Ionomer-poly(vinylalcohol) coated substrates
View Patent ↗Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 15 centipoise (cp) or less; or (ii) a hydrolysis level of about 95 mol % to 100%; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.
1. A multilayer structure comprising a coated substrate comprising a surface layer on the substrate and the surface layer comprises a blend composition comprising
(a) about 99 to about 1 weight %, based on the combination of (a) and (b), of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by
(i) a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 15 centipoise (cp) or less; or
(ii) a hydrolysis level of about 95 mol % to 100%; and
(b) about 1 to about 99 weight %, based on the combination of (a) and (b), of an ionomer composition consisting essentially of a parent acid copolymer that consists essentially of copolymerized units of ethylene and about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate (MFR) from about 200 to about 1000 g/10 min., measured according to ASTM D1238 at 190° C. with a 2160 g load, wherein about 50% to about 70% of the carboxylic acid groups of the copolymer, based on the total carboxylic acid content of the parent acid copolymer as calculated for the non-neutralized parent acid copolymer, are neutralized to carboxylic acid salts consisting essentially of potassium cations, sodium cations or combinations thereof, without the use of ammonia.
2. The multilayer structure of claim 1 wherein the ionomer composition has a MFR from about 1 to about 20 g/10 min.
3. The multilayer structure of claim 1 wherein the acid copolymer has a MFR from about 250 to about 400 g/10 min.
4. The multilayer structure of claim 1 wherein the acid copolymer is an ethylene methacrylic acid dipolymer having about 18 to about 25 weight % of copolymerized units of methacrylic acid.
5. The multilayer structure of claim 1 wherein the ionomer composition comprises at least 11 weight % methacrylic acid salt and has a MFR of at least 1 g/10 min.
6. The multilayer structure of claim 1 wherein about 55% to about 60% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts.
7. The multilayer structure of claim 1 wherein the substrate is paper, paperboard, cardboard, pulp-molded shape, textile, material made from a synthetic fiber spun fabric, film, open-cell foam, closed-cell foam, or metallic foil.
8. The multilayer structure of claim 1 wherein the substrate is paper, paperboard, cardboard, or pulp-molded shape.
9. An article comprising the multilayer structure of claim 1 .
10. The multilayer structure of claim 1 wherein (b) is present in the combination of (a) and (b) in an amount from about 10 to about 95 weight %, (a) being present in a complementary amount.
11. The multilayer structure of claim 1 wherein (b) is present in the combination of (a) and (b) in an amount from about 60 to about 95 weight %, (a) being present in a complementary amount.
12. The multilayer structure of claim 1 wherein the poly(vinyl alcohol) is characterized by a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity at 20° C. of 15 cp or less.
13. The multilayer structure of claim 1 wherein the poly(vinyl alcohol) is characterized by a hydrolysis level of about 95 to 100 mol %.