UV-resistant superhydrophobic coating compositions
View Patent ↗A coating composition for a substrate includes a polymer binder, one or more hydrophobic silicon dioxide compositions, and one or more UV protection agents. The polymer binder can include a fluoropolymer or an epoxy polymer resin. The coating composition can also include molybdenum disulfide.
1. A coating composition for a substrate, the coating composition comprising:
a polymer binder comprising a fluoropolymer or an epoxy polymer resin;
one or more hydrophobic silicon dioxide compositions;
molybdenum disulfide; and
one or more UV protection agents;
wherein the coating composition includes at least about 50% by weight of the polymer binder, from about 0.5% to about 15% by weight of one or more hydrophobic silicon dioxide compositions, from about 0.1% to about 15% by weight of molybdenum disulfide, and from about 0.1% to about 10% by weight of one or more UV protection agents.
2. The coating composition of claim 1 , wherein the polymer binder has a glass transition temperature or a melting point in a range from 75° C. to 350° C.
3. The coating composition of claim 1 , wherein the binder comprises at least one fluoropolymer selected from the group consisting of polytetrafluoroethylene (PTFE), polyvinylidene difluoride (PVDF), and polyhexafluoropropylene (PHFP).
4. The coating composition of claim 1 , wherein the binder comprises at least one epoxy polymer resin having a viscosity at a temperature from about 20° C. to about 27° C. and prior to initiation of curing in the range from 1 centipoise to 25,000 centipoise.
5. The coating composition of claim 1 , wherein at least one of the UV protection agents comprises zinc oxide.
6. The coating composition of claim 1 , wherein each of the one or more hydrophobic silicon dioxide compositions comprises at least one functional group selected from the group consisting of alkyl, alkoxy, silyl, alkoxysilyl and siloxy.
7. A conductor coated with the coating composition of claim 1 .
8. A conductor comprising a plurality of stranded wires, wherein at least one stranded wire is coated with the coating composition of claim 1 .
9. The coating composition of claim 1 , wherein
a contact angle of a water droplet formed on the coating composition is at least 140° after exposure of the coating composition to UV radiation of at least about 1 W/m 2 for a time period of at least about 150 hours.
10. The coating composition of claim 6 , wherein each of the one or more functional groups is selected from the group consisting of methyl chlorosilanes, hexamethyldisilazane (HMDS), polydimethylsiloxane (PDMS), octylsilane, hexadecylsilane, methacrylsilane, dimethyldichlorosilane (DDS), and octamethylcyclotetrasiloxane.
11. The conductor of claim 7 , wherein the conductor comprises a bare overhead conductor.
12. The conductor of claim 7 , wherein an exterior surface of the conductor is coated with the coating composition at a thickness from about 0.00001 inch to about 0.030 inch.
13. The conductor of claim 7 , wherein the conductor is a grounding bare wire.
14. The conductor of claim 7 , wherein the conductor comprises a solid conductor material comprising copper, aluminum or aluminum alloy.
15. The coating composition of claim 9 , wherein the contact angle of a water droplet formed on the coating composition is at least 140° after exposure of the coating composition to UV radiation of at least about 1 W/m 2 for a time period of at least about 470 hours.
16. The conductor of claim 11 , wherein the conductor comprises aluminum, steel or a carbon fiber polymer composite material.