Resin-polyester blend binder compositions, method of making same and articles made therefrom
View Patent ↗An aqueous binder system including a mixture of urea-formaldehyde resin and water-dispersible polyester resin. A combination of the binder system applied to fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or substrate of a coated abrasive product. Fiber insulation, a composite glass mat, glass/polyester mat, polyester mat, or coated abrasive product with the binder system including urea-formaldehyde resin and water-dispersible polyester.
1. An aqueous binder comprising a mixture of:
a water dispersible urea-formaldehyde resin, and
a water dispersible polyester resin,
wherein said mixture comprises about 10 to about 25 wt % said water dispersible polyester resin based upon the dry weight of the urea-formaldehyde resin, wherein the binder has an absence of phosphate groups, wherein said water dispersible polyester resin has a weight average molecular weight of 10,000 to 500,000, wherein the aqueous binder contains substantially no cross-linking agents, and wherein the urea-formaldehyde resin is not a cross-linking resin for the water dispersible polyester resin.
2. The binder of claim 1 , wherein the aqueous binder contains substantially no cross-linked polymers or unreacted epoxy.
3. The binder of claim 1 , wherein the polyester resin is sulfonated.
4. The binder of claim 1 , wherein the binder system is essentially free from latex.
5. The binder of claim 1 , wherein the polyester resin has a molecular weight of 25,000 to 70,000.
6. The binder of claim 1 , wherein the aqueous binder contains substantially no isocyanates, substantially no phosphate-containing polymer, substantially no epoxy, substantially no hydroxyethyl acrylate, no organic solvent, and no solid particulates.
7. The binder of claim 1 , wherein the aqueous binder contains substantially no polyether polyol and no polyhydroxy polyester.
8. The binder of claim 1 , wherein the aqueous binder contains substantially no cross-linked polymers other than optionally the water dispersible polyester resin cross-linked with itself.
9. The binder of claim 1 , wherein the aqueous binder contains substantially no cross-linked polymers.
10. The binder of claim 1 , wherein the aqueous binder contains substantially no cross-linking agents, substantially no epoxy, substantially no unreacted epoxy, substantially no polyester resins with urethane in the polyester backbone, substantially no phosphate-containing polymer, substantially no hydroxyethyl acrylate, no organic solvent, and/or no solid particulates.
11. The binder of claim 1 , wherein the urea-formaldehyde resin is a modified urea-formaldehyde resin comprising a melamine formaldehyde resin.
12. The binder according to claim 1 , wherein the aqueous binder has a total polymer content of the urea-formaldehyde resin and polyester resin of about 60 weight % or less.
13. The binder of claim 1 , wherein based on the total polymer content of the urea-formaldehyde resin and polyester resin, the binder contains from about 60 weight % to about 80 weight % of the polyester resin and from about 20 weight % to about 40 weight % of the urea-form aldehyde resin.
14. The binder of claim 1 , wherein the polyester resin is a sulfopolyester formed as a polycondensation product of:
(1) a first reaction mixture comprising: (a) at least about 70 mol. % dicarboxylic acid or an ester thereof, and (b) about 4-20 mol. % of a difunctional ester forming sulfomonomer containing at least one metal sulfonate group attached to an aromatic nucleus, and functional groups selected from the group consisting of hydroxyls, carboxyls and alkyl esters for a total of 100 mol %; and
(2) a second reaction mixture comprising ethylene glycol, diethylene glycol and optionally triethylene glycol, for a total of about 100 mol. %.
15. The binder of claim 14 ,
wherein the sulfopolyester has an inherent viscosity of at least about 0.20 dL/g measured at 250° C. in 60/40 parts by weight of a phenol/tetrachloroethane solvent at a concentration of 0.25 g/dL, and
wherein the second reaction mixture comprising ethylene glycol, diethylene glycol and optionally triethylene glycol, at least about 20 mol. % of the second reaction mixture being ethylene glycol.
16. The binder of claim 14 , wherein the dicarboxylic acid or an ester thereof comprises terephthalic acid or an ester thereof and the at least about 20 mol. % of the second reaction mixture is ethylene glycol.
17. The binder of claim 14 , wherein the first reaction mixture (A)(1) further comprises from about 0.1 mol. % to about 5 mol. % of a saturated aliphatic or a saturated alicyclic dicarboxylic acid, or ester thereof.
18. The binder of claim 14 , wherein the mixture of a water dispersible urea-formaldehyde resin and a water dispersible polyester resin further comprises a member of the group consisting of acrylic polymer, styrene butadiene rubber, styrene maleic anhydride, and polyurethane dispersion.
19. The binder of claim 14 , wherein the polyester is a polyester, a polyester acrylic hybrid polymer, a polyester acrylic grafted polymer or a polyester extended with at least one member of the group consisting of polyethylene glycol and polyvinyl alcohol.
20. The binder of claim 14 , wherein the difunctional ester forming sulfomonomer is 5-sodiosulfoisophthalic acid or an ester thereof.
21. The binder of claim 14 , wherein the difunctional ester forming sulfomonomer is 5-sodiosulfoisophthalic acid or an ester thereof, the dicarboxylic acid or an ester thereof comprises terephthalic acid, and the mol. ratio of terephthalic acid to 5-sodiosulfoisophthalie acid is approximately 80-90/20-10.
22. A composite mat comprising the binder system of claim 1 .
23. The composite mat of claim 22 , having a percent retention of at least 50%.
24. A coated abrasive comprising a substrate, a coating on the substrate comprising abrasive particles and the binder system of claim 1 .