Electrostatic printing of cyclodextrin compositions
Disclosed herein are methods of electrostatically printing a cyclodextrin composition on a substrate, the method including forming an electrostatically printable composition comprising a polymer and one or more cyclodextrins, one or more cyclodextrin inclusion complexes, or a combination thereof, and electrostatically printing the composition on a substrate. Also described are electrostatically printable compositions, methods of making the compositions, printing systems employing the compositions, substrates having the composition electrostatically printed thereon, laminates thereof, and uses of the printed substrates and laminates.
1. A method of printing a cyclodextrin composition onto a substrate, the method comprising
forming one or more cyclodextrin inclusion complexes, the one or more cyclodextrin inclusion complexes comprising cyclodextrin complexed with a medicament, a fragrance, a colorant, a fungicide, an insecticide, a pesticide, an antimicrobial, a preservative, or 1-methylcyclopropene;
combining a polymer and the one or more cyclodextrin inclusion complexes to form an electrostatically printable composition;
adding the printable composition to a cartridge, the cartridge designed and adapted to be connected to an electrostatic printer for dispensing electrostatically printable materials during electrostatic printing; connecting the cartridge to the electrostatic printer; and
directing the printer to electrostatically print an image on a substrate.
2. The method of claim 1 wherein two or more cartridges are connected to the electrostatic printer, wherein each of the two or more cartridges comprises a different electrostatically printable composition.
3. The method of claim 1 wherein the directing is carried out using a computer.
4. The method of claim 3 wherein the directing includes selecting a pattern of printing, an area of printing, or both.
5. The method of claim 1 wherein the printable composition comprises one or more colorants, matrix modifiers, charge control additives, waxes, low-melting polymers, or a combination of two or more thereof.
6. A composition comprising a core-shell particulate having an average particle size of about 4 μm to 16 μm, the core-shell particulate comprising a polymer core particulate and a shell composition covering about 50% to 250% of the theoretical surface area of the core particulate, the shell composition comprising one or more cyclodextrin inclusion complexes, the one or more cyclodextrin inclusion complexes comprising cyclodextrin complexed with a medicament, a fragrance, a colorant, a fungicide, an insecticide, a pesticide, an antimicrobial, a preservative, or 1-methylcyclopropene, wherein the composition is printable using an electrostatic printing method.
7. The composition of claim 6 wherein the shell composition further comprises a wax or a low melting polymer.
8. The composition of claim 6 wherein the polymer core particulate comprises a polyester.
9. The composition of claim 6 wherein the composition further comprises a matrix modifier or a charge control additive.
10. A printed substrate comprising a first major surface comprising an electrostatically printable composition electrostatically printed on at least a portion of the area thereof, the electrostatically printable composition comprising a core-shell particulate having an average particle size of about 4 μm to 16 μm and comprising a polymer core particulate and a shell composition covering about 50% to 250% of the theoretical surface area of the core particulate, the shell composition comprising one or more cyclodextrin inclusion complexes, the one or more cyclodextrin inclusion complexes comprising cyclodextrin complexed with a medicament, a fragrance, a colorant, a fungicide, an insecticide, a pesticide, an antimicrobial, a preservative, or 1-methylcyclopropene.
11. The printed image of claim 10 wherein the electrostatically printable composition further comprises one or more colorants and the printed area has a color or grayscale value that corresponds to the amount of printed composition present on the printed area.
12. A laminate comprising the printed substrate of claim 10 .
13. An electrostatic printing system, the system comprising
an electrostatic printer,
a computer adapted to direct the printer,
one or more cartridges operably connected the printer for electrostatically printing an electrostatically printable composition on a substrate, wherein at least one of the cartridges comprises an electrostatically printable composition comprising a particulate comprising a polymer and one or more cyclodextrin inclusion complexes, the one or more cyclodextrin inclusion complexes comprising cyclodextrin complexed with a medicament, a fragrance, a colorant, a fungicide, an insecticide, a pesticide, an antimicrobial, a preservative, or 1-methylcyclopropene; and
one or more sheets or rolls of an electrostatically printable substrate.
14. The printing system of claim 13 wherein the electrostatic printer comprises a fusing roller having a variable temperature, wherein the temperature is selected by a user by the user instructing the computer to direct the printer to set the fusing roller temperature.
15. The printing system of claim 13 wherein the printable composition comprises a colorant, and wherein the printing system further comprises an electronic or printed guide displaying the correspondence of color on a printed substrate to the amount of the cyclodextrin inclusion complex that is deposited within a printed area of the printed substrate.
16. The printing system of claim 13 wherein the system further includes a lamination apparatus for contacting a laminating substrate to a printed substrate to form a laminate.
17. A method of making a printable composition, the method comprising
forming a core particulate comprising a polymer;
optionally classifying the core particulate to provide a selected average particle size range;
forming a shell composition comprising one or more cyclodextrin inclusion complexes, the one or more cyclodextrin inclusion complexes comprising cyclodextrin complexed with a medicament, a fragrance, a colorant, a fungicide, an insecticide, a pesticide, an antimicrobial, a preservative, or 1-methylcyclopropene; and
adding the shell composition to the core particulate to form a printable composition,
wherein the printable composition is in the form of a particulate having an average particle size of about 4 μm to 16 μm, further wherein the composition is printable using an electrostatic printing method.
18. The method of claim 17 wherein the adding is carried out using a high speed blending process.
19. The method of claim 17 further comprising classifying the printable composition to provide a selected average particle size.