Reflectors for time-of-flight mass spectrometers having plates with symmetric shielding edges
View Patent ↗The invention relates to reflectors for time-of-flight mass spectrometers, and especially their design. A Mamyrin reflector is provided which consists of metal plates with cut-out internal apertures, and symmetric shielding edges which are set back from the inner edges. The dipole field formed by these shielding edges penetrates only slightly through the plates and into the interior of the reflector. With a good mechanical design, the resolving power of the time-of-flight mass spectrometer increases by around fifteen percent compared to the best prior art to date.
1. A reflector for a time-of-flight mass spectrometer in which approaching ions are decelerated and re-accelerated by electric fields, the reflector comprising a plurality of apertured potential plates having inward-protruding narrow plate lugs and being arranged substantially parallel to one another and separated by insulating spacers in a first direction, wherein an electric field in an interior of the reflector is formed substantially by the narrow plate lugs, and wherein each potential plate has a symmetric shielding edge that extends symmetrically in the first direction to both sides of the narrow plate lug of that potential plate at a predetermined distance from an interior of the reflector.
2. The reflector according to claim 1 , wherein the potential plates are manufactured from planar metal plates.
3. The reflector according to claim 2 , wherein the potential plates are laser cut from the metal plates.
4. A reflector for a time-of-flight mass spectrometer in which approaching ions are decelerated and re-accelerated by electric fields, the reflector comprising a plurality of apertured potential plates arranged substantially parallel to one another and separated by insulating spacers in a first direction, wherein each potential plate has a symmetric shielding edge that extends symmetrically in the first direction to both sides of the potential plate at a predetermined distance from an interior of the reflector, and wherein each potential plate comprises a metal base plate with tabs extending therefrom and two angle plates with openings through which the tabs pass such that the angle plates reside adjacent to an outer edge of the base plate and extend in a substantially perpendicular direction to form the shielding edge.
5. The reflector according to claim 4 , wherein the tabs of a potential plate are integral with and parallel to the base plate and the openings in the angle plates comprise slits within which the tabs reside such that the potential plates are positioned and mechanically stabilized thereby.
6. The reflector according to claim 1 , wherein the spacers which electrically insulate the potential plates from one another are located to a side of the shielding edges away from the apertures of the potential plates.
7. The reflector according to claim 1 , wherein a single, continuously homogeneous field is generated by the potential plates.
8. The reflector according to claim 1 , wherein the potential plates generate a first, relatively strong deceleration field region that reduces the speed of approaching ions, and a second, much weaker reflection field region that brings the ions to a standstill and reflects them.
9. The reflector according to claim 1 , wherein an electric circuit of the potential plates comprises voltage dividers made of precision resistors in order to achieve a potential which increases as uniformly as possible from plate to plate.
10. A time-of-flight mass spectrometer having a reflector according to claim 1 .
11. The mass spectrometer according to claim 10 , wherein the potential plates are manufactured from planar metal plates.
12. The mass spectrometer according to claim 11 , wherein the potential plates are laser cut from the metal plates.
13. The mass spectrometer according to claim 11 , wherein each potential plate comprises a metal base plate with tabs extending therefrom and two angle plates with openings through which the tabs pass such that the angle plates reside adjacent to an outer edge of the base plate and extend in a substantially perpendicular direction to form the shielding edges.
14. The mass spectrometer according to claim 13 , wherein the tabs of a potential plate are integral with and parallel to the base plate and the openings in the angle plates comprise slits within which the tabs reside such that the potential plates are positioned and mechanically stabilized thereby.
15. The mass spectrometer according to claim 10 , wherein the spacers which electrically insulate the potential plates from one another are located to a side of the shielding edges away from the apertures of the potential plates.
16. The mass spectrometer according to claim 10 , wherein a single, continuously homogeneous field is generated by the potential plates.
17. The mass spectrometer according to claim 10 , wherein the potential plates generate a first, relatively strong deceleration field region that reduces the speed of the approaching ions, and a second, much weaker reflection field region that brings the ions to a standstill and reflects them.
18. The mass spectrometer according to claim 10 , wherein an electric circuit of the potential plates comprises voltage dividers made of precision resistors in order to achieve a potential which increases as uniformly as possible from plate to plate.
19. A reflector for a time-of-flight mass spectrometer in which approaching ions are decelerated and re-accelerated by electric fields, the reflector comprising a plurality of apertured potential plates arranged substantially parallel to one another and separated by insulating spacers in a first direction, wherein each potential plate has a symmetric shielding edge that extends symmetrically in the first direction to both sides of the potential plate at a predetermined distance from an interior of the reflector, and wherein each potential plate comprises a metal base plate having insertion lugs extending therefrom and further comprises peripheral plates having apertures through which the insertion lugs pass and being aligned perpendicularly with the metal base plate, whereby the peripheral plates form the symmetric shielding edge around the metal base plate.
20. The reflector according to claim 19 , wherein the insertion lugs of the metal base plate are fixed to the peripheral plates in the apertures by laser welding to produce a torsion-resistant structure.