IP Library Granted Patent US 10,330,364
Granted Patent B2
US 10,330,364 · App. 14/744,776 · Granted Jun 25, 2019

System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant

Inventor: Charles Harkins (Hampstead, NH)
Assignee: Hudson Technologies, Inc.
F25B45/00C09K5/045C10M105/38C10M171/008F25B31/002C09K2205/104C09K2205/122C09K2205/22C09K2205/40C09K2205/43C10M2207/2835C10N2220/302C10N2220/303C10N2240/30F25B2345/001F25B2345/007
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Quick Facts
Patent No.
US 10,330,364
App. No.
14/744,776
Granted
Jun 25, 2019
Kind
B2
Abstract

A system and method for retrofitting a refrigeration system containing an HCFC refrigerant and a compatible lubricant, with an HFC refrigerant, comprising providing a transport container containing a mixture of a miscible lubricant and the HFC refrigerant, removing the HCFC refrigerant from the refrigeration system while maintaining at least a portion of a lubricant immiscible with the HFC refrigerant, and charging the refrigeration system with the mixture. The polyol ester lubricant may be present in a range exceeding about 5-15% by weight, e.g., 8%.

Claims (37)

1. A method for retrofitting a refrigeration system from an HCFC refrigerant compatible with a mineral oil or alkyl benzene lubricant to an HFC refrigerant compatible with a polyol ester lubricant, comprising:

evacuating the HCFC from the refrigeration system, leaving at least a portion of the mineral oil or alkyl benzene lubricant; and

charging the refrigeration system with a composition comprising the HFC refrigerant mixed with a polyol ester lubricant,

thereby resulting in a refrigeration system charged with the HFC and a mixed lubricant comprising both the mineral oil or alkyl benzene lubricant and the polyol ester lubricant.

2. The method according to claim 1 ,

wherein the refrigeration system comprises a hermetically sealed refrigeration system, further comprising:

providing a transport container containing the HFC refrigerant mixed with the polyol ester lubricant; and

said evacuating comprises withdrawing the HCFC from within the refrigeration system through a charge-discharge port, leaving at least a portion of the mineral oil or alkyl benzene lubricant.

3. The method according to claim 1 , wherein the mineral oil or alkyl benzene lubricant is a mineral oil lubricant.

4. The method according to claim 1 , wherein the HCFC comprises R-22, and the HFC comprises R-407C.

5. The method according to claim 1 , wherein the polyol ester is provided in an amount of 5% to 15% by weight.

6. The method according to claim 1 , wherein the polyol ester is provided in an amount of 8% by weight.

7. The method according to claim 1 , wherein the refrigeration system after recharging has a concentration of 15-32% by weight mixed lubricant.

8. The method according to claim 1 , wherein the transport container is U.S. Department of Transportation compliant.

9. The method according to claim 1 , wherein the transport container is compliant at least one of U.S. Department of Transportation standards DOT-39, DOT 3, DOT 3A, DOT 3AA, DOT 3AL, DOT 3B, DOT 3BN, DOT 3E, DOT 4B, DOT 4BA, DOT 4B240ET, DOT 4BW, DOT 4E, DOT 3AL1800; DOT 4D; DOT-3A1000; DOT-3A1200; DOT-3A150; DOT-3A1800; DOT-3A2000; DOT-3A225; DOT-3A240; DOT-3A2400; DOT-3A300; DOT-3A400; DOT-3A480; DOT-3A480X; DOT-3AA; DOT-3AA1000; DOT-3AA1200; DOT-3AA150; DOT-3AA1800; DOT-3AA2000; DOT-3AA225; DOT-3AA240; DOT-3AA2400; DOT-3AA300; DOT-3AA400; DOT-3AA480; DOT-3AAX1800; DOT-3AAX2000; DOT-3AAX2200; DOT-3AAX2400; DOT-3AL; DOT-3AL1000; DOT-3AL150; DOT-3AL1800; DOT-3AL2000; DOT-3AL225; DOT-3AL240; DOT-3AL2400; DOT-3AL400; DOT-3AL480; DOT-3AX1800; DOT-3AX2000; DOT-3AX2200; DOT-3AX2400; DOT-3B; DOT-3B150; DOT-3B1800; DOT-3B225; DOT-3B240; DOT-3B300; DOT-3B400; DOT-3BN400; DOT-3BN480; DOT-3E1800; DOT-3HT; DOT-3HT2000; DOT-3T1800; DOT-3T2000; DOT-3T2200; DOT-3T2400; DOT-4A; DOT-4AA480; DOT-4B; DOT-4B150; DOT-4B150; DOT-4B225; DOT-4B240; DOT-4B240ET; DOT-4B300; DOT-4B400; DOT-4B480; DOT-4BA; DOT-4BA225; DOT-4BA240; DOT-4BA300; DOT-4BA400; DOT-4BW225; DOT-4BW240; DOT-4BW300; DOT-4BW400; DOT-4BW480; DOT-4DA; DOT-4DS; DOT-4E225; DOT-4E240; DOT-4L; DOT-AAX2400; and ICC-3E1800.

