Method of making heat treated coated article using carbon based coating and protective film
View Patent ↗A method of making a heat treated (HT) substantially transparent coated article to be used in shower door applications, window applications, tabletop applications, or any other suitable applications. For example, certain embodiments relate to a method of making a coated article including a step of heat treating a glass substrate coated with at least layer of or including carbon (e.g., diamond-like carbon (DLC)) and an overlying protective film thereon. The protective film may be of or include both (a) an oxygen blocking or barrier layer, and (b) a release layer, with the release layer being located between at least the carbon based layer and the oxygen blocking layer. The release layer is of or includes zinc oxynitride (e.g., ZnO x N z ). Following and/or during heat treatment (e.g., thermal tempering, or the like) the protective film may be entirely or partially removed. Other embodiments of this invention relate to the pre-HT coated article, or the post-HT coated article.
1. A method of making a heat treated coated article, the method comprising:
heat treating a coated glass substrate, the coated glass substrate comprising, prior to the heat treating, a glass substrate, a layer comprising diamond-like carbon (DLC) on the glass substrate, and a protective film on the glass substrate over at least the layer comprising DLC, wherein the protective film includes a release layer and an oxygen barrier layer, the release layer and the oxygen barrier layer being of different material, and wherein the release layer comprises zinc oxynitride ZnO x N z where a nitrogen to oxygen ratio z/x in the release layer is from 0.77 to 1.0;
during said heat treating of the coated glass substrate with the layer comprising DLC and the protective film thereon, the protective film prevents significant burnoff of the layer comprising DLC, and wherein the heat treating comprises heating the glass substrate to temperature(s) sufficient for thermal tempering, heat strengthening, and/or heat bending; and
exposing the protective film to a release liquid and removing at least part of the protective film during and/or after said heat treating.
2. The method of claim 1 , wherein the release layer consists essentially of zinc oxynitride doped with aluminum.
3. The method of claim 1 , wherein the protective film further comprises a layer comprising silicon nitride located over at least the oxygen barrier layer.
4. The method of claim 1 , wherein the coated glass substrate further comprises a layer comprising silicon nitride located between the glass substrate and the layer comprising DLC.
5. The method of claim 1 , wherein the oxygen barrier layer comprises aluminum nitride.
6. The method of claim 1 , wherein the release layer and the oxygen barrier layer directly contact each other.
7. The method of claim 1 , wherein the layer comprising DLC comprises amorphous DLC and has more sp 3 carbon-carbon bonds than sp 2 carbon-carbon bonds.
8. The method of claim 1 , wherein the layer comprising DLC has an average hardness of at least 20 GPa.
9. The method of claim 1 , wherein the layer comprising DLC is hydrogenated.
10. The method of claim 1 , wherein the coated article is substantially transparent at least following heat treating and removal of the protective film.
11. A method of making a heat treated coated article, the method comprising:
heat treating a coated glass substrate, the coated glass substrate comprising, prior to the heat treating, a glass substrate, a layer comprising diamond-like carbon (DLC) on the glass substrate, and a protective film on the glass substrate over at least the layer comprising DLC, wherein the protective film includes a release layer and an oxygen barrier layer, the release layer and the oxygen barrier layer being of different material, and wherein the release layer comprises zinc oxynitride ZnO x N z where a nitrogen to oxygen ratio z/x in the release layer is from 0.77 to 1.0;
during said heat treating of the coated glass substrate with the layer comprising DLC and the protective film thereon, the protective film prevents significant burnoff of the layer comprising DLC;
wherein the heat treating comprises using temperature(s) of at least 580 degrees C.; and
removing at least part of the protective film during and/or after said heat treating.
12. The method of claim 11 , wherein the release layer consists essentially of zinc oxynitride doped with aluminum.
13. The method of claim 11 , wherein the protective film further comprises a layer comprising silicon nitride located over at least the oxygen barrier layer.
14. The method of claim 11 , wherein the coated glass substrate further comprises a layer comprising silicon nitride located between the glass substrate and the layer comprising DLC.
15. The method of claim 11 , wherein the oxygen barrier layer comprises aluminum nitride.
16. The method of claim 11 , wherein the release layer and the oxygen barrier layer directly contact each other.
17. The method of claim 11 , wherein the coated article is substantially transparent at least following heat treating and removal of the protective film.