Li-ion battery having improved safety against combustion
The present invention provides a process comprising for modifying a Li-ion battery having a region of electrochemical activity and an enclosure therefor, said process comprising forming at least one chamber within said enclosure separate from said region of electrochemical activity, positioning combustion abatement agent within said chamber, whereby said combustion abatement agent is not in contact with said region of electrochemical activity, said chamber being pressure or heat sensitive, whereby when said region of electrochemical activity overheats, said chamber is breached, allowing said combustion abatement agent to contact said region of electrochemical activity to abate combustion of said region of electrochemical activity, wherein exemplary of combustion abatement agent is the composition comprising liquid fluoropolyether and exemplary of the of the chamber exhibiting pressure or heat sensitivity is to include a low melting, non-flammable polymer such as polyvinyl alcohol in the material of construction of the chamber.
1. A Li-ion battery comprising
an enclosure, wherein said enclosure is a can,
structure defining a region of Li-ion electrochemical activity positioned within said enclosure,
said structure including oppositely charged electrodes for attracting Li-ions from one said electrode to another said electrode,
structure defining at least one chamber positioned within said enclosure separate from said region of Li-ion electrochemical activity,
said region of Li-ion electrochemical activity being subject to overheating by short-circuiting occurring within said region of Li-ion electrochemical activity,
said chamber containing combustion abatement agent maintained separate from said region of Li-ion electrochemical activity, wherein said enclosure includes a vent for pressure release upon said overheating occurring within said region of Li-ion battery electrochemical activity, and said chamber containing said combustion abatement agent is positioned between said vent and said region of Li-ion electrochemical activity,
said structure defining said chamber containing said combustion abatement agent including a membrane that is breachable by said overheating to thereby release said combustion abatement agent into said region of electrochemical activity to abate combustion therewithin,
with the proviso that when said membrane comprises combustion abatement agent, the presence of said combustion abatement agent in said chamber is optional.
2. The Li-ion battery of claim 1 wherein said membrane is breachable by said overheating causing rupture of said membrane.
3. The Li-ion battery of claim 1 wherein said membrane is breachable by said overheating causing melting of said membrane.
4. The Li-ion battery of claim 1 wherein said membrane is inert to the Li-ion electrochemical activity occurring within said region of Li-ion electrochemical activity.
5. The Li-ion battery of claim 1 wherein said vent includes a closure that opens to permit said pressure release, the opening of said vent accompanying the rupture of said membrane.
6. The Li-ion battery of claim 1 wherein said vent is positioned at one end of said enclosure and an additional chamber including a membrane that is breachable by said overheating and containing combustion abatement agent is positioned remote from said chamber positioned between said vent and said region of Li-ion electrochemical activity, whereby said combustion abatement agent from each said chambers is released into said region of Li-ion electrochemical activity upon said overheating to thereby abate combustion within said region of Li-ion electrochemical activity.
7. The Li-ion battery of claim 1 wherein said combustion abatement agent is a composition comprising liquid fluoropolyether.
8. The Li-ion battery of claim 7 wherein said composition additionally comprises decomposition catalyst and/or solid material.
9. The Li-ion battery of claim 8 wherein said solid material is additional combustion abatement agent.
10. The Li-ion battery of claim 8 wherein said composition resulting from said liquid fluoropolyether and said solid material is a semi-solid.
11. The Li-ion battery of claim 7 wherein said combustion abatement agent is not in contact with said region of electrochemical activity.
12. The Li-ion battery of claim 7 wherein said liquid fluoropolyether is a perfluoropolyether.
13. The Li-ion battery of claim 7 wherein said composition additionally comprises decomposition catalyst comprising a Lewis acid.
14. The Li-ion battery of claim 1 wherein said membrane comprises a thermally destabilizable fluoropolymer.
15. The Li-ion battery of claim 14 wherein said thermally destabilizable fluoropolymer is selected from the group consisting of a tetrafluoroethylene/hexafluoropropylene copolymer and a tetrafluoroethylene/hexafluoropropylene/perfluoro(alkyl vinyl ether) copolymer.
16. Li-ion battery of claim 15 wherein said thermally destabilizable fluoropolymer has at least 300 unstable end groups per 10 6 carbon atoms, said endgroups being selected from the group consisting of —COOH, COF, and —CONH 2 .