10. The method according to claim 1 , wherein the HFC refrigerant is a blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a).

11. The method according to claim 10 , wherein the HFC is R-407C, and the polyol ester lubricant is premixed with the HFC refrigerant in an amount of 8% by weight.

12. The method according to claim 10 , wherein the system after charging has a concentration of 20-25% by weight lubricant mixture.

13. The method according to claim 10 , wherein the HFC refrigerant mixed with the polyol ester lubricant is provided in a U.S. Department of Transportation compliant transport container having a capacity of 50 pounds or lower.

14. A method for retrofitting an HCFC refrigeration system having a mineral oil or alkyl benzene lubricant, which persists as a residual after removal of the HCFC from the refrigeration system by evacuation, to an HFC refrigerant which is not compatible with the HFC refrigerant as a sole lubricant, comprising:

providing a container adapted for common carrier transport, containing a composition comprising an HFC refrigerant mixed with a compatible polyol ester lubricant;

evacuating the HCFC from the refrigeration system, leaving at least a portion of the mineral oil or alkyl benzene lubricant within the refrigeration system; and

charging the refrigeration system with the composition from the container, comprising the HFC refrigerant mixed with the compatible polyol ester lubricant,

to thereby provide the refrigeration system charged with the HFC and a combination of the mineral oil or alkyl benzene lubricant and the HFC refrigerant.

15. The method according to claim 14 , wherein:

the HCFC comprises R-22;

the container comprises a U.S. Department of Transportation certified transport container; and

the HFC is R-407C.

16. The method according to claim 14 , wherein the polyol ester lubricant is present in the container an amount of 5% to 15% by weight and the HFC refrigerant is present in an amount of 95-85% by weight.

17. The method according to claim 14 , wherein the polyol ester lubricant is present in the container an amount of 8% by weight and the HFC refrigerant is present in an amount of 92% by weight.

18. The method according to claim 14 , wherein the HFC is selected from the group consisting of R-134a, R-404A, R-407A, R-407C, R-407F, R-410A, R-417A, R-417B, R-422A, R-422B, R-422C, R-422D, R-424A, R-427A, R-428A, R-434A, R-438A, R-442A, and RS07A.

19. The method according to claim 14 , wherein the transport container is DOT-39 compliant.

20. A method for retrofitting a refrigeration system from an HCFC refrigerant compatible with a mineral oil or alkyl benzene lubricant to 407C premixed with a compatible polyol ester lubricant in an amount of between 5%-20% by weight of the refrigerant, comprising:

providing a mixture of the 407C premixed with the compatible polyol ester lubricant to the refrigeration system in a U.S. Department of Transportation compliant transport container having a capacity of 50 pounds or lower;

evacuating the HCFC from the refrigeration system through a charge-discharge port of the refrigeration system, without draining the mineral oil or alkyl benzene lubricant, and leaving at least a portion of the mineral oil or alkyl benzene lubricant in the refrigeration system; and

charging the refrigeration system with the mixture from the container of the 407C premixed with the compatible polyol ester lubricant,

thereby resulting in the refrigeration system charged with the 407C and a mixed lubricant comprising both the mineral oil or alkyl benzene lubricant and the compatible polyol ester lubricant, wherein the mixed lubricant is present in the refrigeration system in an amount of 16% to 32% by weight of the refrigerant charge, and the compatible polyol ester lubricant is present in the refrigeration system an amount of 25% to 50% by weight of the mixed lubricant.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Aug 21, 2023
From: TCW ASSET MANAGEMENT COMPANY LLC
To: HUDSON TECHNOLOGIES, INC.
Reel/Frame 064650/0964 →
SECURITY INTEREST Recorded Mar 2, 2022
From: HUDSON TECHNOLOGIES, INC.
To: TCW ASSET MANAGEMENT COMPANY LLC, AS AGENT
Reel/Frame 059146/0131 →
RELEASE OF SECURITY INTEREST Recorded Dec 24, 2019
From: PNC BANK, NATIONAL ASSOCIATION
To: HUDSON TECHNOLOGIES, INC
Reel/Frame 051361/0803 →
SECURITY INTEREST Recorded Dec 19, 2019
From: HUDSON TECHNOLOGIES, INC.; HUDSON TECHNOLOGIES COMPANY
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 051337/0590 →
SECURITY INTEREST Recorded Oct 17, 2017
From: HUDSON TECHNOLOGIES, INC.
To: PNC BANK, NATIONAL ASSOCIATION
Reel/Frame 043887/0250 →
SECURITY INTEREST Recorded Oct 10, 2017
From: HUDSON TECHNOLOGIES, INC.
To: U.S. BANK NATIONAL ASSOCIATION, AS AGENT
Reel/Frame 043828/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2015
From: HARKINS, CHARLES, JR.
To: HUDSON TECHNOLOGIES, INC.
Reel/Frame 035869/0347 →
Continuity (3)
Provisional Application 62032129 · Aug 1, 2014
Provisional Application 62017530 · Jun 26, 2014
Related Publication 20150377533A1 · Dec 31, 2015
Cited By (1)
US 12,467,668