Method for controlling aluminum dissolution
View Patent ↗A process for controlling the dissolution of a metal in an acid bath is described. The metal may comprise aluminum and the acid bath may contain a metal catalyst that causes the metal to dissolve. In order to control the rate of dissolution, the metal can be contacted with a cathodic member. In one embodiment, the process can be completely stopped even without removing the metal from the acid bath. The cathodic member provides anodic protection to the metal. In one embodiment, the cathodic member is made from a nickel-chromium-based alloy.
1. A process for dissolving aluminum during the recovery of a nuclear fuel comprising:
contacting a material containing aluminum and a nuclear fuel with a heated dissolution solution comprising an acid and a metal catalyst, the acid and the metal catalyst dissolving the aluminum; and
contacting the aluminum with a cathodic member, the cathodic member comprising a material capable of forming a galvanic couple with aluminum, the cathodic member contacting a sufficient amount of surface area of the aluminum so as to decrease the dissolution rate of aluminum in the dissolution solution.
2. A process as defined in claim 1 , wherein contacting the aluminum with the cathodic member reduces the dissolution rate of aluminum by at least 20%.
3. A process as defined in claim 1 , wherein the cathodic member provides protection to the aluminum and prevents the aluminum from dissolving in the acid.
4. A process as defined in claim 1 , wherein the cathodic member comprises a material that does not dissolve in the acid.
5. A process as defined in claim 1 , wherein the cathodic member comprises a metallic material.
6. A process as defined in claim 1 , wherein the cathodic member comprises an alloy.
7. A process as defined in claim 1 , wherein the cathodic member comprises graphite.
8. A process as defined in claim 1 , wherein the cathodic member comprises gold, platinum, titanium, a stainless steel alloy, a nickel-copper alloy, or mixtures thereof.
9. A process as defined in claim 1 , wherein the cathodic member comprises a nickel-chromium-based alloy.
10. A process as defined in claim 1 , wherein the cathodic member comprises an austenitic super alloy containing from about 40% to about 80% nickel and from about 10% to about 30% chromium.
11. A process as defined in claim 1 , wherein the acid comprises nitric acid.
12. A process as defined in claim 11 , wherein the initial nitric acid concentration in the dissolution solution is from about 4 molar to about 15 molar.
13. A process as defined in claim 1 , wherein the metal catalyst comprises mercury.
14. A process as defined in claim 13 , wherein the mercury concentration in the dissolution solution is from about 0.001 molar to about 0.02 molar.
15. A process as defined in claim 1 , wherein the nuclear fuel comprises a used nuclear fuel.
16. A process as defined in claim 1 , wherein the material containing aluminum and a nuclear fuel comprises an aluminum-uranium alloy or a uranium aluminide dispersed in a continuous aluminum phase.
17. A process as defined in claim 1 , wherein the nuclear fuel comprises uranium, plutonium, or mixtures thereof.
18. A process as defined in claim 1 , wherein the material containing aluminum and a nuclear fuel comprises a fuel assembly, the fuel assembly being lowered into a heated bath containing the acid and the metal catalyst, the fuel assembly being contacted by the cathodic member within the bath.
19. A process as defined in claim 16 , wherein the material containing aluminum and the nuclear fuel comprises a core surrounded by an aluminum cladding, the core comprising the aluminum-uranium alloy or the uranium aluminide dispersed in a continuous aluminum phase.