Lithium secondary battery
View Patent ↗A lithium secondary battery includes a positive electrode, a negative electrode, and a non-aqueous electrolyte, and more particularly, the positive electrode includes a positive active material including lithium-metal oxide in which at least one metal has a continuous concentration gradient from the center to the surface, and the negative electrode includes a negative active material including graphite having an average lattice distance (d 002 ) in the range of 3.356 to 3.365 Å, thereby improving storage characteristics at a high temperature and lifetime characteristics.
1. A lithium secondary battery comprising:
a positive electrode;
a negative electrode; and
a non-aqueous electrolyte,
wherein the positive electrode includes a positive active material including a lithium-metal oxide represented by the following chemical formula 1,
Li x M1 a M2 b M3 c O y chemical formula 1
wherein M1, M2, and M3 are selected from the group consisting of Ni, Co, Mn, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga, and B,
wherein 0<x≤1.1, 2≤y≤2.02, 0<a<1, 0<b<1, 0<c<1, and 0<a+b+c≤1,
wherein M3 has a concentration gradient range in which a concentration increases continuously from a center of the positive active material to a surface of the positive active material,
wherein M1 has a concentration gradient range in which a concentration decreases continuously from the center of the positive active material to the surface of the positive active material,
wherein M2 has a constant concentration from the center of the positive active material to the surface of the positive active material, and
wherein the negative electrode includes a negative active material including graphite which is a blending of a first graphite including a natural graphite and having an average lattice distance (d 002 ) in a range of 3.356 to 3.360 Å, and a second graphite including an artificial graphite and having an average lattice distance (d 002 ) in a range of 3.361 to 3.365 Å.
2. The lithium secondary battery of claim 1 , wherein the M1, M2, and M3 are Ni, Co, and Mn, respectively.
3. The lithium secondary battery of any one of claim 2 , wherein the M1 is Ni, and 0.6≤a≤0.95 and 0.05≤b+c≤0.4.
4. The lithium secondary battery of any one of claim 2 , wherein the M1 is Ni, and 0.7≤a≤0.9 and 0.1≤b+c≤0.3.
5. The lithium secondary battery of claim 1 , wherein a shape of primary particles of the lithium-metal oxide is a rod type.
6. The lithium secondary battery of claim 1 , wherein a blending weight ratio of the first graphite and the second graphite is in a range of 0:100 to 90:10.
7. The lithium secondary battery of claim 1 , wherein a blending weight ratio of the first graphite and the second graphite is in a range of 0:100 to 50:50.