IP Library Granted Patent US 11,718,067
Granted Patent B2
US 11,718,067 · App. 14/720,374 · Granted Aug 8, 2023

Composite material

Inventors: Zachary R. Greenhill (Rye, NY); Joseph J. Belbruno (Hanover, NH); Yuval Avniel (Missoula, MT)
Assignee: Greenhill Antiballistics Corporation
B32B5/30A42B3/12B32B1/00B32B1/08B32B5/16B32B27/30B32B27/302B32B27/36B32B27/365B32B27/38B32B27/40B32B27/42F41H5/0492F42D5/045B32B2307/306B32B2307/3065B32B2307/41B32B2307/412B32B2307/56B32B2307/7265B32B2307/73B32B2457/00B32B2571/00B32B2605/00Y10T428/249971Y10T428/249997Y10T428/25Y10T428/254Y10T428/259
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Quick Facts
Patent No.
US 11,718,067
App. No.
14/720,374
Granted
Aug 8, 2023
Kind
B2
Abstract

Disclosed herein are engineered composite materials suitable for applications that can benefit from a composite material capable of interacting with or responding to, in a controlled or pre-determined manner, changes in its surrounding environment, such as to attenuate a compression wave. The composite material generally includes a plurality of repeating units, with each repeating unit including a first layer of particles having a first mean diameter, and a second layer of particles having a second mean diameter, and an intermediary material that allows mobility of and contact between the first particles within the first layer and mobility of and contact between the second particles within the second layer; the contact allowing momentum transfer between the particles. The first mean diameter and second mean diameter are different and are less than 500 nm. The first or second particles may be core-shell particles having a core that is partly or completely filled with a liquid, a gas and/or a gel, such as a fire suppressant, a medically active agent or a dye.

Claims (26)

1. A composition comprising:

a plurality of repeating units, wherein each of the plurality of repeating units comprises:

a first layer of first particles having a first mean diameter, and

a second layer of second particles having a second mean diameter; and an intermediary material selected from the list consisting of ionomers, polymers, polymerizable monomers, resins, cyclodextrins or combinations thereof,

wherein said intermediary material allows mobility of and contact between the first particles within the first layer and mobility of and contact between the second particles within the second layer, whereby said contact allows momentum transfer between said particles, and

wherein the first mean diameter and the second mean diameter are different and are less than 500 nm; and

wherein the first particles or the second particles are core-shell particles having a core that is partly or completely filled with a liquid, a gas and/or a gel; and

wherein the composition attenuates a compression wave.

2. The composition of claim 1 , wherein the first particles or the second particles are polystyrene.

3. The composition of claim 1 , wherein the first particles or the second particles are silica.

4. The composition of claim 3 , wherein the first particles or the second particles are polarized.

5. The composition of claim 1 , wherein the first particles or the second particles contain metal.

6. The composition of claim 5 , wherein the first particles or the second particles are copper.

7. The composition of claim 1 , wherein a composition of the first particles and a composition of the second particles are different.

8. The composition of claim 1 , wherein at least a portion of the first particles in the first layer contact at least a portion of the second particles in the second layer.

9. The composition of claim 1 , wherein at least a portion of the first particles or the second particles of a repeating unit are in contact with at least a portion of adjacent first particles or adjacent second particles of an adjacent repeating unit.

10. The composition of claim 1 , further comprising a binding layer between a repeating unit and an adjacent repeating unit.

11. The composition of claim 1 , wherein at least one of the plurality of repeating units is in contact with a substrate.

12. The composition of claim 11 , wherein the substrate is at least a portion of an electronic device.

13. The composition of claim 11 , wherein the substrate is glass.

14. The composition of claim 1 , wherein the first mean diameter and the second mean diameter are less than 250 nm.

15. The composition of claim 1 , wherein at least one of the plurality of repeating units comprises a third layer of third particles of a third mean diameter.

16. The composition of claim 1 , wherein the first particles or the second particles comprise a binding coating.

17. The composition of claim 16 , wherein the binding coating is hydrophobic.

18. The composition of claim 1 , wherein the composition is transparent.

19. The composition of claim 1 , wherein the core-shell particles are partly or completely filled with a fire suppressant, a foaming agent, a medically active agent or a dye.

Assignments (3)
CHANGE OF ASSIGNEE ADDRESS Recorded Jun 4, 2018
From: GREENHILL ANTIBALLISTICS CORPORATION
To: GREENHILL ANTIBALLISTICS CORPORATION
Reel/Frame 046291/0908 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED AT REEL: 035714 FRAME: 0460. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jun 9, 2015
From: GREENHILL, ZACHARY R.; BELBRUNO, JOESEPH J.; AVNIEL, YUVAL
To: GREENHILL ANTIBALLISTICS CORPORATION
Reel/Frame 035871/0133 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 26, 2015
From: GREENHILL, ZACHARY R.; BELBRUNO, JOSEPH J.; AVNIEL, YUVAL
To: GREENHILL ANTIBALLISTICS CORPORATION
Reel/Frame 035714/0460 →
Continuity (9)
Continuation 12672865
Continuation In Part PCTUS2008072808 · Aug 11, 2008
Continuation In Part PCTUS2009053465 · Aug 11, 2009
Continuation In Part PCTUS2008072808 · Aug 11, 2008
Provisional Application 61153539 · Feb 18, 2009
Provisional Application 61031913 · Feb 27, 2008
Provisional Application 60955335 · Aug 10, 2007
Related Publication 20160159033A1 · Jun 9, 2016
Related Publication 20210086475A9 · Mar 25, 2021
Cited By (1)
US 12,191,228