IP Library Granted Patent US 10,226,762
Granted Patent B1
US 10,226,762 · App. 14/739,431 · Granted Mar 12, 2019

Alumina binders for SCR catalysts

Inventors: Stuart David Reid (Cambourne, GB); Alexander Nicholas Michael Green (Baldock, GB); Guy Richard Chandler (Cambridge, GB)
Assignee: Johnson Matthey Public Limited Company
B01J29/763B01J29/80B01J35/0013B01J35/04B01J29/7215
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Quick Facts
Patent No.
US 10,226,762
App. No.
14/739,431
Granted
Mar 12, 2019
Kind
B1
Abstract

Provided is a catalytic washcoat having a catalyst component and an alumina binder, wherein the catalyst component includes an aluminosilicate molecular sieve having a beta (BEA) and/or chabazite (CHA) framework, and about 1 to about 10 weight percent of a base metal component comprising iron and/or copper, wherein said weight percent is based on the weight of the aluminosilicate molecular sieve.

Claims (13)

1. A catalytic article:

a. a honeycomb substrate;

b. a catalyst washcoat disposed on and/or within the substrate, wherein the catalyst washcoat comprises (i) an aluminosilicates molecular sieve having an AEI framework and about 1 to about 10 weight percent of at least one base metal component selected from iron and copper, wherein said weight percent is based on the weight of the aluminosilicate molecular sieve; and (ii) about 1 to about 30 weight percent of a binder consisting essentially of alumina, wherein said weight percent is based on the weight of the aluminosilicate molecular sieve,

wherein the catalytic article has been hydrothermally aged, and upon hydrothermal aging, the catalytic article provides higher NOx conversion than a comparable article having a silica binder.

2. The catalytic article of claim 1 , wherein said alumina is γ-alumina.

3. The catalytic article of claim 1 , wherein said alumina is derived from boehmite.

4. The catalytic article of claim 1 , wherein said alumina in said washcoat has a mean disperse particle size of about 60 to about 120 nm.

5. The catalytic article of claim 1 , wherein said alumina in said washcoat has a mean crystallite size of about 5 to about 15 nm.

6. The catalytic article of claim 1 , wherein said alumina binder in said washcoat is present in an amount of about 10 to about 20 weight percent based on the weight of the aluminosilicate molecular sieve.

7. The catalytic article of claim 1 , wherein said aluminosilicate molecular sieve has a silica-to-alumina ratio of about 15 to about 250.

8. The catalytic article of claim 7 , wherein said base metal is copper.

9. The catalytic article of claim 1 , wherein said honeycomb substrate is a flow-through monolith.

10. The catalytic article of claim 1 , wherein said honeycomb substrate is a wall-flow filter.

Assignments (2)
CHANGE OF ADDRESS Recorded Jan 14, 2026
From: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 074703/0733 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 27, 2015
From: REID, STUART DAVID; GREEN, ALEXANDER NICHOLAS MICHAEL; CHANDLER, GUY RICHARD
To: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
Reel/Frame 036186/0367 →
Continuity (3)
Continuation 13465564 · May 7, 2012
Continuation 13355078 · Jan 20, 2012
Provisional Application 61498322 · Jun 17, 2011