionic polymerization, comprising the following reaction steps:
a) polymerizing a mixture of monomers comprising at least one conjugated diene and optionally one or more monoalkenyl arene compounds in the presence of an anionic initiator to form a living polymer;
b) terminating the polymerization, and
c) optionally functionalizing and/or hydrogenating the polymer so produced,
wherein the mixture of monomers comprises an alpha,omega-bis(vinylphenyl)alkane as comonomer.
2. The process of claim 1 , wherein the comonomer is 1,2-bis(vinylphenyl)ethane.
3. The process of claim 1 , wherein the comonomer is used in an amount of less than 2.0 mole % of the monomer mixture.
4. The process of claim 1 , wherein the living polymer is prepared by carrying out the polymerization in the presence of a randomizer.
5. The process of claim 4 , wherein the randomizer is a tertiary amine and selected from the group consisting of trimethylamine, triethylamine, dimethylethylamine, tri-n-propylamine, tri-n-butylamine, dimethylaniline, pyridine, quinoline, N-ethylpiperidine, N-methylmorpholine.
6. The process of claim 4 , wherein the randomizer is a thioether selected from the group consisting of dimethyl sulphide, diethyl sulphide, di-n-propyl sulphide, di-n-butyl sulphide, methyl ethyl sulphide.
7. The process of claim 4 , wherein the randomizer is an ether selected from the group consisting of dimethyl ether, methyl ethyl ether, diethyl ether, di-n-propyl ether, di-n-butyl ether, di-octyl ether, di-benzyl ether, di-phenyl ether, anisole, 1,2-dimethyloxyethane, o-dimethoxy benzene, and tetrahydrofuran.
8. The process of claim 4 , wherein the amount of randomizer is from 0.1 to 8.0% by weight on the monomer mixture.
9. The process of claim 1 , wherein the polymerization is carried out at a temperature from about 20 to about 60° C.
10. The process of claim 1 , wherein the conjugated diene is isoprene or a mixture of monomers comprising at least 80 mole % isoprene.
11. A branched conjugated diene polymer, with a molecular weight distribution Mw/Mn of at least 1.1, comprising an alpha,omega-bis(vinylphenyl)alkane built-in as comonomer in the polymer backbone.
12. A process for preparing a conjugated diene polymer latex, by combining a solution of the branched conjugated diene polymer of claim 11 in an organic solvent with water and a soap, and removing the organic solvent.
13. A conjugated diene polymer latex comprising a branched conjugated diene polymer emulsified in water, wherein the conjugated diene polymer is a branched conjugated diene polymer, with a molecular weight distribution Mw/Mn of at least 1.1, comprising an alpha,omega-bis(vinylphenyl)alkane built-in as comonomer in the polymer backbone.
14. An article made from the conjugated diene polymer latex of claim 13 made by dipping.